剪切力诱导aba型三嵌段共聚物固相转变的原位研究

IF 4.7 3区 材料科学 Q2 CHEMISTRY, PHYSICAL
Jun Wang , Haofeng Sun , Zhijing Han , Mengjia Dou , Haitao Hu , He Cheng , Chunyong He , Zhenhua Xie , Hanqiu Jiang , Naisheng Jiang , Xin Tong , Yubin Ke , Hua Yang
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引用次数: 0

摘要

嵌段共聚物在外力作用下的自组装与相行为的相互作用是材料科学的重要研究方向之一。流变小角中子散射(Rheo-SANS)是一种强大的原位工具,使研究这一问题成为可能。本文介绍了在中国散裂中子源(CSNS)的小角中子散射束线(BL01)上,与Anton-Paar MCR 302e流变仪一起安装和调试Rheo-SANS仪器的情况。我们提供了Rheo-SANS仪器的设计,结构和技术规格的详细描述。利用这个新建的Rheo-SANS设备,我们能够研究嵌段共聚物在外力作用下的相变行为,这是传统表征方法无法实现的。我们通过Rheo-SANS实验证明,对于小填充参数的嵌段共聚物(Pluronic F127),剪切力可以使Hcp相在固体状态下取向。当系统处于类液体状态时,剪切力几乎没有导向作用。相反,对于填充参数较大的嵌段共聚物(Pluronic L64),剪切力在类液状态下容易引起片层相的取向,而在类固状态下,则需要较大的剪切力来诱导片层相的取向。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

In-situ investigation of shear force induced solution phase transformation of ABA-type tri-block copolymers

In-situ investigation of shear force induced solution phase transformation of ABA-type tri-block copolymers
Interplay between self-assembly and phase behaviors for block copolymer under external force is one of the significant research directions in materials science. Rheo-small-angle neutron scattering (Rheo-SANS) is a powerful in situ tool that enables the investigation of this subject. Herein, we present the installation and commissioning of the Rheo-SANS instrument, in conjunction with an Anton-Paar MCR 302e rheometer, at the small-angle neutron scattering beamline (BL01) of the China Spallation Neutron Source (CSNS). We provide a detailed description of the design, construction and technical specifications of the Rheo-SANS instrument. Taking advantage of this newly built Rheo-SANS facility, we are able to investigate the phase transformation behavior of block copolymer under external shear force, which is otherwise impossible for traditional characterization methods. We demonstrate through Rheo-SANS experiment that for block copolymer with small packing parameter (Pluronic F127), shear force can cause orientation of the Hcp phase in solid-like state. While in liquid-like state, shear force hardly orients the system. On the contrary, for block copolymer with large packing parameter (Pluronic L64), shear force can easily cause orientation of the lamella phase in liquid-like state, while in solid-like state, much large shear force is needed to induce the orientation of the lamella phase.
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来源期刊
Colloid and Interface Science Communications
Colloid and Interface Science Communications Materials Science-Materials Chemistry
CiteScore
9.40
自引率
6.70%
发文量
125
审稿时长
43 days
期刊介绍: Colloid and Interface Science Communications provides a forum for the highest visibility and rapid publication of short initial reports on new fundamental concepts, research findings, and topical applications at the forefront of the increasingly interdisciplinary area of colloid and interface science.
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