A. Z. Bekeshev, Yu. A. Kadykova, S. G. Kalganova, A. S. Mostovoy, L. K. Tastanova, M. K. Akhmetova, B. O. Sarsenbaev
{"title":"改性矿物填充环氧复合材料的性能研究","authors":"A. Z. Bekeshev, Yu. A. Kadykova, S. G. Kalganova, A. S. Mostovoy, L. K. Tastanova, M. K. Akhmetova, B. O. Sarsenbaev","doi":"10.1134/S0036029525700430","DOIUrl":null,"url":null,"abstract":"<p>Dispersed fillers (basalt, chromite) are modified in an induction installation at a power of 2 kW and a processing time of 60 s, which ensures a short-term high-temperature effect of high-frequency (HF) currents on the fillers and, as a result, improves the characteristics of the filled epoxy compounds based on them. The chemical composition of the fillers is found to change, which is associated with the removal of unbound moisture, an oxide film, and the oxides of the substances the decomposition temperature is lower than the modification temperature from the surface of basalt and chromite particles. Electron microscopy data demonstrate that basalt particles acquire a needle-like shape after exposure to HF currents, which positively affects the physicomechanical characteristics, since such a filler exerts a micro-reinforcement effect. Chromite particles weakly change their structure after HF current treatment. The study of the dielectric characteristics of the mineral fillers before and after HF current treatment shows that the dielectric constant increases significantly for basalt and chromite, indicating a change in their structure; this increases the strength characteristics from 7 to 17%.</p>","PeriodicalId":769,"journal":{"name":"Russian Metallurgy (Metally)","volume":"2024 9","pages":"1863 - 1867"},"PeriodicalIF":0.4000,"publicationDate":"2025-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Properties of an Epoxy Composite Material Filled with Modified Minerals\",\"authors\":\"A. Z. Bekeshev, Yu. A. Kadykova, S. G. Kalganova, A. S. Mostovoy, L. K. Tastanova, M. K. Akhmetova, B. O. Sarsenbaev\",\"doi\":\"10.1134/S0036029525700430\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Dispersed fillers (basalt, chromite) are modified in an induction installation at a power of 2 kW and a processing time of 60 s, which ensures a short-term high-temperature effect of high-frequency (HF) currents on the fillers and, as a result, improves the characteristics of the filled epoxy compounds based on them. The chemical composition of the fillers is found to change, which is associated with the removal of unbound moisture, an oxide film, and the oxides of the substances the decomposition temperature is lower than the modification temperature from the surface of basalt and chromite particles. Electron microscopy data demonstrate that basalt particles acquire a needle-like shape after exposure to HF currents, which positively affects the physicomechanical characteristics, since such a filler exerts a micro-reinforcement effect. Chromite particles weakly change their structure after HF current treatment. The study of the dielectric characteristics of the mineral fillers before and after HF current treatment shows that the dielectric constant increases significantly for basalt and chromite, indicating a change in their structure; this increases the strength characteristics from 7 to 17%.</p>\",\"PeriodicalId\":769,\"journal\":{\"name\":\"Russian Metallurgy (Metally)\",\"volume\":\"2024 9\",\"pages\":\"1863 - 1867\"},\"PeriodicalIF\":0.4000,\"publicationDate\":\"2025-04-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Metallurgy (Metally)\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0036029525700430\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"METALLURGY & METALLURGICAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Metallurgy (Metally)","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1134/S0036029525700430","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
Properties of an Epoxy Composite Material Filled with Modified Minerals
Dispersed fillers (basalt, chromite) are modified in an induction installation at a power of 2 kW and a processing time of 60 s, which ensures a short-term high-temperature effect of high-frequency (HF) currents on the fillers and, as a result, improves the characteristics of the filled epoxy compounds based on them. The chemical composition of the fillers is found to change, which is associated with the removal of unbound moisture, an oxide film, and the oxides of the substances the decomposition temperature is lower than the modification temperature from the surface of basalt and chromite particles. Electron microscopy data demonstrate that basalt particles acquire a needle-like shape after exposure to HF currents, which positively affects the physicomechanical characteristics, since such a filler exerts a micro-reinforcement effect. Chromite particles weakly change their structure after HF current treatment. The study of the dielectric characteristics of the mineral fillers before and after HF current treatment shows that the dielectric constant increases significantly for basalt and chromite, indicating a change in their structure; this increases the strength characteristics from 7 to 17%.
期刊介绍:
Russian Metallurgy (Metally) publishes results of original experimental and theoretical research in the form of reviews and regular articles devoted to topical problems of metallurgy, physical metallurgy, and treatment of ferrous, nonferrous, rare, and other metals and alloys, intermetallic compounds, and metallic composite materials. The journal focuses on physicochemical properties of metallurgical materials (ores, slags, matters, and melts of metals and alloys); physicochemical processes (thermodynamics and kinetics of pyrometallurgical, hydrometallurgical, electrochemical, and other processes); theoretical metallurgy; metal forming; thermoplastic and thermochemical treatment; computation and experimental determination of phase diagrams and thermokinetic diagrams; mechanisms and kinetics of phase transitions in metallic materials; relations between the chemical composition, phase and structural states of materials and their physicochemical and service properties; interaction between metallic materials and external media; and effects of radiation on these materials.