Xingteng Zhou, Can Yang, Jun Zhang, Jianshen Chen, Ying Li, Lin Lin, Runping Jia, Xiaowei Xu
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In this study, A straightforward and efficient two-step hydrothermal method was utilized to synthesize NiCoSe@KMXene nanocomposites with high precision and reproducibility. The resulting NiCoSe@KMXene electrode exhibits an exceptional specific capacitance (Cs) of 2210<!-- --> <!-- -->F<!-- --> <!-- -->g<sup>-1</sup> at a current density of 2<!-- --> <!-- -->A<!-- --> <!-- -->g<sup>-1</sup> in supercapacitor applications. Additionally, the as-prepared NiCoSe@KMXene electrode material demonstrates excellent electrocatalytic activity for HER, requiring only 51.8<!-- --> <!-- -->mV to achieve the current density of 10<!-- --> <!-- -->mA<!-- --> <!-- -->cm<sup>-2</sup>. Furthermore, the as-prepared sample function as both anode and cathode, enabling the construction of a symmetric supercapacitor (SSC) device with a distinctive architecture. This device exhibits outstanding performance, including superior energy density, high power density, and excellent cycling stability. At the current density of 5<!-- --> <!-- -->A<!-- --> <!-- -->g<sup>-1</sup>, the SSC device delivers a remarkable specific capacitance of 232.5<!-- --> <!-- -->F<!-- --> <!-- -->g<sup>-1</sup>, along with an energy density of 296<!-- --> <!-- -->Wh<!-- --> <!-- -->kg<sup>-1</sup> at a power density of 2.21<!-- --> <!-- -->kW<!-- --> <!-- -->kg<sup>-1</sup>. These results highlight the significant potential of NiCoSe@KMXene materials for energy storage and conversion applications. The strategy employed for the NiCoSe@KMXene nanocomposites offers an innovative approach for synthesizing transition metal-based compounds, eliminating the need for adhesives and enabling more efficient and integrated designs for future applications.","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"58 1","pages":""},"PeriodicalIF":6.3000,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"NiCoSe@KMXene Hybrid Nanocomposites: A Novel Bifunctional Platform for Energy Storage and Conversion Applications\",\"authors\":\"Xingteng Zhou, Can Yang, Jun Zhang, Jianshen Chen, Ying Li, Lin Lin, Runping Jia, Xiaowei Xu\",\"doi\":\"10.1016/j.jallcom.2025.180850\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"As the demand for energy storage and conversion devices continues to rise, the development of electrode materials that are efficient, environmentally sustainable, highly stable, and long-lasting has become a pressing challenge. These materials are required to not only deliver exceptional performance but also align with sustainability goals to effectively address the growing energy and environmental challenges. Transition metal selenides (TMSs) have gained significant attention in research due to their outstanding performance in supercapacitors and hydrogen evolution reactions (HER). They are increasingly regarded as a promising alternative to noble metal-based electrode materials. In this study, A straightforward and efficient two-step hydrothermal method was utilized to synthesize NiCoSe@KMXene nanocomposites with high precision and reproducibility. The resulting NiCoSe@KMXene electrode exhibits an exceptional specific capacitance (Cs) of 2210<!-- --> <!-- -->F<!-- --> <!-- -->g<sup>-1</sup> at a current density of 2<!-- --> <!-- -->A<!-- --> <!-- -->g<sup>-1</sup> in supercapacitor applications. Additionally, the as-prepared NiCoSe@KMXene electrode material demonstrates excellent electrocatalytic activity for HER, requiring only 51.8<!-- --> <!-- -->mV to achieve the current density of 10<!-- --> <!-- -->mA<!-- --> <!-- -->cm<sup>-2</sup>. Furthermore, the as-prepared sample function as both anode and cathode, enabling the construction of a symmetric supercapacitor (SSC) device with a distinctive architecture. This device exhibits outstanding performance, including superior energy density, high power density, and excellent cycling stability. At the current density of 5<!-- --> <!-- -->A<!-- --> <!-- -->g<sup>-1</sup>, the SSC device delivers a remarkable specific capacitance of 232.5<!-- --> <!-- -->F<!-- --> <!-- -->g<sup>-1</sup>, along with an energy density of 296<!-- --> <!-- -->Wh<!-- --> <!-- -->kg<sup>-1</sup> at a power density of 2.21<!-- --> <!-- -->kW<!-- --> <!-- -->kg<sup>-1</sup>. 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引用次数: 0
摘要
随着人们对能量存储和转换设备的需求不断增加,开发高效、环保、高稳定、持久的电极材料已成为一项紧迫的挑战。这些材料不仅需要提供卓越的性能,还需要与可持续发展目标保持一致,以有效应对日益增长的能源和环境挑战。过渡金属硒化物(tms)由于其在超级电容器和析氢反应(HER)中的优异性能而受到广泛关注。它们越来越被认为是贵金属基电极材料的有前途的替代品。本研究采用简单高效的两步水热法合成NiCoSe@KMXene纳米复合材料,具有较高的精密度和重复性。所得NiCoSe@KMXene电极在超级电容器应用中,在电流密度为2 a g-1时,具有2210 F g-1的特殊比电容(Cs)。此外,制备的NiCoSe@KMXene电极材料对HER具有优异的电催化活性,仅需51.8 mV即可达到10 mA cm-2的电流密度。此外,制备的样品可以同时作为阳极和阴极,从而可以构建具有独特结构的对称超级电容器(SSC)器件。该器件具有优异的性能,包括优越的能量密度、高功率密度和优良的循环稳定性。在5 A g-1的电流密度下,SSC器件提供了232.5 F g-1的显着比电容,以及2.21 kW kg-1的功率密度下296 Wh kg-1的能量密度。这些结果突出了NiCoSe@KMXene材料在能量存储和转换应用方面的巨大潜力。NiCoSe@KMXene纳米复合材料所采用的策略为合成过渡金属基化合物提供了一种创新的方法,消除了对粘合剂的需求,并为未来的应用提供了更高效和集成的设计。
NiCoSe@KMXene Hybrid Nanocomposites: A Novel Bifunctional Platform for Energy Storage and Conversion Applications
As the demand for energy storage and conversion devices continues to rise, the development of electrode materials that are efficient, environmentally sustainable, highly stable, and long-lasting has become a pressing challenge. These materials are required to not only deliver exceptional performance but also align with sustainability goals to effectively address the growing energy and environmental challenges. Transition metal selenides (TMSs) have gained significant attention in research due to their outstanding performance in supercapacitors and hydrogen evolution reactions (HER). They are increasingly regarded as a promising alternative to noble metal-based electrode materials. In this study, A straightforward and efficient two-step hydrothermal method was utilized to synthesize NiCoSe@KMXene nanocomposites with high precision and reproducibility. The resulting NiCoSe@KMXene electrode exhibits an exceptional specific capacitance (Cs) of 2210 F g-1 at a current density of 2 A g-1 in supercapacitor applications. Additionally, the as-prepared NiCoSe@KMXene electrode material demonstrates excellent electrocatalytic activity for HER, requiring only 51.8 mV to achieve the current density of 10 mA cm-2. Furthermore, the as-prepared sample function as both anode and cathode, enabling the construction of a symmetric supercapacitor (SSC) device with a distinctive architecture. This device exhibits outstanding performance, including superior energy density, high power density, and excellent cycling stability. At the current density of 5 A g-1, the SSC device delivers a remarkable specific capacitance of 232.5 F g-1, along with an energy density of 296 Wh kg-1 at a power density of 2.21 kW kg-1. These results highlight the significant potential of NiCoSe@KMXene materials for energy storage and conversion applications. The strategy employed for the NiCoSe@KMXene nanocomposites offers an innovative approach for synthesizing transition metal-based compounds, eliminating the need for adhesives and enabling more efficient and integrated designs for future applications.
期刊介绍:
The Journal of Alloys and Compounds is intended to serve as an international medium for the publication of work on solid materials comprising compounds as well as alloys. Its great strength lies in the diversity of discipline which it encompasses, drawing together results from materials science, solid-state chemistry and physics.