Dr.-Ing. Ronny Tobias Zimmermann, Prof. Dr.-Ing. habil. Kai Sundmacher
{"title":"核壳催化转化器颗粒:灵活负载的固定床反应堆运行的蛋黄?核壳催化剂颗粒:装载柔性反应堆操作的蛋黄?","authors":"Dr.-Ing. Ronny Tobias Zimmermann, Prof. Dr.-Ing. habil. Kai Sundmacher","doi":"10.1002/cite.202400141","DOIUrl":null,"url":null,"abstract":"<p>In the Power-to-X concept, wall-cooled fixed-bed tubular reactors will take on a central role in carrying out exothermic, heterogeneously catalyzed reactions. In order to achieve high product yields without overheating the reactors, effective heat management is required, especially for load-flexible operation. One solution for this is the use of core-shell catalyst pellets. In core-shell catalyst pellets, the catalytically active material is separated from the gas bulk by an inert shell (e.g. ‘egg white’ or ‘egg yolk’ pellets). The advantages and disadvantages of this concept are discussed in this article on the basis of analytical equations as well as experimental results on the laboratory and pilot scales, and compared with other concepts.</p>","PeriodicalId":9912,"journal":{"name":"Chemie Ingenieur Technik","volume":"97 5","pages":"411-420"},"PeriodicalIF":1.6000,"publicationDate":"2025-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cite.202400141","citationCount":"0","resultStr":"{\"title\":\"Kern-Schale-Katalysatorpellets: Das Gelbe vom Ei für den lastflexiblen Festbett-Reaktorbetrieb?\\n Core-Shell Catalyst Pellets: The Egg Yolk for Load-Flexible Reactor Operation?\",\"authors\":\"Dr.-Ing. Ronny Tobias Zimmermann, Prof. Dr.-Ing. habil. Kai Sundmacher\",\"doi\":\"10.1002/cite.202400141\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In the Power-to-X concept, wall-cooled fixed-bed tubular reactors will take on a central role in carrying out exothermic, heterogeneously catalyzed reactions. In order to achieve high product yields without overheating the reactors, effective heat management is required, especially for load-flexible operation. One solution for this is the use of core-shell catalyst pellets. In core-shell catalyst pellets, the catalytically active material is separated from the gas bulk by an inert shell (e.g. ‘egg white’ or ‘egg yolk’ pellets). The advantages and disadvantages of this concept are discussed in this article on the basis of analytical equations as well as experimental results on the laboratory and pilot scales, and compared with other concepts.</p>\",\"PeriodicalId\":9912,\"journal\":{\"name\":\"Chemie Ingenieur Technik\",\"volume\":\"97 5\",\"pages\":\"411-420\"},\"PeriodicalIF\":1.6000,\"publicationDate\":\"2025-03-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cite.202400141\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemie Ingenieur Technik\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/cite.202400141\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemie Ingenieur Technik","FirstCategoryId":"5","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/cite.202400141","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Kern-Schale-Katalysatorpellets: Das Gelbe vom Ei für den lastflexiblen Festbett-Reaktorbetrieb?
Core-Shell Catalyst Pellets: The Egg Yolk for Load-Flexible Reactor Operation?
In the Power-to-X concept, wall-cooled fixed-bed tubular reactors will take on a central role in carrying out exothermic, heterogeneously catalyzed reactions. In order to achieve high product yields without overheating the reactors, effective heat management is required, especially for load-flexible operation. One solution for this is the use of core-shell catalyst pellets. In core-shell catalyst pellets, the catalytically active material is separated from the gas bulk by an inert shell (e.g. ‘egg white’ or ‘egg yolk’ pellets). The advantages and disadvantages of this concept are discussed in this article on the basis of analytical equations as well as experimental results on the laboratory and pilot scales, and compared with other concepts.
期刊介绍:
Die Chemie Ingenieur Technik ist die wohl angesehenste deutschsprachige Zeitschrift für Verfahrensingenieure, technische Chemiker, Apparatebauer und Biotechnologen. Als Fachorgan von DECHEMA, GDCh und VDI-GVC gilt sie als das unverzichtbare Forum für den Erfahrungsaustausch zwischen Forschern und Anwendern aus Industrie, Forschung und Entwicklung. Wissenschaftlicher Fortschritt und Praxisnähe: Eine Kombination, die es nur in der CIT gibt!