A. Madhankumar , J. Joel , P. Jeyapandiarajan , P. Ashwath , M. Anthony Xavior
{"title":"氮化硼增强氧化铝陶瓷复合材料的合成与表征","authors":"A. Madhankumar , J. Joel , P. Jeyapandiarajan , P. Ashwath , M. Anthony Xavior","doi":"10.1016/j.diamond.2025.112396","DOIUrl":null,"url":null,"abstract":"<div><div>Alumina-based composites (Al<sub>2</sub>O<sub>3</sub>) exhibit excellent mechanical and electrical properties. Incorporation of boron nitride (BN) further enhances these attributes, making them suitable for aerospace and automotive applications. The improved mechanical strength of these composites at high temperatures is a key attribute. The addition of BN significantly improves the heat resistance of alumina ceramics, making them well-suited for engine components and cutting tools that operate under extreme conditions. Beyond their mechanical benefits, Al<sub>2</sub>O<sub>3</sub>-BN composites excel as electrical insulators, with BN enhancing the material's resistance to electrical conductivity, making them a preferred choice for high-voltage and insulation applications. Ongoing research underscores the potential of these materials in future technological advancements. Experimental investigations show that varying BN content between 0 and 1 wt% results in mechanical property changes. These are supported by experimental stress-strain curves included in the results section. These composites, compacted via hydraulic pressing and sintered in an argon atmosphere at 1600 °C for 4 h, exhibit density improvements from 98.6 % to 99.3 % as BN concentration increases. The optimal BN content of 0.5 wt% yields peak performance, achieving a flexural strength of 424 MPa (an improvement of 3.41 %) and fracture resistance of 6.3 MPa·m<sup>1</sup>/<sup>2</sup> (a 34.04 % enhancement). Additionally, Al<sub>2</sub>O<sub>3</sub>-BN composites demonstrate impressive wear resistance and reduced friction. A BN content of 0.25 wt% lowers wear rates and reduces the coefficient of friction (COF) by 46.11 % at room temperature and 61.30 % at elevated temperatures. To maintain these advantages, it is crucial to keep the BN content below 0.5 wt%, ensuring the optimal balance of mechanical, thermal, and tribological properties for high-performance applications.</div></div>","PeriodicalId":11266,"journal":{"name":"Diamond and Related Materials","volume":"156 ","pages":"Article 112396"},"PeriodicalIF":4.3000,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and characterization of boron nitride reinforced alumina ceramic composites\",\"authors\":\"A. Madhankumar , J. Joel , P. Jeyapandiarajan , P. Ashwath , M. Anthony Xavior\",\"doi\":\"10.1016/j.diamond.2025.112396\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Alumina-based composites (Al<sub>2</sub>O<sub>3</sub>) exhibit excellent mechanical and electrical properties. Incorporation of boron nitride (BN) further enhances these attributes, making them suitable for aerospace and automotive applications. The improved mechanical strength of these composites at high temperatures is a key attribute. The addition of BN significantly improves the heat resistance of alumina ceramics, making them well-suited for engine components and cutting tools that operate under extreme conditions. Beyond their mechanical benefits, Al<sub>2</sub>O<sub>3</sub>-BN composites excel as electrical insulators, with BN enhancing the material's resistance to electrical conductivity, making them a preferred choice for high-voltage and insulation applications. Ongoing research underscores the potential of these materials in future technological advancements. Experimental investigations show that varying BN content between 0 and 1 wt% results in mechanical property changes. These are supported by experimental stress-strain curves included in the results section. These composites, compacted via hydraulic pressing and sintered in an argon atmosphere at 1600 °C for 4 h, exhibit density improvements from 98.6 % to 99.3 % as BN concentration increases. The optimal BN content of 0.5 wt% yields peak performance, achieving a flexural strength of 424 MPa (an improvement of 3.41 %) and fracture resistance of 6.3 MPa·m<sup>1</sup>/<sup>2</sup> (a 34.04 % enhancement). Additionally, Al<sub>2</sub>O<sub>3</sub>-BN composites demonstrate impressive wear resistance and reduced friction. A BN content of 0.25 wt% lowers wear rates and reduces the coefficient of friction (COF) by 46.11 % at room temperature and 61.30 % at elevated temperatures. To maintain these advantages, it is crucial to keep the BN content below 0.5 wt%, ensuring the optimal balance of mechanical, thermal, and tribological properties for high-performance applications.</div></div>\",\"PeriodicalId\":11266,\"journal\":{\"name\":\"Diamond and Related Materials\",\"volume\":\"156 \",\"pages\":\"Article 112396\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2025-05-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Diamond and Related Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0925963525004534\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, COATINGS & FILMS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Diamond and Related Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0925963525004534","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, COATINGS & FILMS","Score":null,"Total":0}
Synthesis and characterization of boron nitride reinforced alumina ceramic composites
Alumina-based composites (Al2O3) exhibit excellent mechanical and electrical properties. Incorporation of boron nitride (BN) further enhances these attributes, making them suitable for aerospace and automotive applications. The improved mechanical strength of these composites at high temperatures is a key attribute. The addition of BN significantly improves the heat resistance of alumina ceramics, making them well-suited for engine components and cutting tools that operate under extreme conditions. Beyond their mechanical benefits, Al2O3-BN composites excel as electrical insulators, with BN enhancing the material's resistance to electrical conductivity, making them a preferred choice for high-voltage and insulation applications. Ongoing research underscores the potential of these materials in future technological advancements. Experimental investigations show that varying BN content between 0 and 1 wt% results in mechanical property changes. These are supported by experimental stress-strain curves included in the results section. These composites, compacted via hydraulic pressing and sintered in an argon atmosphere at 1600 °C for 4 h, exhibit density improvements from 98.6 % to 99.3 % as BN concentration increases. The optimal BN content of 0.5 wt% yields peak performance, achieving a flexural strength of 424 MPa (an improvement of 3.41 %) and fracture resistance of 6.3 MPa·m1/2 (a 34.04 % enhancement). Additionally, Al2O3-BN composites demonstrate impressive wear resistance and reduced friction. A BN content of 0.25 wt% lowers wear rates and reduces the coefficient of friction (COF) by 46.11 % at room temperature and 61.30 % at elevated temperatures. To maintain these advantages, it is crucial to keep the BN content below 0.5 wt%, ensuring the optimal balance of mechanical, thermal, and tribological properties for high-performance applications.
期刊介绍:
DRM is a leading international journal that publishes new fundamental and applied research on all forms of diamond, the integration of diamond with other advanced materials and development of technologies exploiting diamond. The synthesis, characterization and processing of single crystal diamond, polycrystalline films, nanodiamond powders and heterostructures with other advanced materials are encouraged topics for technical and review articles. In addition to diamond, the journal publishes manuscripts on the synthesis, characterization and application of other related materials including diamond-like carbons, carbon nanotubes, graphene, and boron and carbon nitrides. Articles are sought on the chemical functionalization of diamond and related materials as well as their use in electrochemistry, energy storage and conversion, chemical and biological sensing, imaging, thermal management, photonic and quantum applications, electron emission and electronic devices.
The International Conference on Diamond and Carbon Materials has evolved into the largest and most well attended forum in the field of diamond, providing a forum to showcase the latest results in the science and technology of diamond and other carbon materials such as carbon nanotubes, graphene, and diamond-like carbon. Run annually in association with Diamond and Related Materials the conference provides junior and established researchers the opportunity to exchange the latest results ranging from fundamental physical and chemical concepts to applied research focusing on the next generation carbon-based devices.