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IF 2.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Organometallics Pub Date : 2025-04-30 DOI:10.1021/acs.organomet.5c0008810.1021/acs.organomet.5c00088

Philipp Schmid, Karin Bartl, Robert Saf, Takahiro Sasamori, Vladimir Ya. Lee* and Frank Uhlig*,

引用次数: 0

摘要

采用新的合成方法制备了稳定的（三烷基硅基）锗（tBuMeRSi）GeH3 (R = Me, tBu)，并对其进行了表征。该方法包括初始制备（三烷基硅基）（对苯基）germanes (tBuMeRSi)Ge（对苯基）H2，其氯酰化生成（三烷基硅基）chlorgermanes (tBuMeRSi)GeClH2，最后与LiAlH4反应生成所需的（三烷基硅基）germanes (tBuMeRSi)GeH3。这些化合物有可能成为制备纳米锗和低聚物的前体，是新一代锗材料的发展前景。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

(Trialkylsilyl)germanes (tBuMeRSi)GeH3 (R = Me, tBu)

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(Trialkylsilyl)germanes (tBuMeRSi)GeH3 (R = Me, tBu)

Stable (trialkylsilyl)germanes (^tBuMeRSi)GeH₃ (R = Me, ^tBu) were prepared, using a novel synthetic approach, and characterized. This approach includes the initial preparation of the (trialkylsilyl)(p-tolyl)germanes (^tBuMeRSi)Ge(p-tolyl)H₂, chlorodearylation of which produced (trialkylsilyl)chlorogermanes (^tBuMeRSi)GeClH₂, which were finally reacted with LiAlH₄ to produce the desired (trialkylsilyl)germanes (^tBuMeRSi)GeH₃. These compounds have the potential to be precursors for the production of germanium nanoparticles and oligomers, as the prospective materials of the new generation.

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来源期刊

Organometallics 化学-无机化学与核化学

CiteScore

5.60

自引率

7.10%

发文量

382

审稿时长

1.7 months

期刊介绍： Organometallics is the flagship journal of organometallic chemistry and records progress in one of the most active fields of science, bridging organic and inorganic chemistry. The journal publishes Articles, Communications, Reviews, and Tutorials (instructional overviews) that depict research on the synthesis, structure, bonding, chemical reactivity, and reaction mechanisms for a variety of applications, including catalyst design and catalytic processes; main-group, transition-metal, and lanthanide and actinide metal chemistry; synthetic aspects of polymer science and materials science; and bioorganometallic chemistry.