{"title":"二硫化钒(VS2)纳米片作为高效超级电容器电极的研究","authors":"Anila Bhuvanendran Nandana, Raghavan Baby Rakhi","doi":"10.1002/ente.202402153","DOIUrl":null,"url":null,"abstract":"<p>Transition metal dichalcogenides (TMDs) emerge as promising electrode materials for next-generation electrochemical energy-storage devices. In the present study, vanadium disulfide (VS<sub>2</sub>), an underexplored TMD, is investigated as an electrode material for supercapacitors. VS<sub>2</sub> nanosheets are synthesized via a single-step hydrothermal method at 220 °C for 24 h. Multiple characterization techniques, including Fourier-transform infrared, Raman spectroscopy, scanning electron microscope–energy dispersive X-ray analysis, and transmission electron microscope, confirm the formation of phase-pure VS<sub>2</sub> nanosheets with a hexagonal structure. The specific surface area, measured using Brunauer–Emmett–Teller analysis, is 12 m<sup>2</sup> g<sup>−1</sup>. A specific capacitance of 106 F g<sup>−1</sup> at a current density of 1 A g<sup>−1</sup> is demonstrated using symmetric supercapacitors fabricated using these VS<sub>2</sub> nanosheets. Using this device, an energy density of 34 Wh kg<sup>−1</sup> at a power density of 800 W kg<sup>−1</sup> is achieved. Moreover, the supercapacitor maintains 94% capacitance retention after 9000 charge–discharge cycles at 5 A g<sup>−1</sup>, highlighting the potential of VS<sub>2</sub> nanosheets as efficient electrode materials for supercapacitor applications.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 5","pages":""},"PeriodicalIF":3.6000,"publicationDate":"2025-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Exploring Vanadium Disulfide (VS2) Nanosheets as High-Efficiency Supercapacitor Electrodes\",\"authors\":\"Anila Bhuvanendran Nandana, Raghavan Baby Rakhi\",\"doi\":\"10.1002/ente.202402153\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Transition metal dichalcogenides (TMDs) emerge as promising electrode materials for next-generation electrochemical energy-storage devices. In the present study, vanadium disulfide (VS<sub>2</sub>), an underexplored TMD, is investigated as an electrode material for supercapacitors. VS<sub>2</sub> nanosheets are synthesized via a single-step hydrothermal method at 220 °C for 24 h. Multiple characterization techniques, including Fourier-transform infrared, Raman spectroscopy, scanning electron microscope–energy dispersive X-ray analysis, and transmission electron microscope, confirm the formation of phase-pure VS<sub>2</sub> nanosheets with a hexagonal structure. The specific surface area, measured using Brunauer–Emmett–Teller analysis, is 12 m<sup>2</sup> g<sup>−1</sup>. A specific capacitance of 106 F g<sup>−1</sup> at a current density of 1 A g<sup>−1</sup> is demonstrated using symmetric supercapacitors fabricated using these VS<sub>2</sub> nanosheets. Using this device, an energy density of 34 Wh kg<sup>−1</sup> at a power density of 800 W kg<sup>−1</sup> is achieved. Moreover, the supercapacitor maintains 94% capacitance retention after 9000 charge–discharge cycles at 5 A g<sup>−1</sup>, highlighting the potential of VS<sub>2</sub> nanosheets as efficient electrode materials for supercapacitor applications.</p>\",\"PeriodicalId\":11573,\"journal\":{\"name\":\"Energy technology\",\"volume\":\"13 5\",\"pages\":\"\"},\"PeriodicalIF\":3.6000,\"publicationDate\":\"2025-01-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Energy technology\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ente.202402153\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Energy technology","FirstCategoryId":"5","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ente.202402153","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Exploring Vanadium Disulfide (VS2) Nanosheets as High-Efficiency Supercapacitor Electrodes
Transition metal dichalcogenides (TMDs) emerge as promising electrode materials for next-generation electrochemical energy-storage devices. In the present study, vanadium disulfide (VS2), an underexplored TMD, is investigated as an electrode material for supercapacitors. VS2 nanosheets are synthesized via a single-step hydrothermal method at 220 °C for 24 h. Multiple characterization techniques, including Fourier-transform infrared, Raman spectroscopy, scanning electron microscope–energy dispersive X-ray analysis, and transmission electron microscope, confirm the formation of phase-pure VS2 nanosheets with a hexagonal structure. The specific surface area, measured using Brunauer–Emmett–Teller analysis, is 12 m2 g−1. A specific capacitance of 106 F g−1 at a current density of 1 A g−1 is demonstrated using symmetric supercapacitors fabricated using these VS2 nanosheets. Using this device, an energy density of 34 Wh kg−1 at a power density of 800 W kg−1 is achieved. Moreover, the supercapacitor maintains 94% capacitance retention after 9000 charge–discharge cycles at 5 A g−1, highlighting the potential of VS2 nanosheets as efficient electrode materials for supercapacitor applications.
期刊介绍:
Energy Technology provides a forum for researchers and engineers from all relevant disciplines concerned with the generation, conversion, storage, and distribution of energy.
This new journal shall publish articles covering all technical aspects of energy process engineering from different perspectives, e.g.,
new concepts of energy generation and conversion;
design, operation, control, and optimization of processes for energy generation (e.g., carbon capture) and conversion of energy carriers;
improvement of existing processes;
combination of single components to systems for energy generation;
design of systems for energy storage;
production processes of fuels, e.g., hydrogen, electricity, petroleum, biobased fuels;
concepts and design of devices for energy distribution.