{"title":"BiSbTe/MnCoGe多功能材料的非均相界面微观结构及热电磁转换性能","authors":"Longli Wang, Rongcheng Li, Peilin Miao, Jiushun Zhu, Gangjian Tan, Xinfeng Tang","doi":"10.1007/s40195-025-01854-w","DOIUrl":null,"url":null,"abstract":"<div><p>The synergistic cooling of thermoelectromagnetic materials promises a breakthrough in the efficiency of single refrigeration and has attracted extensive research. The study of heterogeneous interface is crucial for achieving the synergistic performance of both materials. In this work, a composite material comprising Bi<sub>2</sub>Te<sub>3</sub>-based thermoelectric material and MnCoGe-based magnetocaloric material is synthesized, which is a material exhibiting both thermoelectric and magnetocaloric properties. During the plasma-activated sintering process of the composite material, elemental interdiffusion of Mn, Co, Sb, and Te occurs, forming a diffusion layer of MnTe and CoSbTe. Reaction of heterogeneous interface leads to point defects within the material, significantly increasing the carrier concentration. Optimization of the sintering temperature results in a thermoelectric figure of merit (<i>ZT</i>) of 0.69 at 300 K and −Δ<i>S</i><sub>max</sub> of 0.97 J kg<sup>−1</sup> K<sup>−1</sup> at room temperature under a 5 T magnetic field for the Bi<sub>0.5</sub>Sb<sub>1.5</sub>Te<sub>3</sub>/10 wt% Mn<sub>0.9</sub>Cu<sub>0.1</sub>CoGe composite sintered at 623 K and under 50 MPa. This study demonstrates that Bi<sub>0.5</sub>Sb<sub>1.5</sub>Te<sub>3</sub>/Mn<sub>0.9</sub>Cu<sub>0.1</sub>CoGe is a potential candidate for efficient thermoelectromagnetic cooling applications.</p></div>","PeriodicalId":457,"journal":{"name":"Acta Metallurgica Sinica-English Letters","volume":"38 5","pages":"839 - 848"},"PeriodicalIF":2.9000,"publicationDate":"2025-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Heterogeneous Interface Microstructure and Thermoelectromagnetic Conversion Performance of BiSbTe/MnCoGe Multifunctional Materials\",\"authors\":\"Longli Wang, Rongcheng Li, Peilin Miao, Jiushun Zhu, Gangjian Tan, Xinfeng Tang\",\"doi\":\"10.1007/s40195-025-01854-w\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The synergistic cooling of thermoelectromagnetic materials promises a breakthrough in the efficiency of single refrigeration and has attracted extensive research. The study of heterogeneous interface is crucial for achieving the synergistic performance of both materials. In this work, a composite material comprising Bi<sub>2</sub>Te<sub>3</sub>-based thermoelectric material and MnCoGe-based magnetocaloric material is synthesized, which is a material exhibiting both thermoelectric and magnetocaloric properties. During the plasma-activated sintering process of the composite material, elemental interdiffusion of Mn, Co, Sb, and Te occurs, forming a diffusion layer of MnTe and CoSbTe. Reaction of heterogeneous interface leads to point defects within the material, significantly increasing the carrier concentration. Optimization of the sintering temperature results in a thermoelectric figure of merit (<i>ZT</i>) of 0.69 at 300 K and −Δ<i>S</i><sub>max</sub> of 0.97 J kg<sup>−1</sup> K<sup>−1</sup> at room temperature under a 5 T magnetic field for the Bi<sub>0.5</sub>Sb<sub>1.5</sub>Te<sub>3</sub>/10 wt% Mn<sub>0.9</sub>Cu<sub>0.1</sub>CoGe composite sintered at 623 K and under 50 MPa. This study demonstrates that Bi<sub>0.5</sub>Sb<sub>1.5</sub>Te<sub>3</sub>/Mn<sub>0.9</sub>Cu<sub>0.1</sub>CoGe is a potential candidate for efficient thermoelectromagnetic cooling applications.</p></div>\",\"PeriodicalId\":457,\"journal\":{\"name\":\"Acta Metallurgica Sinica-English Letters\",\"volume\":\"38 5\",\"pages\":\"839 - 848\"},\"PeriodicalIF\":2.9000,\"publicationDate\":\"2025-04-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Acta Metallurgica Sinica-English Letters\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s40195-025-01854-w\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"METALLURGY & METALLURGICAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Acta Metallurgica Sinica-English Letters","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1007/s40195-025-01854-w","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
Heterogeneous Interface Microstructure and Thermoelectromagnetic Conversion Performance of BiSbTe/MnCoGe Multifunctional Materials
The synergistic cooling of thermoelectromagnetic materials promises a breakthrough in the efficiency of single refrigeration and has attracted extensive research. The study of heterogeneous interface is crucial for achieving the synergistic performance of both materials. In this work, a composite material comprising Bi2Te3-based thermoelectric material and MnCoGe-based magnetocaloric material is synthesized, which is a material exhibiting both thermoelectric and magnetocaloric properties. During the plasma-activated sintering process of the composite material, elemental interdiffusion of Mn, Co, Sb, and Te occurs, forming a diffusion layer of MnTe and CoSbTe. Reaction of heterogeneous interface leads to point defects within the material, significantly increasing the carrier concentration. Optimization of the sintering temperature results in a thermoelectric figure of merit (ZT) of 0.69 at 300 K and −ΔSmax of 0.97 J kg−1 K−1 at room temperature under a 5 T magnetic field for the Bi0.5Sb1.5Te3/10 wt% Mn0.9Cu0.1CoGe composite sintered at 623 K and under 50 MPa. This study demonstrates that Bi0.5Sb1.5Te3/Mn0.9Cu0.1CoGe is a potential candidate for efficient thermoelectromagnetic cooling applications.
期刊介绍:
This international journal presents compact reports of significant, original and timely research reflecting progress in metallurgy, materials science and engineering, including materials physics, physical metallurgy, and process metallurgy.