Near-complete recovery of phosphorus from fresh human urine: Combining magnesium-air fuel cells with modified granular attapulgite

In light of the urge demand for sustainable development and environmental protection, the recovery of phosphorus from source-separated urine holds great significance. This study proposed a novel approach combining magnesium-air fuel cells (MAFC) with modified granular attapulgite (GAT) to recover phosphorus from urine, producing a bulk blending fertilizer and soil amendment. The phosphorus adsorption capacity of GAT was enhanced by more than threefold following modification. The combined process attained a phosphorus recovery efficiency of 99.97 %, with the effluent phosphorus concentration decreased to 0.18 mg L⁻¹, which complies with the discharge standard of pollutants for municipal wastewater treatment plant (GB 18918-2002). In practical implementation, the process effectively treated real urine, yielding artificial phosphate ores (APOs) with a struvite content exceeding 88 % and a phosphate purity over 98 %. The pilot-scale assessment indicated a net benefit of 11.29 $·m⁻³ of urine, demonstrating significant economic feasibility. This work presents an innovative strategy for the efficient recovery of phosphorus from complex wastewater, showcasing its promising potential for practical applications.