Performance investigation of cutoff wall and permeable reactive barriers at a landfill: Multiscale experiments and numerical analyses

Environmental issues from waste management require reliable remediation techniques to prevent groundwater and soil pollution. Cut-off walls and permeable reactive barriers (PRBs) have been widely used for the control and remediation of groundwater pollution. However, the performance of the newly modified barrier materials and site remediation was not well explored. Therefore, in-depth and comparative analyses of 2 % carboxymethyl cellulose (CMC)-modified bentonite and 2 % unmodified sodium bentonite used in vertical barriers are required. Curtain and high-pressure jet grouting composed of CMC-modified bentonite were investigated in a field scale. Additionally, laboratory experiments were conducted to examine the permeability and adsorption properties of the PRB comprised of natural zeolite. The performances of vertical barriers and the PRB were compared by a three-dimensional numerical simulation based on the hydrogeological characteristics of a municipal solid waste landfill (MSWL) in southeastern China. The hydraulic conductivities of CMC-modified bentonite barriers could range from 21.9 %-50.5 % of those of unmodified sodium bentonite barriers, and could be as low as 1.02 × 10^-8 cm/s. Contaminant fluxes through the cut-off wall and PRB were 38.67 % and 44.97 % of that without protection after 10 years in the polluted stratum. It was indicated that the removal rate of NH₃-N can be 52.30 % at the 10th year by using PRBs. These results demonstrated the long-term performance of CMC-modified bentonite vertical barriers combined with PRBs is quite good at landfills or contaminated sites.