A.D. Ohaegbue , S.O. Salawu , R.A. Oderinu , A.O. Akindele , P. Adegbite
{"title":"基于化学动力学和对流通道壁的磁卡森流体三步放热反应的热失控和分布效应","authors":"A.D. Ohaegbue , S.O. Salawu , R.A. Oderinu , A.O. Akindele , P. Adegbite","doi":"10.1016/j.rinp.2025.108277","DOIUrl":null,"url":null,"abstract":"<div><div>The essential contributions of exothermic combustion processes in thermal system designs cannot be overemphasized. A system involving a three-step reaction–diffusion of magneto-Casson fluids has implications for safety management, energy systems, and chemical engineering. Thus, this study examines the thermal runaway phenomenon and its propagation influences on a three-step exothermic reaction of a gravity-driven magneto-Casson fluid, considering convective heat distribution and chemical kinetics along a channel. The study is characterized by an overwhelming temperature rise due to the exothermic heat accumulation, which poses substantial challenges in natural and industrial processes. The interaction between Casson fluid rheological properties, chemical reaction rates, activation energy, and thermal energy with the magnetic field influence is explored. The theoretical model integrating the Casson fluid model is coupled with nonlinear chemical kinetics for a three-step exothermic combustion. Following Newton’s cooling law, the thermal convective exchange at the channel wall is modeled. The dimensionless terms such as the magnetic field intensity, Brinkman number, Grashof number, and Frank-Kamenetskii parameter are utilized to analyze the reaction stability, dissipation, and heat distribution. The study employs a Galerkin weighted residual technique to solve the coupled equations for appropriate parametric sensitivities analysis of the flow characteristics and chemical kinetics on the thermal runaway onset. The main findings revealed that a three-step reaction leads to system complexity, where the reaction intermediate stabilizes and amplifies thermal effects depending on the activation energy. The distribution of temperature in the channel wall provides mitigating runaway risks in industrial applications and gives insights into reaction conditions optimization.</div></div>","PeriodicalId":21042,"journal":{"name":"Results in Physics","volume":"73 ","pages":"Article 108277"},"PeriodicalIF":4.4000,"publicationDate":"2025-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Thermal runaway and distribution effects on a three-step exothermic reaction of magneto-Casson fluid with chemical kinetics and convective channel wall\",\"authors\":\"A.D. Ohaegbue , S.O. Salawu , R.A. Oderinu , A.O. Akindele , P. Adegbite\",\"doi\":\"10.1016/j.rinp.2025.108277\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The essential contributions of exothermic combustion processes in thermal system designs cannot be overemphasized. A system involving a three-step reaction–diffusion of magneto-Casson fluids has implications for safety management, energy systems, and chemical engineering. Thus, this study examines the thermal runaway phenomenon and its propagation influences on a three-step exothermic reaction of a gravity-driven magneto-Casson fluid, considering convective heat distribution and chemical kinetics along a channel. The study is characterized by an overwhelming temperature rise due to the exothermic heat accumulation, which poses substantial challenges in natural and industrial processes. The interaction between Casson fluid rheological properties, chemical reaction rates, activation energy, and thermal energy with the magnetic field influence is explored. The theoretical model integrating the Casson fluid model is coupled with nonlinear chemical kinetics for a three-step exothermic combustion. Following Newton’s cooling law, the thermal convective exchange at the channel wall is modeled. The dimensionless terms such as the magnetic field intensity, Brinkman number, Grashof number, and Frank-Kamenetskii parameter are utilized to analyze the reaction stability, dissipation, and heat distribution. The study employs a Galerkin weighted residual technique to solve the coupled equations for appropriate parametric sensitivities analysis of the flow characteristics and chemical kinetics on the thermal runaway onset. The main findings revealed that a three-step reaction leads to system complexity, where the reaction intermediate stabilizes and amplifies thermal effects depending on the activation energy. The distribution of temperature in the channel wall provides mitigating runaway risks in industrial applications and gives insights into reaction conditions optimization.</div></div>\",\"PeriodicalId\":21042,\"journal\":{\"name\":\"Results in Physics\",\"volume\":\"73 \",\"pages\":\"Article 108277\"},\"PeriodicalIF\":4.4000,\"publicationDate\":\"2025-04-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Results in Physics\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2211379725001718\",\"RegionNum\":2,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Results in Physics","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2211379725001718","RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Thermal runaway and distribution effects on a three-step exothermic reaction of magneto-Casson fluid with chemical kinetics and convective channel wall
The essential contributions of exothermic combustion processes in thermal system designs cannot be overemphasized. A system involving a three-step reaction–diffusion of magneto-Casson fluids has implications for safety management, energy systems, and chemical engineering. Thus, this study examines the thermal runaway phenomenon and its propagation influences on a three-step exothermic reaction of a gravity-driven magneto-Casson fluid, considering convective heat distribution and chemical kinetics along a channel. The study is characterized by an overwhelming temperature rise due to the exothermic heat accumulation, which poses substantial challenges in natural and industrial processes. The interaction between Casson fluid rheological properties, chemical reaction rates, activation energy, and thermal energy with the magnetic field influence is explored. The theoretical model integrating the Casson fluid model is coupled with nonlinear chemical kinetics for a three-step exothermic combustion. Following Newton’s cooling law, the thermal convective exchange at the channel wall is modeled. The dimensionless terms such as the magnetic field intensity, Brinkman number, Grashof number, and Frank-Kamenetskii parameter are utilized to analyze the reaction stability, dissipation, and heat distribution. The study employs a Galerkin weighted residual technique to solve the coupled equations for appropriate parametric sensitivities analysis of the flow characteristics and chemical kinetics on the thermal runaway onset. The main findings revealed that a three-step reaction leads to system complexity, where the reaction intermediate stabilizes and amplifies thermal effects depending on the activation energy. The distribution of temperature in the channel wall provides mitigating runaway risks in industrial applications and gives insights into reaction conditions optimization.
Results in PhysicsMATERIALS SCIENCE, MULTIDISCIPLINARYPHYSIC-PHYSICS, MULTIDISCIPLINARY
CiteScore
8.70
自引率
9.40%
发文量
754
审稿时长
50 days
期刊介绍:
Results in Physics is an open access journal offering authors the opportunity to publish in all fundamental and interdisciplinary areas of physics, materials science, and applied physics. Papers of a theoretical, computational, and experimental nature are all welcome. Results in Physics accepts papers that are scientifically sound, technically correct and provide valuable new knowledge to the physics community. Topics such as three-dimensional flow and magnetohydrodynamics are not within the scope of Results in Physics.
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3. Letters to the Editor: Letters discussing a recent article published in Results in Physics are welcome. These are objective, constructive, or educational critiques of papers published in Results in Physics. Accepted letters will be sent to the author of the original paper for a response. Each letter and response is published together. Letters should be received within 8 weeks of the article''s publication. They should not exceed 750 words of text and 10 references.