晶体硅光伏组件中可恢复和不可恢复的电势诱导降解分流电池的识别

IF 8 2区 材料科学 Q1 ENERGY & FUELS
Ravi Kumar, Rajesh Gupta
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引用次数: 0

摘要

电位诱导降解(PID)是晶体硅(c-Si)光伏(PV)组件中一种严重的降解机制。在p型c-Si光伏组件中,由于钠离子(Na+)的扩散,PID导致负偏置电池相对于接地框架的正面形成分流路径,这种现象称为PID分流(PID-s)。目前已经报道了多种涉及Na+向外扩散的pid回收方法。然而,有些细胞几乎完全恢复,有些细胞则完全没有恢复。在不知道细胞可恢复性的情况下进行PID-s恢复是低效和浪费的;因此,需要一种在恢复之前识别可恢复和不可恢复单元的方法。在这项工作中,提出了一种使用电流分辨电致发光(EL)成像的方法,通过评估其pids的欧姆或非欧姆性质来识别PV组件中的可恢复和不可恢复电池,这取决于Na+离子的浓度。来自三个不同模块的共90个细胞进行了pid的降解和恢复。实验结果表明,在不同的被试细胞中,PID-s的损失和恢复程度不同。分析强调,非欧姆分流器比欧姆分流器表现出更大的恢复潜力,这一发现通过暗锁定热成像(DLIT)得到了进一步验证。此外,所提出的方法定性地提供了对单个细胞恢复潜力的见解,建立了EL成像作为评估pid严重程度和预测恢复的有效工具。这为PV系统中pid诊断和缓解策略的未来发展铺平了道路。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Identification of Recoverable and Non-Recoverable Potential-Induced Degradation-Shunted Cells in Crystalline Silicon Photovoltaic Modules

Potential-induced degradation (PID) is a severe degradation mechanism in crystalline silicon (c-Si) photovoltaic (PV) modules. In p-type c-Si PV modules, PID results in the formation of shunt paths on the front side of negatively biased cells relative to the grounded frame due to the diffusion of sodium ions (Na+), a phenomenon known as PID shunting (PID-s). Various methods for PID-s recovery, which involve the outward diffusion of Na+, have been reported. However, whereas some cells show almost complete recovery, others exhibit no recovery at all. Conducting PID-s recovery without knowing the recoverability of the cells is inefficient and wasteful; therefore, a method to identify recoverable and non-recoverable cells prior to recovery is needed. In this work, a method using current-resolved electroluminescence (EL) imaging is proposed to identify recoverable and non-recoverable cells in a PV module by evaluating their PID-s nature as ohmic or non-ohmic, which depends on the concentration of Na+ ions. A total of 90 cells from three different modules are subjected to PID-s degradation and recovery. The experimental results show varying degrees of PID-s loss and recovery among the tested cells. The analysis highlights that non-ohmic shunts exhibit greater recovery potential than ohmic ones, a finding further verified using dark lock-in thermography (DLIT). Furthermore, the proposed method qualitatively provides insights into the recovery potential of individual cells, establishing EL imaging as an effective tool for assessing PID-s severity and predicting recovery. This paves the way for future advancements in PID-s diagnostics and mitigation strategies within PV systems.

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来源期刊
Progress in Photovoltaics
Progress in Photovoltaics 工程技术-能源与燃料
CiteScore
18.10
自引率
7.50%
发文量
130
审稿时长
5.4 months
期刊介绍: Progress in Photovoltaics offers a prestigious forum for reporting advances in this rapidly developing technology, aiming to reach all interested professionals, researchers and energy policy-makers. The key criterion is that all papers submitted should report substantial “progress” in photovoltaics. Papers are encouraged that report substantial “progress” such as gains in independently certified solar cell efficiency, eligible for a new entry in the journal''s widely referenced Solar Cell Efficiency Tables. Examples of papers that will not be considered for publication are those that report development in materials without relation to data on cell performance, routine analysis, characterisation or modelling of cells or processing sequences, routine reports of system performance, improvements in electronic hardware design, or country programs, although invited papers may occasionally be solicited in these areas to capture accumulated “progress”.
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