Shuangwu Xu , Le Zhao , Zheting Liu , Huapeng Sun , Dan Sun , Zhiguang Peng , Yougen Tang , Wenyao Wang , Haiyan Wang
{"title":"六方氮化硼填料提高了钠金属电池用聚合物固态电解质的电化学性能","authors":"Shuangwu Xu , Le Zhao , Zheting Liu , Huapeng Sun , Dan Sun , Zhiguang Peng , Yougen Tang , Wenyao Wang , Haiyan Wang","doi":"10.1039/d5cc01608h","DOIUrl":null,"url":null,"abstract":"<div><div>In order to improve the electrochemical performance of PVDF-HFP solid-state electrolytes, we introduced hexagonal-BN into the PVDF-HFP polymer matrix. The strong interaction of hexagonal-BN on TFSI<sup>−</sup> promotes the dissociation of sodium salts and restricts the movement of TFSI<sup>−</sup>, which improves the Na<sup>+</sup> transference number and the interfacial stability of solid-state electrolytes.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"61 43","pages":"Pages 7887-7890"},"PeriodicalIF":4.2000,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A hexagonal-BN filler boosts the electrochemical performance of polymeric solid-state electrolytes for sodium–metal batteries†\",\"authors\":\"Shuangwu Xu , Le Zhao , Zheting Liu , Huapeng Sun , Dan Sun , Zhiguang Peng , Yougen Tang , Wenyao Wang , Haiyan Wang\",\"doi\":\"10.1039/d5cc01608h\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In order to improve the electrochemical performance of PVDF-HFP solid-state electrolytes, we introduced hexagonal-BN into the PVDF-HFP polymer matrix. The strong interaction of hexagonal-BN on TFSI<sup>−</sup> promotes the dissociation of sodium salts and restricts the movement of TFSI<sup>−</sup>, which improves the Na<sup>+</sup> transference number and the interfacial stability of solid-state electrolytes.</div></div>\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"61 43\",\"pages\":\"Pages 7887-7890\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2025-05-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1359734525008742\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734525008742","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
A hexagonal-BN filler boosts the electrochemical performance of polymeric solid-state electrolytes for sodium–metal batteries†
In order to improve the electrochemical performance of PVDF-HFP solid-state electrolytes, we introduced hexagonal-BN into the PVDF-HFP polymer matrix. The strong interaction of hexagonal-BN on TFSI− promotes the dissociation of sodium salts and restricts the movement of TFSI−, which improves the Na+ transference number and the interfacial stability of solid-state electrolytes.
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.