{"title":"超声辅助快速制备Cu泡沫/Cu- sn IMC复合材料夹层用于高温模贴","authors":"L. Zhu, J. Ren, M.L. Huang","doi":"10.1016/j.matchar.2025.115100","DOIUrl":null,"url":null,"abstract":"<div><div>The development of full intermetallic compound (IMC) joints with high melting temperatures is critical for advanced die-attach in third-generation semiconductor power devices. This study demonstrates an innovative ultrasonic-assisted manufacturing strategy to fabricate high-performance Cu foam/Cu-Sn IMC composite interlayers, consisting of three-dimensional continuous Cu foam skeletons, Cu<sub>6</sub>Sn<sub>5</sub> and Cu<sub>3</sub>Sn IMCs, by low-power ultrasonic-assisted immersion soldering (260 °C, 180 s). The rapid fabrication of composite interlayer was attributed to that the cavitation erosion effect promoted the wettability of the molten Sn on Cu surface, and the acoustic cavitation and streaming effects simultaneously enhanced both the dissolution rate and the diffusivity of substantial Cu atoms from high specific surface area Cu foam into the molten Sn. The composite joints prepared by diffusion bonding of two Cu substrates with the composite interlayers achieved the metallurgical bonding through the formation of thin interfacial Cu<sub>3</sub>Sn IMCs. The optimized composite joint demonstrated exceptional mechanical performance with a shear strength of 65.3 MPa and fracture elongation of 33.1 %, owing to the combined effects of the fine grain strengthening of Cu-Sn IMCs induced by the ultrasonic vibration and the ductile three-dimensional continuous Cu foam skeletons.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"224 ","pages":"Article 115100"},"PeriodicalIF":4.8000,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Ultrasonic-assisted rapid fabrication of Cu foam/Cu-Sn IMC composite interlayers for high-temperature die-attach applications\",\"authors\":\"L. Zhu, J. Ren, M.L. Huang\",\"doi\":\"10.1016/j.matchar.2025.115100\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The development of full intermetallic compound (IMC) joints with high melting temperatures is critical for advanced die-attach in third-generation semiconductor power devices. This study demonstrates an innovative ultrasonic-assisted manufacturing strategy to fabricate high-performance Cu foam/Cu-Sn IMC composite interlayers, consisting of three-dimensional continuous Cu foam skeletons, Cu<sub>6</sub>Sn<sub>5</sub> and Cu<sub>3</sub>Sn IMCs, by low-power ultrasonic-assisted immersion soldering (260 °C, 180 s). The rapid fabrication of composite interlayer was attributed to that the cavitation erosion effect promoted the wettability of the molten Sn on Cu surface, and the acoustic cavitation and streaming effects simultaneously enhanced both the dissolution rate and the diffusivity of substantial Cu atoms from high specific surface area Cu foam into the molten Sn. The composite joints prepared by diffusion bonding of two Cu substrates with the composite interlayers achieved the metallurgical bonding through the formation of thin interfacial Cu<sub>3</sub>Sn IMCs. The optimized composite joint demonstrated exceptional mechanical performance with a shear strength of 65.3 MPa and fracture elongation of 33.1 %, owing to the combined effects of the fine grain strengthening of Cu-Sn IMCs induced by the ultrasonic vibration and the ductile three-dimensional continuous Cu foam skeletons.</div></div>\",\"PeriodicalId\":18727,\"journal\":{\"name\":\"Materials Characterization\",\"volume\":\"224 \",\"pages\":\"Article 115100\"},\"PeriodicalIF\":4.8000,\"publicationDate\":\"2025-04-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Characterization\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1044580325003894\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CHARACTERIZATION & TESTING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Characterization","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1044580325003894","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CHARACTERIZATION & TESTING","Score":null,"Total":0}
引用次数: 0
摘要
高熔点全金属间化合物(IMC)接头的开发是第三代半导体功率器件中先进的模接技术的关键。本研究展示了一种创新的超声辅助制造策略,通过低功率超声辅助浸没焊接(260°C, 180 s),制备高性能泡沫铜/Cu- sn IMC复合中间层,由三维连续泡沫铜骨架、Cu6Sn5和Cu3Sn IMC组成。复合中间层的快速制备归因于空化侵蚀效应提高了熔融锡在Cu表面的润湿性,声空化和流化效应同时提高了大量Cu原子从高比表面积Cu泡沫中溶解到熔融锡中的速度和扩散率。将两个Cu衬底与复合中间层扩散结合制备复合接头,通过形成薄界面Cu3Sn IMCs实现了冶金结合。超声振动诱导Cu- sn IMCs的细晶强化和三维连续Cu泡沫骨架的延展性共同作用,使该复合接头的抗剪强度达到65.3 MPa,断裂伸长率达到33.1%。
Ultrasonic-assisted rapid fabrication of Cu foam/Cu-Sn IMC composite interlayers for high-temperature die-attach applications
The development of full intermetallic compound (IMC) joints with high melting temperatures is critical for advanced die-attach in third-generation semiconductor power devices. This study demonstrates an innovative ultrasonic-assisted manufacturing strategy to fabricate high-performance Cu foam/Cu-Sn IMC composite interlayers, consisting of three-dimensional continuous Cu foam skeletons, Cu6Sn5 and Cu3Sn IMCs, by low-power ultrasonic-assisted immersion soldering (260 °C, 180 s). The rapid fabrication of composite interlayer was attributed to that the cavitation erosion effect promoted the wettability of the molten Sn on Cu surface, and the acoustic cavitation and streaming effects simultaneously enhanced both the dissolution rate and the diffusivity of substantial Cu atoms from high specific surface area Cu foam into the molten Sn. The composite joints prepared by diffusion bonding of two Cu substrates with the composite interlayers achieved the metallurgical bonding through the formation of thin interfacial Cu3Sn IMCs. The optimized composite joint demonstrated exceptional mechanical performance with a shear strength of 65.3 MPa and fracture elongation of 33.1 %, owing to the combined effects of the fine grain strengthening of Cu-Sn IMCs induced by the ultrasonic vibration and the ductile three-dimensional continuous Cu foam skeletons.
期刊介绍:
Materials Characterization features original articles and state-of-the-art reviews on theoretical and practical aspects of the structure and behaviour of materials.
The Journal focuses on all characterization techniques, including all forms of microscopy (light, electron, acoustic, etc.,) and analysis (especially microanalysis and surface analytical techniques). Developments in both this wide range of techniques and their application to the quantification of the microstructure of materials are essential facets of the Journal.
The Journal provides the Materials Scientist/Engineer with up-to-date information on many types of materials with an underlying theme of explaining the behavior of materials using novel approaches. Materials covered by the journal include:
Metals & Alloys
Ceramics
Nanomaterials
Biomedical materials
Optical materials
Composites
Natural Materials.