改性矿物填充环氧复合材料的性能研究

IF 0.4 Q4 METALLURGY & METALLURGICAL ENGINEERING
A. Z. Bekeshev, Yu. A. Kadykova, S. G. Kalganova, A. S. Mostovoy, L. K. Tastanova, M. K. Akhmetova, B. O. Sarsenbaev
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引用次数: 0

摘要

分散填料(玄武岩、铬铁矿)在功率为2 kW、处理时间为60 s的感应装置中进行改性,确保了高频(HF)电流对填料的短期高温作用,从而改善了基于它们的填充环氧化合物的特性。发现填料的化学成分发生了变化,这与玄武岩和铬铁矿颗粒表面未结合的水分、氧化膜的去除以及分解温度低于改性温度的物质的氧化物有关。电镜数据表明,玄武岩颗粒暴露于高频电流后呈现针状,这对物理力学特性有积极影响,因为这种填料具有微补强作用。经高频电流处理后,铬铁矿颗粒的结构变化较弱。对HF电流处理前后矿物填料介电特性的研究表明,玄武岩和铬铁矿的介电常数显著增大,表明其结构发生了变化;这使强度特性从7%增加到17%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Properties of an Epoxy Composite Material Filled with Modified Minerals

Dispersed fillers (basalt, chromite) are modified in an induction installation at a power of 2 kW and a processing time of 60 s, which ensures a short-term high-temperature effect of high-frequency (HF) currents on the fillers and, as a result, improves the characteristics of the filled epoxy compounds based on them. The chemical composition of the fillers is found to change, which is associated with the removal of unbound moisture, an oxide film, and the oxides of the substances the decomposition temperature is lower than the modification temperature from the surface of basalt and chromite particles. Electron microscopy data demonstrate that basalt particles acquire a needle-like shape after exposure to HF currents, which positively affects the physicomechanical characteristics, since such a filler exerts a micro-reinforcement effect. Chromite particles weakly change their structure after HF current treatment. The study of the dielectric characteristics of the mineral fillers before and after HF current treatment shows that the dielectric constant increases significantly for basalt and chromite, indicating a change in their structure; this increases the strength characteristics from 7 to 17%.

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来源期刊
Russian Metallurgy (Metally)
Russian Metallurgy (Metally) METALLURGY & METALLURGICAL ENGINEERING-
CiteScore
0.70
自引率
25.00%
发文量
140
期刊介绍: Russian Metallurgy (Metally)  publishes results of original experimental and theoretical research in the form of reviews and regular articles devoted to topical problems of metallurgy, physical metallurgy, and treatment of ferrous, nonferrous, rare, and other metals and alloys, intermetallic compounds, and metallic composite materials. The journal focuses on physicochemical properties of metallurgical materials (ores, slags, matters, and melts of metals and alloys); physicochemical processes (thermodynamics and kinetics of pyrometallurgical, hydrometallurgical, electrochemical, and other processes); theoretical metallurgy; metal forming; thermoplastic and thermochemical treatment; computation and experimental determination of phase diagrams and thermokinetic diagrams; mechanisms and kinetics of phase transitions in metallic materials; relations between the chemical composition, phase and structural states of materials and their physicochemical and service properties; interaction between metallic materials and external media; and effects of radiation on these materials.
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