基于热解、燃烧和火焰蔓延实验的典型保温材料火灾危险性研究

IF 3.1 3区 化学 Q2 POLYMER SCIENCE
Wenlong Zhang, Qingsheng Zhang, Rongkun Pan, Jiangkun Chao, Hui Yu, Yanming Ding
{"title":"基于热解、燃烧和火焰蔓延实验的典型保温材料火灾危险性研究","authors":"Wenlong Zhang,&nbsp;Qingsheng Zhang,&nbsp;Rongkun Pan,&nbsp;Jiangkun Chao,&nbsp;Hui Yu,&nbsp;Yanming Ding","doi":"10.1007/s00289-025-05695-6","DOIUrl":null,"url":null,"abstract":"<div><p>Thermal insulation materials are widely installed in buildings, but they are greatly flammable and have caused many fires. Therefore, it is essential to estimate their fire risk. There are several significant stages in the combustion process of solid combustibles. They will produce gas at the pyrolysis stage. If the concentration of pyrolysis gas is high enough, pyrolysis gas can be burned after mixing with air. Finally, the burning flames spread, causing a large-scale fire. Thus, the combustion characteristics of solid combustibles can be understood through the parameters from multiple stages. The characteristics of expanded polystyrene (EPS) were comprehensively studied using thermogravimetry, cone calorimeter and flame spread experiments, and its fire risk was characterized using the analytic hierarchy process method. The results showed that EPS had stable activation energy during the pyrolysis, ranging from 203 to 235 kJ/mol. Ignition time was short (7–19 s), and peak heat release rate was 102–166 kW/m<sup>2</sup> and smoke production rate (SPR) was 0.06–0.13 m<sup>2</sup>/s. Furthermore, flame spread performance displayed that because of the different flame spread rates of wall fire and pool fire, there were regular fluctuations in flame temperature. The flame height of the pool fire was greater than that of the wall fire. Flame spread rate, flame temperature and SPR had the greatest impact on the fire risk. This study helps to understand fire risk from multiple stages and determine the weight of different factors, so as to take appropriate measures to reduce the fire risk.</p></div>","PeriodicalId":737,"journal":{"name":"Polymer Bulletin","volume":"82 9","pages":"4005 - 4029"},"PeriodicalIF":3.1000,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Study on fire risk of typical thermal insulation materials based on pyrolysis, combustion and flame spread experiments\",\"authors\":\"Wenlong Zhang,&nbsp;Qingsheng Zhang,&nbsp;Rongkun Pan,&nbsp;Jiangkun Chao,&nbsp;Hui Yu,&nbsp;Yanming Ding\",\"doi\":\"10.1007/s00289-025-05695-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Thermal insulation materials are widely installed in buildings, but they are greatly flammable and have caused many fires. Therefore, it is essential to estimate their fire risk. There are several significant stages in the combustion process of solid combustibles. They will produce gas at the pyrolysis stage. If the concentration of pyrolysis gas is high enough, pyrolysis gas can be burned after mixing with air. Finally, the burning flames spread, causing a large-scale fire. Thus, the combustion characteristics of solid combustibles can be understood through the parameters from multiple stages. The characteristics of expanded polystyrene (EPS) were comprehensively studied using thermogravimetry, cone calorimeter and flame spread experiments, and its fire risk was characterized using the analytic hierarchy process method. The results showed that EPS had stable activation energy during the pyrolysis, ranging from 203 to 235 kJ/mol. Ignition time was short (7–19 s), and peak heat release rate was 102–166 kW/m<sup>2</sup> and smoke production rate (SPR) was 0.06–0.13 m<sup>2</sup>/s. Furthermore, flame spread performance displayed that because of the different flame spread rates of wall fire and pool fire, there were regular fluctuations in flame temperature. The flame height of the pool fire was greater than that of the wall fire. Flame spread rate, flame temperature and SPR had the greatest impact on the fire risk. This study helps to understand fire risk from multiple stages and determine the weight of different factors, so as to take appropriate measures to reduce the fire risk.</p></div>\",\"PeriodicalId\":737,\"journal\":{\"name\":\"Polymer Bulletin\",\"volume\":\"82 9\",\"pages\":\"4005 - 4029\"},\"PeriodicalIF\":3.1000,\"publicationDate\":\"2025-03-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Bulletin\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s00289-025-05695-6\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Bulletin","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s00289-025-05695-6","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0

摘要

保温材料广泛应用于建筑中,但其易燃性强,已引起多次火灾。因此,对其火灾风险进行评估是十分必要的。固体可燃物的燃烧过程有几个重要的阶段。它们会在热解阶段产生气体。如果热解气的浓度足够高,热解气与空气混合后即可燃烧。最后,燃烧的火焰蔓延开来,引起了一场大规模的火灾。因此,可以通过多级参数来了解固体可燃物的燃烧特性。采用热重法、锥量热法和火焰蔓延实验对膨胀聚苯乙烯(EPS)的特性进行了全面研究,并采用层次分析法对其火灾危险性进行了表征。结果表明,EPS在热解过程中具有稳定的活化能,在203 ~ 235 kJ/mol之间。点火时间短(7 ~ 19 s),峰值放热速率为102 ~ 166 kW/m2,产烟速率(SPR)为0.06 ~ 0.13 m2/s。此外,火焰蔓延性能表明,由于墙火和池火的火焰蔓延速度不同,火焰温度有规律的波动。池火的火焰高度大于墙火。火焰蔓延速度、火焰温度和SPR对火灾危险性的影响最大。本研究有助于从多个阶段了解火灾风险,确定不同因素的权重,从而采取相应的措施降低火灾风险。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Study on fire risk of typical thermal insulation materials based on pyrolysis, combustion and flame spread experiments

Thermal insulation materials are widely installed in buildings, but they are greatly flammable and have caused many fires. Therefore, it is essential to estimate their fire risk. There are several significant stages in the combustion process of solid combustibles. They will produce gas at the pyrolysis stage. If the concentration of pyrolysis gas is high enough, pyrolysis gas can be burned after mixing with air. Finally, the burning flames spread, causing a large-scale fire. Thus, the combustion characteristics of solid combustibles can be understood through the parameters from multiple stages. The characteristics of expanded polystyrene (EPS) were comprehensively studied using thermogravimetry, cone calorimeter and flame spread experiments, and its fire risk was characterized using the analytic hierarchy process method. The results showed that EPS had stable activation energy during the pyrolysis, ranging from 203 to 235 kJ/mol. Ignition time was short (7–19 s), and peak heat release rate was 102–166 kW/m2 and smoke production rate (SPR) was 0.06–0.13 m2/s. Furthermore, flame spread performance displayed that because of the different flame spread rates of wall fire and pool fire, there were regular fluctuations in flame temperature. The flame height of the pool fire was greater than that of the wall fire. Flame spread rate, flame temperature and SPR had the greatest impact on the fire risk. This study helps to understand fire risk from multiple stages and determine the weight of different factors, so as to take appropriate measures to reduce the fire risk.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Polymer Bulletin
Polymer Bulletin 化学-高分子科学
CiteScore
6.00
自引率
6.20%
发文量
0
审稿时长
5.5 months
期刊介绍: "Polymer Bulletin" is a comprehensive academic journal on polymer science founded in 1988. It was founded under the initiative of the late Mr. Wang Baoren, a famous Chinese chemist and educator. This journal is co-sponsored by the Chinese Chemical Society, the Institute of Chemistry, and the Chinese Academy of Sciences and is supervised by the China Association for Science and Technology. It is a core journal and is publicly distributed at home and abroad. "Polymer Bulletin" is a monthly magazine with multiple columns, including a project application guide, outlook, review, research papers, highlight reviews, polymer education and teaching, information sharing, interviews, polymer science popularization, etc. The journal is included in the CSCD Chinese Science Citation Database. It serves as the source journal for Chinese scientific and technological paper statistics and the source journal of Peking University's "Overview of Chinese Core Journals."
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信