Thomas Ojonugwa Daniel, Raphael Ananwude Chikwenze, Benneth Igwe, John Ubi Arikpo
{"title":"椰壳-长春花壳生物复合材料交替保温性能的研究","authors":"Thomas Ojonugwa Daniel, Raphael Ananwude Chikwenze, Benneth Igwe, John Ubi Arikpo","doi":"10.1007/s11356-025-36435-y","DOIUrl":null,"url":null,"abstract":"<div><p>Periwinkle and coconut shells are becoming increasingly popular as dielectric materials with thermal insulation properties. Natural sources of synthesis could provide a cheaper and more ecologically friendly alternative to chemically synthesizing such compounds as thermal insulators or fillers in polymer composites. The utilization of a fine powder made from periwinkle shell and coconut shell composites as an alternative filler for composite materials and as a thermal insulation material was investigated in this study. Cleaning, oven drying, and milling of the components resulted in bio composite powder particles. X-ray fluorescence, scanning electron microscopy (SEM), X-ray diffraction (XRD), and thermal conductivity measurements were used to characterize the powders. CaO is the most abundant metallic oxide in the powder, accounting for 81.8 wt %, according to XRF. For coconut shell, periwinkle shell, and coconut-periwinkle shell composite materials, the average grain size from SEM examination is 4.88 µm, 6.37 µm, and 11.04 µm respectively. The creation of a polycrystalline film can be seen in the XRD patterns of periwinkle shell powder and composites of periwinkle and coconut shell powders, but the XRD pattern of coconut shell is amorphous. The thermal conductance of the composite material is 21.18 Wm<sup>−1</sup> k<sup>−1</sup>, which is higher than TiO<sub>2</sub> and SiO<sub>2</sub>, which are often employed as fillers in polymeric materials insulation. This shows that, in comparison to polymer composites containing TiO<sub>2</sub> and SiO<sub>2</sub>, the composite material could yield insulating materials with improved thermal conductivity characteristics, enhancing the growing waste to wealth concept.\n</p></div>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":"32 19","pages":"12121 - 12132"},"PeriodicalIF":5.8000,"publicationDate":"2025-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Investigation of coconut-periwinkle shell bio-composites for alternate thermal insulation application\",\"authors\":\"Thomas Ojonugwa Daniel, Raphael Ananwude Chikwenze, Benneth Igwe, John Ubi Arikpo\",\"doi\":\"10.1007/s11356-025-36435-y\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Periwinkle and coconut shells are becoming increasingly popular as dielectric materials with thermal insulation properties. Natural sources of synthesis could provide a cheaper and more ecologically friendly alternative to chemically synthesizing such compounds as thermal insulators or fillers in polymer composites. The utilization of a fine powder made from periwinkle shell and coconut shell composites as an alternative filler for composite materials and as a thermal insulation material was investigated in this study. Cleaning, oven drying, and milling of the components resulted in bio composite powder particles. X-ray fluorescence, scanning electron microscopy (SEM), X-ray diffraction (XRD), and thermal conductivity measurements were used to characterize the powders. CaO is the most abundant metallic oxide in the powder, accounting for 81.8 wt %, according to XRF. For coconut shell, periwinkle shell, and coconut-periwinkle shell composite materials, the average grain size from SEM examination is 4.88 µm, 6.37 µm, and 11.04 µm respectively. The creation of a polycrystalline film can be seen in the XRD patterns of periwinkle shell powder and composites of periwinkle and coconut shell powders, but the XRD pattern of coconut shell is amorphous. The thermal conductance of the composite material is 21.18 Wm<sup>−1</sup> k<sup>−1</sup>, which is higher than TiO<sub>2</sub> and SiO<sub>2</sub>, which are often employed as fillers in polymeric materials insulation. This shows that, in comparison to polymer composites containing TiO<sub>2</sub> and SiO<sub>2</sub>, the composite material could yield insulating materials with improved thermal conductivity characteristics, enhancing the growing waste to wealth concept.\\n</p></div>\",\"PeriodicalId\":545,\"journal\":{\"name\":\"Environmental Science and Pollution Research\",\"volume\":\"32 19\",\"pages\":\"12121 - 12132\"},\"PeriodicalIF\":5.8000,\"publicationDate\":\"2025-04-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Environmental Science and Pollution Research\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11356-025-36435-y\",\"RegionNum\":3,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"0\",\"JCRName\":\"ENVIRONMENTAL SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Science and Pollution Research","FirstCategoryId":"93","ListUrlMain":"https://link.springer.com/article/10.1007/s11356-025-36435-y","RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"0","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
Investigation of coconut-periwinkle shell bio-composites for alternate thermal insulation application
Periwinkle and coconut shells are becoming increasingly popular as dielectric materials with thermal insulation properties. Natural sources of synthesis could provide a cheaper and more ecologically friendly alternative to chemically synthesizing such compounds as thermal insulators or fillers in polymer composites. The utilization of a fine powder made from periwinkle shell and coconut shell composites as an alternative filler for composite materials and as a thermal insulation material was investigated in this study. Cleaning, oven drying, and milling of the components resulted in bio composite powder particles. X-ray fluorescence, scanning electron microscopy (SEM), X-ray diffraction (XRD), and thermal conductivity measurements were used to characterize the powders. CaO is the most abundant metallic oxide in the powder, accounting for 81.8 wt %, according to XRF. For coconut shell, periwinkle shell, and coconut-periwinkle shell composite materials, the average grain size from SEM examination is 4.88 µm, 6.37 µm, and 11.04 µm respectively. The creation of a polycrystalline film can be seen in the XRD patterns of periwinkle shell powder and composites of periwinkle and coconut shell powders, but the XRD pattern of coconut shell is amorphous. The thermal conductance of the composite material is 21.18 Wm−1 k−1, which is higher than TiO2 and SiO2, which are often employed as fillers in polymeric materials insulation. This shows that, in comparison to polymer composites containing TiO2 and SiO2, the composite material could yield insulating materials with improved thermal conductivity characteristics, enhancing the growing waste to wealth concept.
期刊介绍:
Environmental Science and Pollution Research (ESPR) serves the international community in all areas of Environmental Science and related subjects with emphasis on chemical compounds. This includes:
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