Shu-Hao Zhou , Zhen Jin , Qian-Xi Li , Chen-Xin Ding , Jie Li , Wei Song , Yu-Ru Sun
{"title":"风成沙负载氧化镧纳米粒子高效去除水中磷酸盐","authors":"Shu-Hao Zhou , Zhen Jin , Qian-Xi Li , Chen-Xin Ding , Jie Li , Wei Song , Yu-Ru Sun","doi":"10.1016/j.cep.2025.110334","DOIUrl":null,"url":null,"abstract":"<div><div>A composite material, lanthanum oxide nanoparticles modified aeolian sand (LOAS), for phosphate removal from water was prepared by hydrothermal method. The optimum preparation conditions were obtained by controlling the amount of lanthanum and polyethylene glycol, and the growth period. The results of XRD, SEM and TEM studies showed that the lanthanum oxide nanoparticles formed a disordered layered structure on the surface of the aeolian sand. The adsorption rate reached 80 % in 180 min, according to the adsorption kinetic analysis, which demonstrated that the Elovich kinetic model fit the experimental data well. 71.383 mg P/g was the anticipated adsorption capability, and the Freundlich model was more closely matched by the adsorption isotherm. FT-IR and XPS were used to study the adsorption process of phosphate, and LOAS was insensitive to the initial pH or coexisting anions, adsorption efficiency is above 80 %. The findings demonstrated that the primary processes of phosphate adsorption were electrostatic interactions and ligand exchange.</div></div>","PeriodicalId":9929,"journal":{"name":"Chemical Engineering and Processing - Process Intensification","volume":"214 ","pages":"Article 110334"},"PeriodicalIF":3.8000,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Highly efficient phosphate removal from water with lanthanum oxide nanoparticles loaded on aeolian sand\",\"authors\":\"Shu-Hao Zhou , Zhen Jin , Qian-Xi Li , Chen-Xin Ding , Jie Li , Wei Song , Yu-Ru Sun\",\"doi\":\"10.1016/j.cep.2025.110334\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A composite material, lanthanum oxide nanoparticles modified aeolian sand (LOAS), for phosphate removal from water was prepared by hydrothermal method. The optimum preparation conditions were obtained by controlling the amount of lanthanum and polyethylene glycol, and the growth period. The results of XRD, SEM and TEM studies showed that the lanthanum oxide nanoparticles formed a disordered layered structure on the surface of the aeolian sand. The adsorption rate reached 80 % in 180 min, according to the adsorption kinetic analysis, which demonstrated that the Elovich kinetic model fit the experimental data well. 71.383 mg P/g was the anticipated adsorption capability, and the Freundlich model was more closely matched by the adsorption isotherm. FT-IR and XPS were used to study the adsorption process of phosphate, and LOAS was insensitive to the initial pH or coexisting anions, adsorption efficiency is above 80 %. The findings demonstrated that the primary processes of phosphate adsorption were electrostatic interactions and ligand exchange.</div></div>\",\"PeriodicalId\":9929,\"journal\":{\"name\":\"Chemical Engineering and Processing - Process Intensification\",\"volume\":\"214 \",\"pages\":\"Article 110334\"},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2025-04-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Engineering and Processing - Process Intensification\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0255270125001837\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Engineering and Processing - Process Intensification","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0255270125001837","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Highly efficient phosphate removal from water with lanthanum oxide nanoparticles loaded on aeolian sand
A composite material, lanthanum oxide nanoparticles modified aeolian sand (LOAS), for phosphate removal from water was prepared by hydrothermal method. The optimum preparation conditions were obtained by controlling the amount of lanthanum and polyethylene glycol, and the growth period. The results of XRD, SEM and TEM studies showed that the lanthanum oxide nanoparticles formed a disordered layered structure on the surface of the aeolian sand. The adsorption rate reached 80 % in 180 min, according to the adsorption kinetic analysis, which demonstrated that the Elovich kinetic model fit the experimental data well. 71.383 mg P/g was the anticipated adsorption capability, and the Freundlich model was more closely matched by the adsorption isotherm. FT-IR and XPS were used to study the adsorption process of phosphate, and LOAS was insensitive to the initial pH or coexisting anions, adsorption efficiency is above 80 %. The findings demonstrated that the primary processes of phosphate adsorption were electrostatic interactions and ligand exchange.
期刊介绍:
Chemical Engineering and Processing: Process Intensification is intended for practicing researchers in industry and academia, working in the field of Process Engineering and related to the subject of Process Intensification.Articles published in the Journal demonstrate how novel discoveries, developments and theories in the field of Process Engineering and in particular Process Intensification may be used for analysis and design of innovative equipment and processing methods with substantially improved sustainability, efficiency and environmental performance.