{"title":"超临界co2 -水-煤-岩耦合破裂机理及多场相互作用效应","authors":"Fei Yu, Guangzhe Deng and Chao Yuan","doi":"10.1039/D4SE00870G","DOIUrl":null,"url":null,"abstract":"<p >A novel supercritical CO<small><sub>2</sub></small> fracturing device developed in-house was employed to devise experimental schemes utilizing water at various temperatures as a heat-carrying fluid. In this work, we studied the influence of heat source power and the initial CO<small><sub>2</sub></small> pressure on the coal-breaking process and fracture evolution driven by thermal shock. The evolution law of fluids' temperature and failure fields was analyzed by establishing a multi-field coupling thermo-hydro-mechanical-damageable (THMD) numerical model. Multidimensional methods were utilized to study the mineral composition and microscopic pore-fracture structure evolution of CO<small><sub>2</sub></small>–water coupling coal rocks. The fracturing process initiated by CO<small><sub>2</sub></small> predominantly featured stress-induced radial fractures stemming from the rapid release of high-pressure gases. Additionally, it included branch fractures, which were a consequence of the expansion of major radial fractures due to high-temperature, high-pressure CO<small><sub>2</sub></small> during phase transitions. Additionally, simulated results were consistent with experimental findings, indicating that the initial CO<small><sub>2</sub></small> pressure limitedly affected the fracturing of coal rocks. However, the failure scope of coal rocks was enhanced by increasing the heat source power. The number of pores increased after CO<small><sub>2</sub></small>–water–coal coupling, accompanied by an enlarged pore size. Besides, connectivity among pores was enhanced. The pores of coal samples included adsorption pores, seepage pores, and transport pores. The total porosity of CO<small><sub>2</sub></small>–water coupling coal samples increased. Acid corrosion enhanced the effective porosity by 2.91%, whereas that of natural coal samples was reduced.</p>","PeriodicalId":104,"journal":{"name":"Sustainable Energy & Fuels","volume":" 9","pages":" 2466-2477"},"PeriodicalIF":5.0000,"publicationDate":"2025-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fracture mechanism and multi-field interaction effects of supercritical CO2–water–coal rock coupling\",\"authors\":\"Fei Yu, Guangzhe Deng and Chao Yuan\",\"doi\":\"10.1039/D4SE00870G\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >A novel supercritical CO<small><sub>2</sub></small> fracturing device developed in-house was employed to devise experimental schemes utilizing water at various temperatures as a heat-carrying fluid. In this work, we studied the influence of heat source power and the initial CO<small><sub>2</sub></small> pressure on the coal-breaking process and fracture evolution driven by thermal shock. The evolution law of fluids' temperature and failure fields was analyzed by establishing a multi-field coupling thermo-hydro-mechanical-damageable (THMD) numerical model. Multidimensional methods were utilized to study the mineral composition and microscopic pore-fracture structure evolution of CO<small><sub>2</sub></small>–water coupling coal rocks. The fracturing process initiated by CO<small><sub>2</sub></small> predominantly featured stress-induced radial fractures stemming from the rapid release of high-pressure gases. Additionally, it included branch fractures, which were a consequence of the expansion of major radial fractures due to high-temperature, high-pressure CO<small><sub>2</sub></small> during phase transitions. Additionally, simulated results were consistent with experimental findings, indicating that the initial CO<small><sub>2</sub></small> pressure limitedly affected the fracturing of coal rocks. However, the failure scope of coal rocks was enhanced by increasing the heat source power. The number of pores increased after CO<small><sub>2</sub></small>–water–coal coupling, accompanied by an enlarged pore size. Besides, connectivity among pores was enhanced. The pores of coal samples included adsorption pores, seepage pores, and transport pores. The total porosity of CO<small><sub>2</sub></small>–water coupling coal samples increased. Acid corrosion enhanced the effective porosity by 2.91%, whereas that of natural coal samples was reduced.</p>\",\"PeriodicalId\":104,\"journal\":{\"name\":\"Sustainable Energy & Fuels\",\"volume\":\" 9\",\"pages\":\" 2466-2477\"},\"PeriodicalIF\":5.0000,\"publicationDate\":\"2025-03-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Sustainable Energy & Fuels\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/se/d4se00870g\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Sustainable Energy & Fuels","FirstCategoryId":"88","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/se/d4se00870g","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Fracture mechanism and multi-field interaction effects of supercritical CO2–water–coal rock coupling
A novel supercritical CO2 fracturing device developed in-house was employed to devise experimental schemes utilizing water at various temperatures as a heat-carrying fluid. In this work, we studied the influence of heat source power and the initial CO2 pressure on the coal-breaking process and fracture evolution driven by thermal shock. The evolution law of fluids' temperature and failure fields was analyzed by establishing a multi-field coupling thermo-hydro-mechanical-damageable (THMD) numerical model. Multidimensional methods were utilized to study the mineral composition and microscopic pore-fracture structure evolution of CO2–water coupling coal rocks. The fracturing process initiated by CO2 predominantly featured stress-induced radial fractures stemming from the rapid release of high-pressure gases. Additionally, it included branch fractures, which were a consequence of the expansion of major radial fractures due to high-temperature, high-pressure CO2 during phase transitions. Additionally, simulated results were consistent with experimental findings, indicating that the initial CO2 pressure limitedly affected the fracturing of coal rocks. However, the failure scope of coal rocks was enhanced by increasing the heat source power. The number of pores increased after CO2–water–coal coupling, accompanied by an enlarged pore size. Besides, connectivity among pores was enhanced. The pores of coal samples included adsorption pores, seepage pores, and transport pores. The total porosity of CO2–water coupling coal samples increased. Acid corrosion enhanced the effective porosity by 2.91%, whereas that of natural coal samples was reduced.
期刊介绍:
Sustainable Energy & Fuels will publish research that contributes to the development of sustainable energy technologies with a particular emphasis on new and next-generation technologies.