pd催化1,1-二取代末端烯烃与甲酸芳基酯的氢酯化反应

IF 2.5 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

New Journal of Chemistry Pub Date : 2025-03-24 DOI:10.1039/D5NJ00149H

Junhua Li, Yaqian Min, Tianci Shen, Yan Yang, Fengyin Wang and Yian Shi

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引用次数: 0

摘要

多种1,1-二取代末端烯烃可以与Pd(OAc)2-DPEphos和甲酸芳基酯进行高效的氢酯化反应，得到相应的含各种官能团的羧酸酯，收率高。该反应过程操作简单，不需要处理有毒CO气体或强酸。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Pd-catalyzed hydroesterification of 1,1-disubstituted terminal olefins with aryl formates†

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Pd-catalyzed hydroesterification of 1,1-disubstituted terminal olefins with aryl formates†

A variety of 1,1-disubstituted terminal olefins can be efficiently hydroesterified with Pd(OAc)₂-DPEphos and aryl formates to give the corresponding carboxylic esters bearing various functional groups in good yields. The reaction process is operationally simple and requires no handling of toxic CO gas or strong acid.

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