含硫试剂与α-三氟甲基烯烃的可见光加成反应

IF 3.3 2区化学 Q1 CHEMISTRY, ORGANIC

Journal of Organic Chemistry Pub Date : 2025-04-22 DOI:10.1021/acs.joc.5c0039610.1021/acs.joc.5c00396

Yi-Rong Chen, Jia-Hui Han, Weidong Rao, Ping Song*, Shu-su Shen, Daopeng Sheng and Shun-Yi Wang*,

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引用次数: 0

摘要

本文描述了含硫试剂（亚硫酸钠、二硫代磺酸钠）与α-三氟甲基烯烃在可见光下的加成反应。通过可见光诱导的亚硫酸钠与α-三氟甲基烯烃自由基加成反应，从溶剂中获得质子，合成了一系列三氟甲基磺酸盐。通过α-三氟甲基烯烃与二硫代磺酸盐的可见光双官能化反应，合成了一系列二硫代磺酸衍生物。该策略具有反应条件温和、底物通用性好、收率高、可达99%的优点。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Visible-Light-Mediated Addition Reactions of Sulfur-Containing Reagents with α-Trifluoromethyl Alkenes

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Visible-Light-Mediated Addition Reactions of Sulfur-Containing Reagents with α-Trifluoromethyl Alkenes

Herein, we described the addition reactions of sulfur-containing reagents (sodium sulfinates, dithiosulfonates) with α-trifluoromethyl alkenes under visible light. A series of trifluoromethyl sulfonates were synthesized via the visible-light-induced radical addition reaction of sodium sulfinates and α-trifluoromethyl alkenes to obtain protons from the solvent. A series of dithiosulfonated derivatives were synthesized via visible-light-induced bifunctionalization reaction of α-trifluoromethyl alkenes with dithiosulfonates.This strategy has the advantages of mild reaction conditions, good substrate universality and high yield up to 99% yield.

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来源期刊

Journal of Organic Chemistry 化学-有机化学

CiteScore

6.20

自引率

11.10%

发文量

1467

审稿时长

2 months

期刊介绍： Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.