NaCl-KCl熔盐体系中低温电化学生产硼化钍的研究

IF 3.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-05-09 DOI:10.1039/D5DT00563A

Tiejian Zhu and Cheng Peng

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引用次数: 0

摘要

采用熔盐电化学方法，在NaCl-KCl-ThF₄-KBF₄体系中，在973 K下合成了硼化钍。形成的硼化物类型受电流密度和B/Th摩尔比的影响。较低的B/Th比有利于ThB₄的形成，较高的B/Th比有利于ThB₆的形成。这种方法为钍化合物合成提供了一种绿色、低温的替代方法，支持可持续的TMSR燃料回收。

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Low-temperature electrochemical production of thorium borides in NaCl-KCl molten salt systems†

Thorium borides were synthesized via molten-salt electrochemistry in a NaCl-KCl-ThF₄-KBF₄ system at 973 K. The type of boride formed is influenced by the current density and B/Th molar ratio. Lower B/Th ratios favor ThB₄, while higher ratios promote ThB₆ formation. This method provides a green, low-temperature alternative for thorium compound synthesis, supporting sustainable TMSR fuel recycling.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.