风成沙负载氧化镧纳米粒子高效去除水中磷酸盐

IF 3.8 3区 工程技术 Q3 ENERGY & FUELS
Shu-Hao Zhou , Zhen Jin , Qian-Xi Li , Chen-Xin Ding , Jie Li , Wei Song , Yu-Ru Sun
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引用次数: 0

摘要

采用水热法制备了氧化镧纳米粒子修饰风成砂(LOAS)去除水中磷酸盐的复合材料。通过控制镧、聚乙二醇的用量和生长周期,获得了最佳的制备条件。XRD、SEM和TEM研究结果表明,氧化镧纳米颗粒在风沙表面形成了无序的层状结构。吸附动力学分析表明,Elovich动力学模型与实验数据吻合较好,在180 min内吸附率达到80%。71.383 mg P/g为预期吸附量,Freundlich模型与吸附等温线更为吻合。利用FT-IR和XPS研究了LOAS对磷酸盐的吸附过程,结果表明LOAS对初始pH值和共存阴离子不敏感,吸附效率在80%以上。结果表明,磷酸吸附的主要过程是静电相互作用和配体交换。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Highly efficient phosphate removal from water with lanthanum oxide nanoparticles loaded on aeolian sand

Highly efficient phosphate removal from water with lanthanum oxide nanoparticles loaded on aeolian sand
A composite material, lanthanum oxide nanoparticles modified aeolian sand (LOAS), for phosphate removal from water was prepared by hydrothermal method. The optimum preparation conditions were obtained by controlling the amount of lanthanum and polyethylene glycol, and the growth period. The results of XRD, SEM and TEM studies showed that the lanthanum oxide nanoparticles formed a disordered layered structure on the surface of the aeolian sand. The adsorption rate reached 80 % in 180 min, according to the adsorption kinetic analysis, which demonstrated that the Elovich kinetic model fit the experimental data well. 71.383 mg P/g was the anticipated adsorption capability, and the Freundlich model was more closely matched by the adsorption isotherm. FT-IR and XPS were used to study the adsorption process of phosphate, and LOAS was insensitive to the initial pH or coexisting anions, adsorption efficiency is above 80 %. The findings demonstrated that the primary processes of phosphate adsorption were electrostatic interactions and ligand exchange.
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来源期刊
CiteScore
7.80
自引率
9.30%
发文量
408
审稿时长
49 days
期刊介绍: Chemical Engineering and Processing: Process Intensification is intended for practicing researchers in industry and academia, working in the field of Process Engineering and related to the subject of Process Intensification.Articles published in the Journal demonstrate how novel discoveries, developments and theories in the field of Process Engineering and in particular Process Intensification may be used for analysis and design of innovative equipment and processing methods with substantially improved sustainability, efficiency and environmental performance.
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