Sion Kim , Kamal Asghar , Miguta Faustine Ngulimi , Bum Kyoung Seo , Changhyun Roh
{"title":"1,3-二乙基-2-硫脲对碳钢SA 106 GR.B的缓蚀性能","authors":"Sion Kim , Kamal Asghar , Miguta Faustine Ngulimi , Bum Kyoung Seo , Changhyun Roh","doi":"10.1016/j.mlblux.2025.100242","DOIUrl":null,"url":null,"abstract":"<div><div>The corrosion inhibition efficiency of 1,3-diethyl-2-thiourea (DETU) was evaluated in the inorganic-based Hydrazine-Based Reductive Ion Decontamination (HyBRID) solution under actual decontamination temperature conditions. The results showed that adding 0.01 wt% DETU reduced the corrosion depth and rate of carbon steel by ∼30 % (from 9.89 to 6.90 µm and 3.29 to 2.30 µm/h, respectively), and the dissolved iron concentration by ∼27 % (from 193.35 to 140.35 ppm). This inhibition effect is attributed to the strong adsorption of DETU on the carbon steel surface, forming a protective layer. These results suggest that DETU is an effective corrosion inhibitor for structural materials in pressurized heavy water reactors (PHWR) using inorganic acid-based chemical decontamination.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"25 ","pages":"Article 100242"},"PeriodicalIF":2.2000,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"1,3-Diethyl-2-Thiourea as a corrosion inhibitor for carbon steel SA 106 GR.B\",\"authors\":\"Sion Kim , Kamal Asghar , Miguta Faustine Ngulimi , Bum Kyoung Seo , Changhyun Roh\",\"doi\":\"10.1016/j.mlblux.2025.100242\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The corrosion inhibition efficiency of 1,3-diethyl-2-thiourea (DETU) was evaluated in the inorganic-based Hydrazine-Based Reductive Ion Decontamination (HyBRID) solution under actual decontamination temperature conditions. The results showed that adding 0.01 wt% DETU reduced the corrosion depth and rate of carbon steel by ∼30 % (from 9.89 to 6.90 µm and 3.29 to 2.30 µm/h, respectively), and the dissolved iron concentration by ∼27 % (from 193.35 to 140.35 ppm). This inhibition effect is attributed to the strong adsorption of DETU on the carbon steel surface, forming a protective layer. These results suggest that DETU is an effective corrosion inhibitor for structural materials in pressurized heavy water reactors (PHWR) using inorganic acid-based chemical decontamination.</div></div>\",\"PeriodicalId\":18245,\"journal\":{\"name\":\"Materials Letters: X\",\"volume\":\"25 \",\"pages\":\"Article 100242\"},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2025-05-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Letters: X\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2590150825000055\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Letters: X","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2590150825000055","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
1,3-Diethyl-2-Thiourea as a corrosion inhibitor for carbon steel SA 106 GR.B
The corrosion inhibition efficiency of 1,3-diethyl-2-thiourea (DETU) was evaluated in the inorganic-based Hydrazine-Based Reductive Ion Decontamination (HyBRID) solution under actual decontamination temperature conditions. The results showed that adding 0.01 wt% DETU reduced the corrosion depth and rate of carbon steel by ∼30 % (from 9.89 to 6.90 µm and 3.29 to 2.30 µm/h, respectively), and the dissolved iron concentration by ∼27 % (from 193.35 to 140.35 ppm). This inhibition effect is attributed to the strong adsorption of DETU on the carbon steel surface, forming a protective layer. These results suggest that DETU is an effective corrosion inhibitor for structural materials in pressurized heavy water reactors (PHWR) using inorganic acid-based chemical decontamination.