具有增强光催化活性的Z-scheme BiVO4/CNTs/Cu2O三元异质结的构建及其全天候抗菌应用

IF 4.1 3区 化学 Q2 CHEMISTRY, PHYSICAL
Rongqing Wang , Jiajia Wu , Jiaqi Wan , Peng Wang , Dun Zhang
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引用次数: 0

摘要

异质结的构建是实现光诱导载流子分离和迁移的有效策略。在这项工作中,首先利用直接的湿化学合成工艺构建了Z-scheme BiVO4/CNTs/Cu2O (BCC)体系,用于抗菌目的,并讨论了理想的CNTs比例。结果表明,CNTs质量比为3%的BCC-3光催化剂具有最好的光催化抗菌性能。这可能是因为z型异质结维持了光诱导载体的高氧化还原电位,从而能够产生更多用于抗菌目的的活性物质。此外,由于少量Cu2O的存在,制备的复合材料在黑暗状态和没有外部光源的情况下表现出全天候的抗菌活性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Construction of Z-scheme BiVO4/CNTs/Cu2O ternary heterojunction with enhanced photocatalytic activity for round-the-clock antibacterial application
The construction of heterojunctions is a productive strategy in getting the separation and migration of photoinduced carriers. In this work, Z-scheme BiVO4/CNTs/Cu2O (BCC) system was initially constructed utilizing a straightforward wet chemical synthesis process for antibacterial purposes, and a desirable CNTs proportion was discussed. The results exposed that the BCC-3 photocatalyst with a CNTs mass proportion of 3 % had the greatest photocatalytic antibacterial property. This might be because the Z-scheme heterojunction sustains the high redox potential of photoinduced carriers, enabling the production of more active substances for antibacterial purposes. Additionally, the as-prepared composites exhibited round-the-clock antibacterial activity in the dark state and the absence of an external light source due to the presence of a small amount of Cu2O.
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来源期刊
CiteScore
7.90
自引率
7.00%
发文量
580
审稿时长
48 days
期刊介绍: JPPA publishes the results of fundamental studies on all aspects of chemical phenomena induced by interactions between light and molecules/matter of all kinds. All systems capable of being described at the molecular or integrated multimolecular level are appropriate for the journal. This includes all molecular chemical species as well as biomolecular, supramolecular, polymer and other macromolecular systems, as well as solid state photochemistry. In addition, the journal publishes studies of semiconductor and other photoactive organic and inorganic materials, photocatalysis (organic, inorganic, supramolecular and superconductor). The scope includes condensed and gas phase photochemistry, as well as synchrotron radiation chemistry. A broad range of processes and techniques in photochemistry are covered such as light induced energy, electron and proton transfer; nonlinear photochemical behavior; mechanistic investigation of photochemical reactions and identification of the products of photochemical reactions; quantum yield determinations and measurements of rate constants for primary and secondary photochemical processes; steady-state and time-resolved emission, ultrafast spectroscopic methods, single molecule spectroscopy, time resolved X-ray diffraction, luminescence microscopy, and scattering spectroscopy applied to photochemistry. Papers in emerging and applied areas such as luminescent sensors, electroluminescence, solar energy conversion, atmospheric photochemistry, environmental remediation, and related photocatalytic chemistry are also welcome.
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