{"title":"垂直管道注入乙二醇对水合物堵塞的去除效果研究","authors":"Zhen-Bin Xu, Xiao-Hui Wang, Yi-Wei Wu, Yu-Hao Bu, Yu-Zhou Chen, Ling-Ban Wang, Hong-Shuai Wang, Chang-Yu Sun, Guang-Jin Chen","doi":"10.1016/j.ces.2025.121770","DOIUrl":null,"url":null,"abstract":"<div><div>Hydrate blockages threaten the safe transportation of deep-sea pipelines. Limited by flow loop scale, generating sufficient hydrate blockages for removal studies in lab is challenging. This study proposed a novel method to prepare solid hydrate blockages by separating hydrate crystals from residual gas–liquid mixtures via high-pressure filtration. The effects of ethylene glycol (EG) concentration, temperature, volume, and soak time on hydrate decomposition were systematically examined. Results show that increasing EG concentration from 5 wt% to 50 wt% enhances decomposition by 415 %, though EG efficiency declines at higher concentrations. Raising the temperature from 30 °C to 80 °C increases gas decomposition by 182 %, with peak thermal efficiency at 50 °C. Increasing injection volume from 50 mL to 170 mL boosts dissociation by 406 %. Injecting EG solution causes the decomposition of hydrate plugs, resulting in the increase of pressure in the pipeline, with a maximum increase of 1.31 MPa. Soak time correlates positively with EG concentration, but longer soak time reduce the average decomposition rate. These dissociation characteristics are crucial for the flow assurance of oil and natural gas.</div></div>","PeriodicalId":271,"journal":{"name":"Chemical Engineering Science","volume":"313 ","pages":"Article 121770"},"PeriodicalIF":4.1000,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Study on the removal efficiency of hydrate blockage by injection ethylene glycol in vertical pipeline\",\"authors\":\"Zhen-Bin Xu, Xiao-Hui Wang, Yi-Wei Wu, Yu-Hao Bu, Yu-Zhou Chen, Ling-Ban Wang, Hong-Shuai Wang, Chang-Yu Sun, Guang-Jin Chen\",\"doi\":\"10.1016/j.ces.2025.121770\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Hydrate blockages threaten the safe transportation of deep-sea pipelines. Limited by flow loop scale, generating sufficient hydrate blockages for removal studies in lab is challenging. This study proposed a novel method to prepare solid hydrate blockages by separating hydrate crystals from residual gas–liquid mixtures via high-pressure filtration. The effects of ethylene glycol (EG) concentration, temperature, volume, and soak time on hydrate decomposition were systematically examined. Results show that increasing EG concentration from 5 wt% to 50 wt% enhances decomposition by 415 %, though EG efficiency declines at higher concentrations. Raising the temperature from 30 °C to 80 °C increases gas decomposition by 182 %, with peak thermal efficiency at 50 °C. Increasing injection volume from 50 mL to 170 mL boosts dissociation by 406 %. Injecting EG solution causes the decomposition of hydrate plugs, resulting in the increase of pressure in the pipeline, with a maximum increase of 1.31 MPa. Soak time correlates positively with EG concentration, but longer soak time reduce the average decomposition rate. These dissociation characteristics are crucial for the flow assurance of oil and natural gas.</div></div>\",\"PeriodicalId\":271,\"journal\":{\"name\":\"Chemical Engineering Science\",\"volume\":\"313 \",\"pages\":\"Article 121770\"},\"PeriodicalIF\":4.1000,\"publicationDate\":\"2025-04-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Engineering Science\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0009250925005937\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Engineering Science","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0009250925005937","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Study on the removal efficiency of hydrate blockage by injection ethylene glycol in vertical pipeline
Hydrate blockages threaten the safe transportation of deep-sea pipelines. Limited by flow loop scale, generating sufficient hydrate blockages for removal studies in lab is challenging. This study proposed a novel method to prepare solid hydrate blockages by separating hydrate crystals from residual gas–liquid mixtures via high-pressure filtration. The effects of ethylene glycol (EG) concentration, temperature, volume, and soak time on hydrate decomposition were systematically examined. Results show that increasing EG concentration from 5 wt% to 50 wt% enhances decomposition by 415 %, though EG efficiency declines at higher concentrations. Raising the temperature from 30 °C to 80 °C increases gas decomposition by 182 %, with peak thermal efficiency at 50 °C. Increasing injection volume from 50 mL to 170 mL boosts dissociation by 406 %. Injecting EG solution causes the decomposition of hydrate plugs, resulting in the increase of pressure in the pipeline, with a maximum increase of 1.31 MPa. Soak time correlates positively with EG concentration, but longer soak time reduce the average decomposition rate. These dissociation characteristics are crucial for the flow assurance of oil and natural gas.
期刊介绍:
Chemical engineering enables the transformation of natural resources and energy into useful products for society. It draws on and applies natural sciences, mathematics and economics, and has developed fundamental engineering science that underpins the discipline.
Chemical Engineering Science (CES) has been publishing papers on the fundamentals of chemical engineering since 1951. CES is the platform where the most significant advances in the discipline have ever since been published. Chemical Engineering Science has accompanied and sustained chemical engineering through its development into the vibrant and broad scientific discipline it is today.