金刚石薄膜和纳米膜中氮浓度和晶体尺寸对晶格热导率的影响

IF 4.3 3区 材料科学 Q2 MATERIALS SCIENCE, COATINGS & FILMS
N.K. Ali , M.S. Omar , S.O. Yousf
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引用次数: 0

摘要

本文综合分析了金刚石材料的晶格热导率(LTC),重点研究了氮杂质和晶体尺寸的双重影响。利用改进的Debye-Callaway模型,对两组钻石样品进行了理论计算。第一组由不同氮浓度的单晶钻石组成,从几乎纯的到高度掺杂的样品不等。第二组包括不同尺寸的单晶、微膜和纳米膜,允许对尺寸依赖效应进行研究。该研究系统地研究了各种声子散射机制的贡献,包括声子-声子相互作用(正常和Umklapp过程),点缺陷,同位素,边界散射,位错,声子-电子相互作用以及纵向和横向声子模式的声子共振散射。值得注意的是,声子共振散射在低温下的LTC降低中起着重要作用,声子与局部缺陷引起的振动模式相互作用。氮杂质作为强散射中心,显著破坏了晶格结构,降低了LTC。还原程度与氮浓度、缺陷密度和血小板构型有关。晶体尺寸是另一个关键因素,因为较小的样品表现出增强的边界散射,导致LTC显著下降,特别是在纳米尺度上。这项工作进一步确定了LTC、氮浓度和晶体尺寸之间的系统关系,为预测热输运行为提供了关键的数学模型。这些发现为定制金刚石材料提供了有价值的见解,这些材料可用于热管理、大功率电子和能源系统的高级应用,在这些应用中,精确控制热性能是必不可少的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

On the nitrogen concentration and crystal size dependence of lattice thermal conductivity in diamond thin and nanofilms

On the nitrogen concentration and crystal size dependence of lattice thermal conductivity in diamond thin and nanofilms
This work comprehensively analyses lattice thermal conductivity (LTC) in diamond materials, focusing on the dual influence of nitrogen impurities and crystal size. Using a modified Debye-Callaway model, theoretical calculations are performed for two groups of diamond specimens. The first group comprises single-crystal diamonds with varying nitrogen concentrations, ranging from nearly pure to highly doped specimens. The second group comprises single crystals, microfilms, and nanofilms of varying sizes, allowing for an investigation of size-dependent effects. The study systematically examines the contributions of various phonon-scattering mechanisms, including phonon-phonon interactions (Normal and Umklapp processes), point defects, isotopes, boundary scattering, dislocations, phonon-electron interactions, and phonon resonance scattering for both longitudinal and transverse phonon modes. Notably, phonon resonance scattering plays a significant role in LTC reduction at low temperatures, where phonons interact with localized defect-induced vibrational modes. Nitrogen impurities act as strong scattering centers, significantly disrupting the lattice structure and reducing LTC. The degree of reduction correlates with nitrogen concentration, defect density, and platelet configurations. Crystal size is another critical factor, as smaller samples exhibit enhanced boundary scattering, resulting in a pronounced decline in LTC, particularly at nanoscale dimensions. The work further identifies systematic relationships between LTC, nitrogen concentration, and crystal size, providing key mathematical models to predict thermal transport behaviour. These findings offer valuable insights into tailoring diamond materials for advanced applications in thermal management, high-power electronics, and energy systems, where precise control of thermal properties is essential.
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来源期刊
Diamond and Related Materials
Diamond and Related Materials 工程技术-材料科学:综合
CiteScore
6.00
自引率
14.60%
发文量
702
审稿时长
2.1 months
期刊介绍: DRM is a leading international journal that publishes new fundamental and applied research on all forms of diamond, the integration of diamond with other advanced materials and development of technologies exploiting diamond. The synthesis, characterization and processing of single crystal diamond, polycrystalline films, nanodiamond powders and heterostructures with other advanced materials are encouraged topics for technical and review articles. In addition to diamond, the journal publishes manuscripts on the synthesis, characterization and application of other related materials including diamond-like carbons, carbon nanotubes, graphene, and boron and carbon nitrides. Articles are sought on the chemical functionalization of diamond and related materials as well as their use in electrochemistry, energy storage and conversion, chemical and biological sensing, imaging, thermal management, photonic and quantum applications, electron emission and electronic devices. The International Conference on Diamond and Carbon Materials has evolved into the largest and most well attended forum in the field of diamond, providing a forum to showcase the latest results in the science and technology of diamond and other carbon materials such as carbon nanotubes, graphene, and diamond-like carbon. Run annually in association with Diamond and Related Materials the conference provides junior and established researchers the opportunity to exchange the latest results ranging from fundamental physical and chemical concepts to applied research focusing on the next generation carbon-based devices.
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