Pedro H. R. Oliveira, Marieli O. Rodrigues, Caren D. G. da Silva, Josina Bohlen, Merle Arrowsmith, Arumugam Jayaraman, Lukas Lubczyk, Felipe Fantuzzi, Eufrânio N. da Silva Júnior, Holger Braunschweig
{"title":"外封底:硼炔和双炔直接形成硼炔(新。化学18/2025)","authors":"Pedro H. R. Oliveira, Marieli O. Rodrigues, Caren D. G. da Silva, Josina Bohlen, Merle Arrowsmith, Arumugam Jayaraman, Lukas Lubczyk, Felipe Fantuzzi, Eufrânio N. da Silva Júnior, Holger Braunschweig","doi":"10.1002/ange.202506308","DOIUrl":null,"url":null,"abstract":"<p>In their Research Article (e202423391), Felipe Fantuzzi, Eufrânio N. da Silva Júnior, Holger Braunschweig et al. report a selective one-step synthesis of perarylated borirenes from boroles and 1,3-diynes. The study includes substrate scope, X-ray, and DFT analyses. The cover illustrates this process with a phenyl balloon carrying a borirene ring arising above a sky filled with borole precursors, highlighting the novelty and aromaticity of the three-membered boron-bearing rings (Cover design: Danilo Londoño).\n\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure></p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 18","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2025-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202506308","citationCount":"0","resultStr":"{\"title\":\"Outside Back Cover: Straightforward Formation of Borirenes from Boroles and Dialkynes (Angew. Chem. 18/2025)\",\"authors\":\"Pedro H. R. Oliveira, Marieli O. Rodrigues, Caren D. G. da Silva, Josina Bohlen, Merle Arrowsmith, Arumugam Jayaraman, Lukas Lubczyk, Felipe Fantuzzi, Eufrânio N. da Silva Júnior, Holger Braunschweig\",\"doi\":\"10.1002/ange.202506308\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In their Research Article (e202423391), Felipe Fantuzzi, Eufrânio N. da Silva Júnior, Holger Braunschweig et al. report a selective one-step synthesis of perarylated borirenes from boroles and 1,3-diynes. The study includes substrate scope, X-ray, and DFT analyses. The cover illustrates this process with a phenyl balloon carrying a borirene ring arising above a sky filled with borole precursors, highlighting the novelty and aromaticity of the three-membered boron-bearing rings (Cover design: Danilo Londoño).\\n\\n <figure>\\n <div><picture>\\n <source></source></picture><p></p>\\n </div>\\n </figure></p>\",\"PeriodicalId\":7803,\"journal\":{\"name\":\"Angewandte Chemie\",\"volume\":\"137 18\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2025-03-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202506308\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Angewandte Chemie\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ange.202506308\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ange.202506308","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
Felipe Fantuzzi, eufr nio N. da Silva Júnior, Holger Braunschweig等人在他们的研究文章(e202423391)中报道了一种由硼烷和1,3-炔选择性一步合成过芳基硼烯的方法。该研究包括衬底范围、x射线和DFT分析。封面用一个携带硼环的苯气球在充满硼前体的天空中升起来说明了这一过程,突出了三元硼环的新颖性和芳香性(封面设计:Danilo Londoño)。
Outside Back Cover: Straightforward Formation of Borirenes from Boroles and Dialkynes (Angew. Chem. 18/2025)
In their Research Article (e202423391), Felipe Fantuzzi, Eufrânio N. da Silva Júnior, Holger Braunschweig et al. report a selective one-step synthesis of perarylated borirenes from boroles and 1,3-diynes. The study includes substrate scope, X-ray, and DFT analyses. The cover illustrates this process with a phenyl balloon carrying a borirene ring arising above a sky filled with borole precursors, highlighting the novelty and aromaticity of the three-membered boron-bearing rings (Cover design: Danilo Londoño).