富磺酸盐金属-有机骨架的孔隙空间划分及其净化天然气甲烷的研究

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-05-01 DOI:10.1039/d5cc01014d

Chaozhuang Xue, Hui Peng, Jinle Hou, Konggang Qu

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引用次数: 0

摘要

通过在富含磺酸盐的acs型金属有机骨架（MOF）上实施孔隙空间划分（PSP）策略，我们开发了一种新的pacs结构，其特征是具有丰富的O/N相互作用位点的分段孔隙。该结构以高选择性和高容量从C2H6/C3H8/CH4三元混合物中选择性地吸附C2H6和C3H8，实现了一次吸附对天然气中CH4的有效净化。

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Pore Space Partition on Sulfonate-rich Metal-Organic Framework for Purification of Methane from Natural Gas

By implementing the pore space partition (PSP) strategy on a sulfonate-rich acs-type metal-organic framework (MOF), we developed a new pacs structure, which features segmented pores with abundant O/N interacting sites. This structure selective uptake C2H6 and C3H8 from ternary mixture of C2H6/C3H8/CH4 with high selectivity and capacity, enabling effective purification of CH4 from natural gas through one adsorption process.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.