{"title":"面向未来移动出行的新一代玻璃体复合材料:平衡可持续性和功能性——展望","authors":"Jinhyeok Kang , Changwoo Nam","doi":"10.1016/j.eurpolymj.2025.113967","DOIUrl":null,"url":null,"abstract":"<div><div>Vitrimer composites have been identified as a class of promising materials for future mobility applications, offering a unique balance between sustainability and functionality. These materials incorporate dynamic covalent bonds (DCBs), which enable recyclability, self-healing, and reprocessability while preserving the intrinsic mechanical, thermal and chemical properties of conventional thermosets. This review provides a systematic analysis of vitrimer composites, with a particular focus on their structural design, the influence of fillers on DCB dynamics, and their impact on key functional properties. Specifically, the study examines how network architecture, including cross-linking density and polymer-filler interactions, governs the viscoelastic behavior and reprocessability of vitrimer composites. Furthermore, the discussion addresses the role of epoxy, polyurethane, polyimide, and polybenzoxazine matrix in vitrimer composites, highlighting their mechanical strength, heat resistance, and electromagnetic interference shielding, all of which are critical for next-generation mobility technologies.</div></div>","PeriodicalId":315,"journal":{"name":"European Polymer Journal","volume":"233 ","pages":"Article 113967"},"PeriodicalIF":5.8000,"publicationDate":"2025-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Next-generation vitrimer composites for future mobility: Balancing sustainability and functionality – A perspective\",\"authors\":\"Jinhyeok Kang , Changwoo Nam\",\"doi\":\"10.1016/j.eurpolymj.2025.113967\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Vitrimer composites have been identified as a class of promising materials for future mobility applications, offering a unique balance between sustainability and functionality. These materials incorporate dynamic covalent bonds (DCBs), which enable recyclability, self-healing, and reprocessability while preserving the intrinsic mechanical, thermal and chemical properties of conventional thermosets. This review provides a systematic analysis of vitrimer composites, with a particular focus on their structural design, the influence of fillers on DCB dynamics, and their impact on key functional properties. Specifically, the study examines how network architecture, including cross-linking density and polymer-filler interactions, governs the viscoelastic behavior and reprocessability of vitrimer composites. Furthermore, the discussion addresses the role of epoxy, polyurethane, polyimide, and polybenzoxazine matrix in vitrimer composites, highlighting their mechanical strength, heat resistance, and electromagnetic interference shielding, all of which are critical for next-generation mobility technologies.</div></div>\",\"PeriodicalId\":315,\"journal\":{\"name\":\"European Polymer Journal\",\"volume\":\"233 \",\"pages\":\"Article 113967\"},\"PeriodicalIF\":5.8000,\"publicationDate\":\"2025-05-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"European Polymer Journal\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0014305725002551\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Polymer Journal","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0014305725002551","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Next-generation vitrimer composites for future mobility: Balancing sustainability and functionality – A perspective
Vitrimer composites have been identified as a class of promising materials for future mobility applications, offering a unique balance between sustainability and functionality. These materials incorporate dynamic covalent bonds (DCBs), which enable recyclability, self-healing, and reprocessability while preserving the intrinsic mechanical, thermal and chemical properties of conventional thermosets. This review provides a systematic analysis of vitrimer composites, with a particular focus on their structural design, the influence of fillers on DCB dynamics, and their impact on key functional properties. Specifically, the study examines how network architecture, including cross-linking density and polymer-filler interactions, governs the viscoelastic behavior and reprocessability of vitrimer composites. Furthermore, the discussion addresses the role of epoxy, polyurethane, polyimide, and polybenzoxazine matrix in vitrimer composites, highlighting their mechanical strength, heat resistance, and electromagnetic interference shielding, all of which are critical for next-generation mobility technologies.
期刊介绍:
European Polymer Journal is dedicated to publishing work on fundamental and applied polymer chemistry and macromolecular materials. The journal covers all aspects of polymer synthesis, including polymerization mechanisms and chemical functional transformations, with a focus on novel polymers and the relationships between molecular structure and polymer properties. In addition, we welcome submissions on bio-based or renewable polymers, stimuli-responsive systems and polymer bio-hybrids. European Polymer Journal also publishes research on the biomedical application of polymers, including drug delivery and regenerative medicine. The main scope is covered but not limited to the following core research areas:
Polymer synthesis and functionalization
• Novel synthetic routes for polymerization, functional modification, controlled/living polymerization and precision polymers.
Stimuli-responsive polymers
• Including shape memory and self-healing polymers.
Supramolecular polymers and self-assembly
• Molecular recognition and higher order polymer structures.
Renewable and sustainable polymers
• Bio-based, biodegradable and anti-microbial polymers and polymeric bio-nanocomposites.
Polymers at interfaces and surfaces
• Chemistry and engineering of surfaces with biological relevance, including patterning, antifouling polymers and polymers for membrane applications.
Biomedical applications and nanomedicine
• Polymers for regenerative medicine, drug delivery molecular release and gene therapy
The scope of European Polymer Journal no longer includes Polymer Physics.