稳定磁场下食用银箔的校准自由激光诱导击穿光谱(CF-LIBS)分析

IF 1.4 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES
Saba Mushtaq, Khurram Siraj, Muhammad Shahzad Abdul Rahim, Qaneeta Younas, Breara Muhammad Hussain, Muhammad Qasim, Muhammad Mustafa
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引用次数: 0

摘要

采用磁场(B)负载LIBS对食用银箔进行了初步分析。用Nd-YAG脉冲激光(100 mJ,1064 nm)在B = 0.75 T存在的银箔表面制备银等离子体,通过检测银等离子体中的必需和有毒元素(C、Ag、Al、Fe、Ca、Cr、Si、Mg、Na),分析了LIBS灵敏度的显著增强。在磁场的作用下,光发射强度、等离子体温度(Te)和电子数密度(ne)等参数均得到增强(B)。银等离子体中的信号增强归因于磁约束和放松等离子体后重组率的增加。此外,本研究对热β的值进行了分析估计(βt < 1),证实了磁约束在所有样品中的有效性。采用零场和b场无标定LIBS (CF-LIBS)法测定了样品的元素组成。结果表明,银箔中存在25-35%的铝和0.8-1.08%的铬的欺骗性掺假,最终通过食物链在人体中积累,对人体健康造成高风险
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Analysis of Edible Silver Foils Under Steady Magnetic Field by Calibration Free Laser Induced Breakdown Spectroscopy (CF-LIBS)

The Rudimentary Analysis of Edible Silver foil has been Investigated by a Magnetic Field (B)-supported LIBS. The Silver Plasma was Produced by Employing an Nd-YAG Pulsed Laser (100 mJ,1064 nm,) on the Surface of Silver foil in the Presence of B = 0.75 T, which Analyzed the Significant Enhancement in the LIBS Sensitivity by Detecting the Essential and Toxic Elements (C, Ag, Al, Fe, Ca, Cr, Si, Mg, Na) in Silver Plasma. The Enhancement Factor is up to four-fold and Optical Emission Intensity, Plasma Parameters like Plasma Temperature (Te) and electron Number Density (ne) were Enhanced in the Presence of a Magnetic Field (B). The Signal Enhancement in Silver Plasma was Ascribed to Magnetic Confinement and an Increase in Recombination rate after Relaxing the Plasma. Moreover, the Value of Thermal beta is Estimated Analytically (βt < 1) in this Study, which Confirms the Validity of Magnetic Confinement in all Samples. The Elemental Composition was Determined by the Calibration-Free LIBS (CF-LIBS) Approach with Zero Fields and B-field. The Result Revealed that Silver Foils were Fraudulently Adulterated by 25–35% Aluminum, and 0.8–1.08% Chromium, which Eventually Accumulates in the Human body via the food Chain Leading to high Risks to Human Health

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来源期刊
CiteScore
4.00
自引率
5.90%
发文量
122
审稿时长
>12 weeks
期刊介绍: The aim of this journal is to foster the growth of scientific research among Iranian scientists and to provide a medium which brings the fruits of their research to the attention of the world’s scientific community. The journal publishes original research findings – which may be theoretical, experimental or both - reviews, techniques, and comments spanning all subjects in the field of basic sciences, including Physics, Chemistry, Mathematics, Statistics, Biology and Earth Sciences
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