二硫化钒(VS2)纳米片作为高效超级电容器电极的研究

IF 3.6 4区 工程技术 Q3 ENERGY & FUELS
Anila Bhuvanendran Nandana, Raghavan Baby Rakhi
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引用次数: 0

摘要

过渡金属二硫族化合物(TMDs)是下一代电化学储能装置中很有前途的电极材料。在本研究中,二硫化钒(VS2)是一种尚未开发的TMD,研究其作为超级电容器的电极材料。采用单步水热法制备了VS2纳米片,温度220℃,反应时间24 h。采用傅里叶变换红外、拉曼光谱、扫描电子显微镜-能量色散x射线分析和透射电子显微镜等多种表征技术,证实了具有六边形结构的相纯VS2纳米片的形成。使用brunauer - emmet - teller分析测量的比表面积为12 m2 g−1。利用这些VS2纳米片制成的对称超级电容器,证明了在电流密度为1ag−1时的比电容为106 F g−1。在800w kg−1的功率密度下,可实现34wh kg−1的能量密度。此外,在5a g−1的条件下,该超级电容器在9000次充放电循环后保持94%的电容保持率,突出了VS2纳米片作为超级电容器高效电极材料的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Exploring Vanadium Disulfide (VS2) Nanosheets as High-Efficiency Supercapacitor Electrodes

Exploring Vanadium Disulfide (VS2) Nanosheets as High-Efficiency Supercapacitor Electrodes

Transition metal dichalcogenides (TMDs) emerge as promising electrode materials for next-generation electrochemical energy-storage devices. In the present study, vanadium disulfide (VS2), an underexplored TMD, is investigated as an electrode material for supercapacitors. VS2 nanosheets are synthesized via a single-step hydrothermal method at 220 °C for 24 h. Multiple characterization techniques, including Fourier-transform infrared, Raman spectroscopy, scanning electron microscope–energy dispersive X-ray analysis, and transmission electron microscope, confirm the formation of phase-pure VS2 nanosheets with a hexagonal structure. The specific surface area, measured using Brunauer–Emmett–Teller analysis, is 12 m2 g−1. A specific capacitance of 106 F g−1 at a current density of 1 A g−1 is demonstrated using symmetric supercapacitors fabricated using these VS2 nanosheets. Using this device, an energy density of 34 Wh kg−1 at a power density of 800 W kg−1 is achieved. Moreover, the supercapacitor maintains 94% capacitance retention after 9000 charge–discharge cycles at 5 A g−1, highlighting the potential of VS2 nanosheets as efficient electrode materials for supercapacitor applications.

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来源期刊
Energy technology
Energy technology ENERGY & FUELS-
CiteScore
7.00
自引率
5.30%
发文量
0
审稿时长
1.3 months
期刊介绍: Energy Technology provides a forum for researchers and engineers from all relevant disciplines concerned with the generation, conversion, storage, and distribution of energy. This new journal shall publish articles covering all technical aspects of energy process engineering from different perspectives, e.g., new concepts of energy generation and conversion; design, operation, control, and optimization of processes for energy generation (e.g., carbon capture) and conversion of energy carriers; improvement of existing processes; combination of single components to systems for energy generation; design of systems for energy storage; production processes of fuels, e.g., hydrogen, electricity, petroleum, biobased fuels; concepts and design of devices for energy distribution.
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