钙的PCP和POCOP复合物

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-04-28 DOI:10.1039/d5cc00872g

Alessandro Messori, Marcel Potocnik, Richard Collins, Tobias Kraemer, Mark Chadwick, Sara Belazregue

{"title":"钙的PCP和POCOP复合物","authors":"Alessandro Messori, Marcel Potocnik, Richard Collins, Tobias Kraemer, Mark Chadwick, Sara Belazregue","doi":"10.1039/d5cc00872g","DOIUrl":null,"url":null,"abstract":"The first synthesis of PCP and POCOP complexes of calcium are described. Ca(N(SiMe3)2)2 is reacted with Li[tBuPCP] or Li[tBuPOCOP] to form (tBuPCP)Ca(N(SiMe3)2) (1a) and (tBuPOCOP)Ca(N(SiMe3)2) (1b). Reaction of 1b or Ca(N(SiMe3)2)2with excess Li[tBuPOCOP] leads to a homoleptic complex Ca(tBuPOCOP) ,22. The (iPrPOCOP) ligand exclusively forms the homoleptic complex Ca(iPrPOCOP)2, 3.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"11 1","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"PCP and POCOP complexes of calcium\",\"authors\":\"Alessandro Messori, Marcel Potocnik, Richard Collins, Tobias Kraemer, Mark Chadwick, Sara Belazregue\",\"doi\":\"10.1039/d5cc00872g\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The first synthesis of PCP and POCOP complexes of calcium are described. Ca(N(SiMe3)2)2 is reacted with Li[tBuPCP] or Li[tBuPOCOP] to form (tBuPCP)Ca(N(SiMe3)2) (1a) and (tBuPOCOP)Ca(N(SiMe3)2) (1b). Reaction of 1b or Ca(N(SiMe3)2)2with excess Li[tBuPOCOP] leads to a homoleptic complex Ca(tBuPOCOP) ,22. The (iPrPOCOP) ligand exclusively forms the homoleptic complex Ca(iPrPOCOP)2, 3.\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"11 1\",\"pages\":\"\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2025-04-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d5cc00872g\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d5cc00872g","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

首次合成了钙的PCP和POCOP配合物。Ca(N(SiMe3)2)2与Li[tBuPCP]或Li[tBuPOCOP]反应生成（tBuPCP）Ca(N(SiMe3)2) （1a）和（tBuPOCOP）Ca(N(SiMe3)2) （1b）。1b或Ca(N(SiMe3)2)2与过量Li[tBuPOCOP]反应可形成同感复合物Ca(tBuPOCOP),22。（iPrPOCOP）配体专门形成同感复合物Ca(iPrPOCOP) 2,3。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

PCP and POCOP complexes of calcium

The first synthesis of PCP and POCOP complexes of calcium are described. Ca(N(SiMe3)2)2 is reacted with Li[tBuPCP] or Li[tBuPOCOP] to form (tBuPCP)Ca(N(SiMe3)2) (1a) and (tBuPOCOP)Ca(N(SiMe3)2) (1b). Reaction of 1b or Ca(N(SiMe3)2)2with excess Li[tBuPOCOP] leads to a homoleptic complex Ca(tBuPOCOP) ,22. The (iPrPOCOP) ligand exclusively forms the homoleptic complex Ca(iPrPOCOP)2, 3.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.