{"title":"CoFe2O4@Bi2/3Cu3Ti4O12@Graphene复合材料的光学特性及高频(k波段)微波吸收性能","authors":"A. Magaji , M.D. Nurhafizah , D. Basandrai","doi":"10.1016/j.ceramint.2025.01.582","DOIUrl":null,"url":null,"abstract":"<div><div>Electromagnetic pollution has been on the rise due to advancement in electronics. This type of pollution could affect the operation of electronic devices and may causes radiation related disease. The sol-gel auto-combustion method was used to prepare CoFe<sub>2</sub>O<sub>4</sub> and Bi<sub>2/3</sub>Cu<sub>3</sub>Ti<sub>4</sub>O<sub>12</sub> whereas mechanical blending was used to prepare CoFe<sub>2</sub>O<sub>4</sub>@Bi<sub>2/3</sub>Cu<sub>3</sub>Ti<sub>4</sub>O<sub>12</sub>@graphene composite. The XRD analysis affirm the purity of the prepared samples which was later confirmed by FTIR analysis. The presence of Bi<sub>2/3</sub>Cu<sub>3</sub>Ti<sub>4</sub>O<sub>12</sub> and graphene resulted in the reduction of the magnetic interaction which is supported by VSM analysis and the plot of <span><math><mrow><msup><mi>μ</mi><mo>′</mo></msup></mrow></math></span> and <span><math><mrow><msup><mi>μ</mi><mo>″</mo></msup></mrow></math></span>. CoFe<sub>2</sub>O<sub>4</sub>@Bi<sub>2/3</sub>Cu<sub>3</sub>Ti<sub>4</sub>O<sub>12</sub>@graphene composite possesses the lowest value of <span><math><mrow><msub><mi>E</mi><mi>g</mi></msub></mrow></math></span> (3.76 eV). The magnetic parameters of CoFe<sub>2</sub>O<sub>4</sub> tend to decrease with the addition of Bi<sub>2/3</sub>Cu<sub>3</sub>Ti<sub>4</sub>O<sub>12</sub> and graphene. The sample CoFe<sub>2</sub>O<sub>4</sub>@Bi<sub>2/3</sub>Cu<sub>3</sub>Ti<sub>4</sub>O<sub>12</sub>@graphene composite shows the least <span><math><mrow><mi>R</mi><mi>L</mi></mrow></math></span> of <span><math><mrow><mo>−</mo></mrow></math></span> 25.73 dB for an absorber thickness of 2.00 mm at a frequency of 21.59 dB with 3.00 bandwidth of effective absorption. The results demonstrate the possibility of applying CoFe<sub>2</sub>O<sub>4</sub>@Bi<sub>2/3</sub>Cu<sub>3</sub>Ti<sub>4</sub>O<sub>12</sub>@graphene composite as an efficient microwave absorber.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"51 13","pages":"Pages 18056-18072"},"PeriodicalIF":5.1000,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Optical properties and high-frequency (K-band) microwave absorption performance of CoFe2O4@Bi2/3Cu3Ti4O12@Graphene composite\",\"authors\":\"A. Magaji , M.D. Nurhafizah , D. Basandrai\",\"doi\":\"10.1016/j.ceramint.2025.01.582\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Electromagnetic pollution has been on the rise due to advancement in electronics. This type of pollution could affect the operation of electronic devices and may causes radiation related disease. The sol-gel auto-combustion method was used to prepare CoFe<sub>2</sub>O<sub>4</sub> and Bi<sub>2/3</sub>Cu<sub>3</sub>Ti<sub>4</sub>O<sub>12</sub> whereas mechanical blending was used to prepare CoFe<sub>2</sub>O<sub>4</sub>@Bi<sub>2/3</sub>Cu<sub>3</sub>Ti<sub>4</sub>O<sub>12</sub>@graphene composite. The XRD analysis affirm the purity of the prepared samples which was later confirmed by FTIR analysis. The presence of Bi<sub>2/3</sub>Cu<sub>3</sub>Ti<sub>4</sub>O<sub>12</sub> and graphene resulted in the reduction of the magnetic interaction which is supported by VSM analysis and the plot of <span><math><mrow><msup><mi>μ</mi><mo>′</mo></msup></mrow></math></span> and <span><math><mrow><msup><mi>μ</mi><mo>″</mo></msup></mrow></math></span>. CoFe<sub>2</sub>O<sub>4</sub>@Bi<sub>2/3</sub>Cu<sub>3</sub>Ti<sub>4</sub>O<sub>12</sub>@graphene composite possesses the lowest value of <span><math><mrow><msub><mi>E</mi><mi>g</mi></msub></mrow></math></span> (3.76 eV). The magnetic parameters of CoFe<sub>2</sub>O<sub>4</sub> tend to decrease with the addition of Bi<sub>2/3</sub>Cu<sub>3</sub>Ti<sub>4</sub>O<sub>12</sub> and graphene. The sample CoFe<sub>2</sub>O<sub>4</sub>@Bi<sub>2/3</sub>Cu<sub>3</sub>Ti<sub>4</sub>O<sub>12</sub>@graphene composite shows the least <span><math><mrow><mi>R</mi><mi>L</mi></mrow></math></span> of <span><math><mrow><mo>−</mo></mrow></math></span> 25.73 dB for an absorber thickness of 2.00 mm at a frequency of 21.59 dB with 3.00 bandwidth of effective absorption. The results demonstrate the possibility of applying CoFe<sub>2</sub>O<sub>4</sub>@Bi<sub>2/3</sub>Cu<sub>3</sub>Ti<sub>4</sub>O<sub>12</sub>@graphene composite as an efficient microwave absorber.</div></div>\",\"PeriodicalId\":267,\"journal\":{\"name\":\"Ceramics International\",\"volume\":\"51 13\",\"pages\":\"Pages 18056-18072\"},\"PeriodicalIF\":5.1000,\"publicationDate\":\"2025-05-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ceramics International\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S027288422500639X\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ceramics International","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S027288422500639X","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Optical properties and high-frequency (K-band) microwave absorption performance of CoFe2O4@Bi2/3Cu3Ti4O12@Graphene composite
Electromagnetic pollution has been on the rise due to advancement in electronics. This type of pollution could affect the operation of electronic devices and may causes radiation related disease. The sol-gel auto-combustion method was used to prepare CoFe2O4 and Bi2/3Cu3Ti4O12 whereas mechanical blending was used to prepare CoFe2O4@Bi2/3Cu3Ti4O12@graphene composite. The XRD analysis affirm the purity of the prepared samples which was later confirmed by FTIR analysis. The presence of Bi2/3Cu3Ti4O12 and graphene resulted in the reduction of the magnetic interaction which is supported by VSM analysis and the plot of and . CoFe2O4@Bi2/3Cu3Ti4O12@graphene composite possesses the lowest value of (3.76 eV). The magnetic parameters of CoFe2O4 tend to decrease with the addition of Bi2/3Cu3Ti4O12 and graphene. The sample CoFe2O4@Bi2/3Cu3Ti4O12@graphene composite shows the least of 25.73 dB for an absorber thickness of 2.00 mm at a frequency of 21.59 dB with 3.00 bandwidth of effective absorption. The results demonstrate the possibility of applying CoFe2O4@Bi2/3Cu3Ti4O12@graphene composite as an efficient microwave absorber.
期刊介绍:
Ceramics International covers the science of advanced ceramic materials. The journal encourages contributions that demonstrate how an understanding of the basic chemical and physical phenomena may direct materials design and stimulate ideas for new or improved processing techniques, in order to obtain materials with desired structural features and properties.
Ceramics International covers oxide and non-oxide ceramics, functional glasses, glass ceramics, amorphous inorganic non-metallic materials (and their combinations with metal and organic materials), in the form of particulates, dense or porous bodies, thin/thick films and laminated, graded and composite structures. Process related topics such as ceramic-ceramic joints or joining ceramics with dissimilar materials, as well as surface finishing and conditioning are also covered. Besides traditional processing techniques, manufacturing routes of interest include innovative procedures benefiting from externally applied stresses, electromagnetic fields and energetic beams, as well as top-down and self-assembly nanotechnology approaches. In addition, the journal welcomes submissions on bio-inspired and bio-enabled materials designs, experimentally validated multi scale modelling and simulation for materials design, and the use of the most advanced chemical and physical characterization techniques of structure, properties and behaviour.
Technologically relevant low-dimensional systems are a particular focus of Ceramics International. These include 0, 1 and 2-D nanomaterials (also covering CNTs, graphene and related materials, and diamond-like carbons), their nanocomposites, as well as nano-hybrids and hierarchical multifunctional nanostructures that might integrate molecular, biological and electronic components.