{"title":"CB/SiO2纳米填充氟碳/环氧树脂共混涂料的制备及其耐腐蚀、耐冰性能","authors":"Jingjing Wang, Changquan Li, Xing Shen, Fuhao Liang, Alidad Amirfazli","doi":"10.1007/s11998-024-01024-0","DOIUrl":null,"url":null,"abstract":"<div><p>To prepare coatings with excellent abrasion and strong corrosion resistance, we have taken advantage of the stable physicochemical properties of epoxy resin and its high compatibility with other substances to improve the fluorocarbon surface due to the low surface reactivity caused by the C–F bonding by a simple polymer blending method. The prepared CB/SiO<sub>2</sub>-FEVE/EP nanocomposite coatings contain abundant C–F bonds and reactive O–H and epoxy groups, significantly improving the coating’s durable anticorrosive properties. The changes of polymer blending on the coating properties were observed by scanning electron microscopy, durability, Tafel, and electrochemical and self-cleaning tests on the experimental samples. The findings demonstrate that the coated surface characterized by SEM at FEVE: EP = 1:1 has superior interfacial compatibility and outstanding long-term corrosion prevention and self-cleaning qualities compared to the pure FEVE/EP coating. The Tafel and EIS fitting data demonstrate that the CB/SiO<sub>2</sub>-FEVE/EP coating has a corrosion current density approximately three orders of magnitude lower than the aluminum sheet, and the former has exceptional corrosion resistance. The CB/SiO<sub>2</sub>-FEVE/EP coatings prepared from FEVE: EP = 1:1 blends are of significant research value in solving the increasing corrosion cost problem in various industries.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"22 3","pages":"971 - 984"},"PeriodicalIF":2.3000,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The preparation of CB/SiO2 nano-filled fluorocarbon/epoxy resin blend coating and its durable anticorrosion and anti-ice properties\",\"authors\":\"Jingjing Wang, Changquan Li, Xing Shen, Fuhao Liang, Alidad Amirfazli\",\"doi\":\"10.1007/s11998-024-01024-0\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>To prepare coatings with excellent abrasion and strong corrosion resistance, we have taken advantage of the stable physicochemical properties of epoxy resin and its high compatibility with other substances to improve the fluorocarbon surface due to the low surface reactivity caused by the C–F bonding by a simple polymer blending method. The prepared CB/SiO<sub>2</sub>-FEVE/EP nanocomposite coatings contain abundant C–F bonds and reactive O–H and epoxy groups, significantly improving the coating’s durable anticorrosive properties. The changes of polymer blending on the coating properties were observed by scanning electron microscopy, durability, Tafel, and electrochemical and self-cleaning tests on the experimental samples. The findings demonstrate that the coated surface characterized by SEM at FEVE: EP = 1:1 has superior interfacial compatibility and outstanding long-term corrosion prevention and self-cleaning qualities compared to the pure FEVE/EP coating. The Tafel and EIS fitting data demonstrate that the CB/SiO<sub>2</sub>-FEVE/EP coating has a corrosion current density approximately three orders of magnitude lower than the aluminum sheet, and the former has exceptional corrosion resistance. The CB/SiO<sub>2</sub>-FEVE/EP coatings prepared from FEVE: EP = 1:1 blends are of significant research value in solving the increasing corrosion cost problem in various industries.</p></div>\",\"PeriodicalId\":619,\"journal\":{\"name\":\"Journal of Coatings Technology and Research\",\"volume\":\"22 3\",\"pages\":\"971 - 984\"},\"PeriodicalIF\":2.3000,\"publicationDate\":\"2024-12-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Coatings Technology and Research\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11998-024-01024-0\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Coatings Technology and Research","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s11998-024-01024-0","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0
摘要
为了制备具有优异耐磨性和强耐腐蚀性的涂料,我们利用环氧树脂稳定的物理化学性质和与其他物质的高相容性,通过简单的聚合物共混方法改善了碳氟化合物表面C-F键合导致的低表面反应性。制备的CB/SiO2-FEVE/EP纳米复合涂层含有丰富的C-F键、活性O-H和环氧基,显著提高了涂层的耐腐蚀性能。通过扫描电镜、耐久性能、Tafel性能、电化学性能和自洁性能等测试,观察聚合物共混对涂层性能的影响。研究结果表明,与纯FEVE/EP涂层相比,FEVE: EP = 1:1时的涂层表面具有更好的界面相容性和良好的长期防腐和自清洁性能。Tafel和EIS拟合数据表明,CB/SiO2-FEVE/EP涂层的腐蚀电流密度比铝板低约3个数量级,前者具有优异的耐腐蚀性。FEVE: EP = 1:1共混物制备的CB/SiO2-FEVE/EP涂层对解决各行业日益增长的腐蚀成本问题具有重要的研究价值。
The preparation of CB/SiO2 nano-filled fluorocarbon/epoxy resin blend coating and its durable anticorrosion and anti-ice properties
To prepare coatings with excellent abrasion and strong corrosion resistance, we have taken advantage of the stable physicochemical properties of epoxy resin and its high compatibility with other substances to improve the fluorocarbon surface due to the low surface reactivity caused by the C–F bonding by a simple polymer blending method. The prepared CB/SiO2-FEVE/EP nanocomposite coatings contain abundant C–F bonds and reactive O–H and epoxy groups, significantly improving the coating’s durable anticorrosive properties. The changes of polymer blending on the coating properties were observed by scanning electron microscopy, durability, Tafel, and electrochemical and self-cleaning tests on the experimental samples. The findings demonstrate that the coated surface characterized by SEM at FEVE: EP = 1:1 has superior interfacial compatibility and outstanding long-term corrosion prevention and self-cleaning qualities compared to the pure FEVE/EP coating. The Tafel and EIS fitting data demonstrate that the CB/SiO2-FEVE/EP coating has a corrosion current density approximately three orders of magnitude lower than the aluminum sheet, and the former has exceptional corrosion resistance. The CB/SiO2-FEVE/EP coatings prepared from FEVE: EP = 1:1 blends are of significant research value in solving the increasing corrosion cost problem in various industries.
期刊介绍:
Journal of Coatings Technology and Research (JCTR) is a forum for the exchange of research, experience, knowledge and ideas among those with a professional interest in the science, technology and manufacture of functional, protective and decorative coatings including paints, inks and related coatings and their raw materials, and similar topics.