陨石金属对印尼富镍匕首的可能贡献:比较原始匕首和新锻造的模拟物

IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS
Franz Brandstätter, Niels J. de Winter, Alessandro Migliori, Roman Padillia-Alvarez, Dan Topa, Seerp Visser, Steven Goderis, Philippe Claeys, Christian Koeberl
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引用次数: 0

摘要

“维也纳世界博物馆”收藏了大量来自印度尼西亚的克里斯匕首。这些物品以其金属叶片而闻名,这些金属叶片由多层组成,经过复杂的锻造过程,包括对各个层的反复折叠和焊接。人们普遍认为,一些克里斯是通过添加陨铁镍制成的,这些陨铁来自于坠落在中爪哇的Prambanan陨石,该陨石自18世纪后期以来就已为人所知。在我们的研究中,我们从这个集合中选择了五个富镍的克里斯,目的是在它们的叶片中识别来自Prambanan或其他铁陨石来源的镍铁。为了更好地了解锻造过程,我们研究了类似于生产原始克里斯的锻造过程所产生的模拟物体,并使用Campo del Cielo和Gibeon陨石中的铁陨石材料作为混合物。这些研究是通过非破坏性分析技术进行的,包括手持式x射线荧光(HH-XRF)分析,扫描电子显微镜(SEM)和电子探针(EMP)分析。采用h - xrf和微x射线荧光(μ-XRF)分析,便携式激光烧蚀(pLA)亚采样和电感耦合等离子体质谱(ICP-MS)分析了原始匕首的微量元素。通过比较两种材料获得的数据,我们证明了在kris匕首中识别陨石成分存在的主要困难是由于(准)非破坏性方法的独家使用,以及由污染、腐蚀和蚀刻特征引起的局部表面异质性。我们还表明,在前现代克里斯匕首中存在大量的Ni和Co(在wt%范围内)并不意味着它是用陨星金属的混合物制造的。我们发现,在调查的五种匕首中,只有一把匕首(no。900382)可能是用Prambanan铁陨石中的镍铁混合物制成的,因为它含有高浓度的亲铁元素,并且具有与陨石相当的Ni/Co比率。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
On the possible contribution of meteoritic metal to Ni-rich Indonesian kris daggers: Comparing original daggers and newly forged analog objects

The “Weltmuseum Wien” owns a large collection of kris daggers from Indonesia. These objects are famous for their metal blades consisting of numerous layers made by a complicated forging process involving repeated folding and welding of the individual layers. There is a widespread belief that some krises were manufactured by adding meteoritic nickel–iron from the Prambanan meteorite that fell in Central Java and is known since the late 18th century. In our study, we investigated a selection of five Ni-rich krises from this collection with the aim to identify in their blades nickel–iron from Prambanan or another iron meteorite source. To obtain a better insight into the forging process, we investigated analog objects that were produced by a forging procedure similar to the one applied in the production of original krises and by using iron meteorite material from the meteorites Campo del Cielo and Gibeon as admixture. These investigations were performed by nondestructive analytical techniques, including handheld X-ray fluorescence (HH-XRF) analysis, scanning electron microscopy (SEM), and electron microprobe (EMP) analysis. The original daggers were investigated by HH-XRF and micro-X-ray fluorescence (μ-XRF) analysis, as well as by portable laser ablation (pLA) subsampling followed by trace element analysis using inductively coupled plasma mass spectrometry (ICP-MS). By comparing the data obtained for both materials, we demonstrate that the main difficulties in identifying the presence of a meteoritic component in the kris daggers are due to the exclusive use of (quasi-)nondestructive methods in combination with locally varying surface heterogeneities, resulting from contamination, corrosion, and etching features. We also show that the presence of significant amounts of Ni and Co (in the wt% range) in a premodern kris dagger does not imply that it was manufactured with an admixture of meteoritic metal. We found that among the five krises investigated, only a single dagger (no. 900382) was manufactured with the possible admixture of nickel–iron from the Prambanan iron meteorite, as it contains high concentrations of siderophile elements and has a Ni/Co ratio comparable to that of the meteorite.

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来源期刊
Meteoritics & Planetary Science
Meteoritics & Planetary Science 地学天文-地球化学与地球物理
CiteScore
3.90
自引率
31.80%
发文量
121
审稿时长
3 months
期刊介绍: First issued in 1953, the journal publishes research articles describing the latest results of new studies, invited reviews of major topics in planetary science, editorials on issues of current interest in the field, and book reviews. The publications are original, not considered for publication elsewhere, and undergo peer-review. The topics include the origin and history of the solar system, planets and natural satellites, interplanetary dust and interstellar medium, lunar samples, meteors, and meteorites, asteroids, comets, craters, and tektites. Our authors and editors are professional scientists representing numerous disciplines, including astronomy, astrophysics, physics, geophysics, chemistry, isotope geochemistry, mineralogy, earth science, geology, and biology. MAPS has subscribers in over 40 countries. Fifty percent of MAPS'' readers are based outside the USA. The journal is available in hard copy and online.
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