碱性介质中网状聚吡咯- nabio2纳米复合材料电催化析氧增强反应

IF 1.8 4区 材料科学 Q2 MATERIALS SCIENCE, CERAMICS
Munirah D. Albaqami, Muhammad Imran Anwar, Saikh Mohammad, Abdul Ghafoor Abid, Shahroz Saleem
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引用次数: 0

摘要

当涉及到水分解过程产生氢气的能力时,水氧化反应(WOR)的挑战性动力学提供了一个实质性的障碍。因此,为了在水电解过程中启动氢气和氧气的生产,需要高效的催化剂。在此,我们报道了NaBiO2@PPy纳米复合材料能够在碱性介质中进行析氧反应(OER)的发展。制备的NaBiO2@PPy纳米复合材料及其个体通过各种技术进行表征,以确定结构,元素,质地和形态特征。该材料在227 mV的低过电位下可产生10 mA/cm2的析氧电流密度,并可保持长达50 h的稳定性。此外,制备的NaBiO2@PPy纳米复合材料的塔非斜率也较小,为30.8 mV/dec。因此,这种催化材料将是一个很好的选择,以创造一个成本效益高,环保碱性介质。为了提高水电解的性能,这项工作为未来的应用提供了一种革命性的设计材料和电极制造方法。图形抽象
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Enhanced electrocatalytic oxygen evolution reaction of network structured Polypyrrole-NaBiO2 nanocomposite in alkaline media

When it comes to the ability of the water splitting process to create hydrogen, the challenging dynamics of the water-oxidation reaction (WOR) provide a substantial impediment. So, in order to start both hydrogen and oxygen production during water electrolysis, efficient catalysts are needed. Herein, we report the development of NaBiO2@PPy nanocomposite capable of oxygen evolution reactions (OER) in alkaline medium. The fabricated NaBiO2@PPy nanocomposite and its individuals are characterized via various techniques to confirm the structural, elemental, textural, and morphological characteristics. This material produces a current density of 10 mA/cm2 for oxygen evolution comparatively at low overpotentials of 227 mV and maintains its stability for up to 50 h. Furthermore, the fabricated NaBiO2@PPy nanocomposite also shows less Tafel slope of 30.8 mV/dec. Therefore, this catalytic material would be a good option for creating a cost-effective, and environmentally friendly alkaline medium. In order to enhance the performance of water electrolysis, this work offers a revolutionary designed material and electrode fabrication method for future applications.

Graphical Abstract

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来源期刊
Journal of the Australian Ceramic Society
Journal of the Australian Ceramic Society Materials Science-Materials Chemistry
CiteScore
3.70
自引率
5.30%
发文量
123
期刊介绍: Publishes high quality research and technical papers in all areas of ceramic and related materials Spans the broad and growing fields of ceramic technology, material science and bioceramics Chronicles new advances in ceramic materials, manufacturing processes and applications Journal of the Australian Ceramic Society since 1965 Professional language editing service is available through our affiliates Nature Research Editing Service and American Journal Experts at the author''s cost and does not guarantee that the manuscript will be reviewed or accepted
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