Thangapandi Chellapandi , Nandhakumar Eswaramoorthy , N. Dineshbabu , Senthilkumar Nallusamy , Krzysztof Pikon , Mahesh Ganesapillai
{"title":"沸石咪唑酸框架-8微晶降解酸性红27食用染料和四环素药物的光催化剂","authors":"Thangapandi Chellapandi , Nandhakumar Eswaramoorthy , N. Dineshbabu , Senthilkumar Nallusamy , Krzysztof Pikon , Mahesh Ganesapillai","doi":"10.1016/j.vacuum.2025.114397","DOIUrl":null,"url":null,"abstract":"<div><div>The widespread application of azo dyes in the textile and pharmaceutical industries pose a significant threat to environment and health concerns. Addressing these issues require an efficient, cost-effective, and environmentally sustainable approach to mitigate water pollution. In this study, zeolitic imidazolate framework-8 (ZIF-8) was synthesized <em>via</em> a simple, in-situ, solvo-thermal method and evaluated its photocatalytic efficiency in degrading Acid Red 27 (AR27) dye and tetracycline (TC) drug. The synthesized ZIF-8 was comprehensively characterized using various techniques, including SEM, TEM, XPS, FT-IR, XRD, and UV–Vis spectroscopy. Photocatalytic degradation experiments demonstrated that ZIF-8 exhibited remarkable degradation efficiencies of 84.1 % for AR27 and 96.48 % for TC. Kinetic analysis revealed that the degradation of both dye and antibiotic followed a pseudo-first-order reaction model. Hence, ZIF-8 could be a competent photocatalyst for the removal of variety of industrial effluents i.e. organic dyes and pharmaceutical drugs.</div></div>","PeriodicalId":23559,"journal":{"name":"Vacuum","volume":"239 ","pages":"Article 114397"},"PeriodicalIF":3.8000,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Zeolitic imidazolate framework-8 microcrystals as photocatalysts for acid red 27 food dye and tetracycline drug degradation\",\"authors\":\"Thangapandi Chellapandi , Nandhakumar Eswaramoorthy , N. Dineshbabu , Senthilkumar Nallusamy , Krzysztof Pikon , Mahesh Ganesapillai\",\"doi\":\"10.1016/j.vacuum.2025.114397\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The widespread application of azo dyes in the textile and pharmaceutical industries pose a significant threat to environment and health concerns. Addressing these issues require an efficient, cost-effective, and environmentally sustainable approach to mitigate water pollution. In this study, zeolitic imidazolate framework-8 (ZIF-8) was synthesized <em>via</em> a simple, in-situ, solvo-thermal method and evaluated its photocatalytic efficiency in degrading Acid Red 27 (AR27) dye and tetracycline (TC) drug. The synthesized ZIF-8 was comprehensively characterized using various techniques, including SEM, TEM, XPS, FT-IR, XRD, and UV–Vis spectroscopy. Photocatalytic degradation experiments demonstrated that ZIF-8 exhibited remarkable degradation efficiencies of 84.1 % for AR27 and 96.48 % for TC. Kinetic analysis revealed that the degradation of both dye and antibiotic followed a pseudo-first-order reaction model. Hence, ZIF-8 could be a competent photocatalyst for the removal of variety of industrial effluents i.e. organic dyes and pharmaceutical drugs.</div></div>\",\"PeriodicalId\":23559,\"journal\":{\"name\":\"Vacuum\",\"volume\":\"239 \",\"pages\":\"Article 114397\"},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2025-05-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Vacuum\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0042207X25003872\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Vacuum","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0042207X25003872","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Zeolitic imidazolate framework-8 microcrystals as photocatalysts for acid red 27 food dye and tetracycline drug degradation
The widespread application of azo dyes in the textile and pharmaceutical industries pose a significant threat to environment and health concerns. Addressing these issues require an efficient, cost-effective, and environmentally sustainable approach to mitigate water pollution. In this study, zeolitic imidazolate framework-8 (ZIF-8) was synthesized via a simple, in-situ, solvo-thermal method and evaluated its photocatalytic efficiency in degrading Acid Red 27 (AR27) dye and tetracycline (TC) drug. The synthesized ZIF-8 was comprehensively characterized using various techniques, including SEM, TEM, XPS, FT-IR, XRD, and UV–Vis spectroscopy. Photocatalytic degradation experiments demonstrated that ZIF-8 exhibited remarkable degradation efficiencies of 84.1 % for AR27 and 96.48 % for TC. Kinetic analysis revealed that the degradation of both dye and antibiotic followed a pseudo-first-order reaction model. Hence, ZIF-8 could be a competent photocatalyst for the removal of variety of industrial effluents i.e. organic dyes and pharmaceutical drugs.
期刊介绍:
Vacuum is an international rapid publications journal with a focus on short communication. All papers are peer-reviewed, with the review process for short communication geared towards very fast turnaround times. The journal also published full research papers, thematic issues and selected papers from leading conferences.
A report in Vacuum should represent a major advance in an area that involves a controlled environment at pressures of one atmosphere or below.
The scope of the journal includes:
1. Vacuum; original developments in vacuum pumping and instrumentation, vacuum measurement, vacuum gas dynamics, gas-surface interactions, surface treatment for UHV applications and low outgassing, vacuum melting, sintering, and vacuum metrology. Technology and solutions for large-scale facilities (e.g., particle accelerators and fusion devices). New instrumentation ( e.g., detectors and electron microscopes).
2. Plasma science; advances in PVD, CVD, plasma-assisted CVD, ion sources, deposition processes and analysis.
3. Surface science; surface engineering, surface chemistry, surface analysis, crystal growth, ion-surface interactions and etching, nanometer-scale processing, surface modification.
4. Materials science; novel functional or structural materials. Metals, ceramics, and polymers. Experiments, simulations, and modelling for understanding structure-property relationships. Thin films and coatings. Nanostructures and ion implantation.