{"title":"pbtca改性自交联壳聚糖凝胶对废水中铀的高效电吸附","authors":"Shengxing Yang, Chunpei Yan, Bin Huang, Tianxiang Jin, Dingge Guo, Minnan Xiao, Yong Qian","doi":"10.1016/j.desal.2025.118984","DOIUrl":null,"url":null,"abstract":"<div><div>Nuclear energy is an essential part of the global energy mix, and its sustainable development relies on efficient and selective uranium extraction technologies. This study presents a 2-phosphonate butane 1, 2, 4-tricarboxylic acid (PBTCA)-modified self-crosslinked chitosan gel as a novel adsorbent for uranium extraction from wastewater. At an optimized voltage of −0.6 V, the material exhibited an impressive adsorption capacity of 631.94 mg·g<sup>−1</sup>, along with excellent electrochemical performance and cycling stability. This innovative material, characterized by low energy consumption, high adsorption efficiency, and excellent regeneration capability, provides a promising solution for uranium recovery. This work highlights the potential of targeted chemical modifications in enhancing polymer-based electrosorption technologies.</div></div>","PeriodicalId":299,"journal":{"name":"Desalination","volume":"612 ","pages":"Article 118984"},"PeriodicalIF":8.3000,"publicationDate":"2025-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"PBTCA-modified self-crosslinked chitosan gels for efficient electrosorption of uranium from wastewater\",\"authors\":\"Shengxing Yang, Chunpei Yan, Bin Huang, Tianxiang Jin, Dingge Guo, Minnan Xiao, Yong Qian\",\"doi\":\"10.1016/j.desal.2025.118984\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Nuclear energy is an essential part of the global energy mix, and its sustainable development relies on efficient and selective uranium extraction technologies. This study presents a 2-phosphonate butane 1, 2, 4-tricarboxylic acid (PBTCA)-modified self-crosslinked chitosan gel as a novel adsorbent for uranium extraction from wastewater. At an optimized voltage of −0.6 V, the material exhibited an impressive adsorption capacity of 631.94 mg·g<sup>−1</sup>, along with excellent electrochemical performance and cycling stability. This innovative material, characterized by low energy consumption, high adsorption efficiency, and excellent regeneration capability, provides a promising solution for uranium recovery. This work highlights the potential of targeted chemical modifications in enhancing polymer-based electrosorption technologies.</div></div>\",\"PeriodicalId\":299,\"journal\":{\"name\":\"Desalination\",\"volume\":\"612 \",\"pages\":\"Article 118984\"},\"PeriodicalIF\":8.3000,\"publicationDate\":\"2025-05-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Desalination\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S001191642500459X\",\"RegionNum\":1,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Desalination","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S001191642500459X","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
PBTCA-modified self-crosslinked chitosan gels for efficient electrosorption of uranium from wastewater
Nuclear energy is an essential part of the global energy mix, and its sustainable development relies on efficient and selective uranium extraction technologies. This study presents a 2-phosphonate butane 1, 2, 4-tricarboxylic acid (PBTCA)-modified self-crosslinked chitosan gel as a novel adsorbent for uranium extraction from wastewater. At an optimized voltage of −0.6 V, the material exhibited an impressive adsorption capacity of 631.94 mg·g−1, along with excellent electrochemical performance and cycling stability. This innovative material, characterized by low energy consumption, high adsorption efficiency, and excellent regeneration capability, provides a promising solution for uranium recovery. This work highlights the potential of targeted chemical modifications in enhancing polymer-based electrosorption technologies.
期刊介绍:
Desalination is a scholarly journal that focuses on the field of desalination materials, processes, and associated technologies. It encompasses a wide range of disciplines and aims to publish exceptional papers in this area.
The journal invites submissions that explicitly revolve around water desalting and its applications to various sources such as seawater, groundwater, and wastewater. It particularly encourages research on diverse desalination methods including thermal, membrane, sorption, and hybrid processes.
By providing a platform for innovative studies, Desalination aims to advance the understanding and development of desalination technologies, promoting sustainable solutions for water scarcity challenges.