Qi Cao , Na Zhao , Chengdong Xia , Zhengjin Zhang , Long Cheng , Dejing Zhou
{"title":"钎焊和人工时效对高强四层层叠铝合金组织和力学性能的影响","authors":"Qi Cao , Na Zhao , Chengdong Xia , Zhengjin Zhang , Long Cheng , Dejing Zhou","doi":"10.1016/j.vacuum.2025.114388","DOIUrl":null,"url":null,"abstract":"<div><div>The lightweight design of power battery thermal management systems remains a critical challenge for new energy vehicles. Conventional aluminum alloys often fail to achieve satisfactory mechanical properties after high-temperature brazing (600 °C). To address this limitation, we developed modified aluminum alloys (6061MOD and 3003MOD) and engineered a four-layer laminar structure (4045/3003MOD/6061MOD/3003MOD) for water-cooled plate applications. The microstructural changes and mechanical behavior of these materials were systematically investigated after high-temperature brazing and subsequent aging treatments. Brazing induced substantial grain growth in the 6061MOD core layer, increasing average grain size from 42.3 μm to 90.1 μm. Optimal mechanical properties were achieved through post-brazing treatment: air cooling followed by 200 °C aging for 2 h. This treatment resulted in a tensile strength of 287.1 MPa and a yield strength of 230.5 MPa, primarily attributed to the fine precipitation of Al-Cu, AlMgSiCu (Q), and Mg<sub>2</sub>Si reinforcing precipitates. Elemental diffusion analysis revealed Mg penetration depths of 63.7 μm (initial brazing) and 81.9 μm (secondary brazing), with the 3003MOD layer effective blocking of Mg diffusion. This laminated structural design, which integrates components with distinct functional properties, provides an innovative strategy for developing lightweight, high-strength brazed materials while offering critical implications for next-generation vehicle thermal management systems.</div></div>","PeriodicalId":23559,"journal":{"name":"Vacuum","volume":"239 ","pages":"Article 114388"},"PeriodicalIF":3.8000,"publicationDate":"2025-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of brazing and artificial aging on the microstructure and mechanical properties of a high-strength four-layer laminar aluminum alloy\",\"authors\":\"Qi Cao , Na Zhao , Chengdong Xia , Zhengjin Zhang , Long Cheng , Dejing Zhou\",\"doi\":\"10.1016/j.vacuum.2025.114388\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The lightweight design of power battery thermal management systems remains a critical challenge for new energy vehicles. Conventional aluminum alloys often fail to achieve satisfactory mechanical properties after high-temperature brazing (600 °C). To address this limitation, we developed modified aluminum alloys (6061MOD and 3003MOD) and engineered a four-layer laminar structure (4045/3003MOD/6061MOD/3003MOD) for water-cooled plate applications. The microstructural changes and mechanical behavior of these materials were systematically investigated after high-temperature brazing and subsequent aging treatments. Brazing induced substantial grain growth in the 6061MOD core layer, increasing average grain size from 42.3 μm to 90.1 μm. Optimal mechanical properties were achieved through post-brazing treatment: air cooling followed by 200 °C aging for 2 h. This treatment resulted in a tensile strength of 287.1 MPa and a yield strength of 230.5 MPa, primarily attributed to the fine precipitation of Al-Cu, AlMgSiCu (Q), and Mg<sub>2</sub>Si reinforcing precipitates. Elemental diffusion analysis revealed Mg penetration depths of 63.7 μm (initial brazing) and 81.9 μm (secondary brazing), with the 3003MOD layer effective blocking of Mg diffusion. This laminated structural design, which integrates components with distinct functional properties, provides an innovative strategy for developing lightweight, high-strength brazed materials while offering critical implications for next-generation vehicle thermal management systems.</div></div>\",\"PeriodicalId\":23559,\"journal\":{\"name\":\"Vacuum\",\"volume\":\"239 \",\"pages\":\"Article 114388\"},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2025-05-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Vacuum\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0042207X25003781\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Vacuum","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0042207X25003781","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Effect of brazing and artificial aging on the microstructure and mechanical properties of a high-strength four-layer laminar aluminum alloy
The lightweight design of power battery thermal management systems remains a critical challenge for new energy vehicles. Conventional aluminum alloys often fail to achieve satisfactory mechanical properties after high-temperature brazing (600 °C). To address this limitation, we developed modified aluminum alloys (6061MOD and 3003MOD) and engineered a four-layer laminar structure (4045/3003MOD/6061MOD/3003MOD) for water-cooled plate applications. The microstructural changes and mechanical behavior of these materials were systematically investigated after high-temperature brazing and subsequent aging treatments. Brazing induced substantial grain growth in the 6061MOD core layer, increasing average grain size from 42.3 μm to 90.1 μm. Optimal mechanical properties were achieved through post-brazing treatment: air cooling followed by 200 °C aging for 2 h. This treatment resulted in a tensile strength of 287.1 MPa and a yield strength of 230.5 MPa, primarily attributed to the fine precipitation of Al-Cu, AlMgSiCu (Q), and Mg2Si reinforcing precipitates. Elemental diffusion analysis revealed Mg penetration depths of 63.7 μm (initial brazing) and 81.9 μm (secondary brazing), with the 3003MOD layer effective blocking of Mg diffusion. This laminated structural design, which integrates components with distinct functional properties, provides an innovative strategy for developing lightweight, high-strength brazed materials while offering critical implications for next-generation vehicle thermal management systems.
期刊介绍:
Vacuum is an international rapid publications journal with a focus on short communication. All papers are peer-reviewed, with the review process for short communication geared towards very fast turnaround times. The journal also published full research papers, thematic issues and selected papers from leading conferences.
A report in Vacuum should represent a major advance in an area that involves a controlled environment at pressures of one atmosphere or below.
The scope of the journal includes:
1. Vacuum; original developments in vacuum pumping and instrumentation, vacuum measurement, vacuum gas dynamics, gas-surface interactions, surface treatment for UHV applications and low outgassing, vacuum melting, sintering, and vacuum metrology. Technology and solutions for large-scale facilities (e.g., particle accelerators and fusion devices). New instrumentation ( e.g., detectors and electron microscopes).
2. Plasma science; advances in PVD, CVD, plasma-assisted CVD, ion sources, deposition processes and analysis.
3. Surface science; surface engineering, surface chemistry, surface analysis, crystal growth, ion-surface interactions and etching, nanometer-scale processing, surface modification.
4. Materials science; novel functional or structural materials. Metals, ceramics, and polymers. Experiments, simulations, and modelling for understanding structure-property relationships. Thin films and coatings. Nanostructures and ion implantation.