树型聚己内酯-艾草吸附膜去除废水中Cu（II）

IF 6.3 2区工程技术 Q1 ENGINEERING, CHEMICAL

Journal of water process engineering Pub Date : 2025-04-27 DOI:10.1016/j.jwpe.2025.107767

Han Bi Lee , Ah-Jeong Choi , Heejin Kim , Ju Yeon Kim , Young-Kwan Kim , Min Wook Lee

{"title":"树型聚己内酯-艾草吸附膜去除废水中Cu（II）","authors":"Han Bi Lee , Ah-Jeong Choi , Heejin Kim , Ju Yeon Kim , Young-Kwan Kim , Min Wook Lee","doi":"10.1016/j.jwpe.2025.107767","DOIUrl":null,"url":null,"abstract":"<div><div>Recently, wastewater discharge has been increasing due to the increase in semiconductor production, and heavy metals in semiconductor wastewater can cause life-threatening effects on the brain, liver, and kidneys. In this study, we developed an eco-friendly polycaprolactone-mugwort (PCL-mugwort) adsorption membrane through electrospinning to remove various heavy metal ions contained in semiconductor wastewater. PCL is a representative biodegradable and biocompatible polymer, and mugwort is a natural material and rich in minerals, calcium, iron, and etc. The removal performance of the PCL-mugwort adsorption membranes for heavy metal ions was evaluated under static conditions with stirring and dynamic conditions with filtration. With 100 μM aqueous solution (5 mL) of copper ions, the 36 cm<sup>2</sup> the PCL-mugwort adsorption membrane, with a mugwort content in the membrane: 0.13 mg/cm<sup>2</sup>, shows a high removal efficiency of 71.7 % within 6 h under a static condition and 65.4 % under a dynamic condition with a flow rate of 10 mL/h. The removal mechanism was analyzed using two- and three-parameter isotherms, indicating that the adsorption followed a multilayer process on a heterogeneous surface with adsorption sites having different energies. In addition, the PCL-mugwort adsorption membrane was scrolled to mimic the internal structure of a non-powered artificial tree with a capillary force to pump wastewater for simultaneous removal of heavy metal ions and evaporation of clean water.</div></div>","PeriodicalId":17528,"journal":{"name":"Journal of water process engineering","volume":"74 ","pages":"Article 107767"},"PeriodicalIF":6.3000,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Tree-inspired polycaprolactone-mugwort adsorption membrane for Cu(II) removal from wastewater\",\"authors\":\"Han Bi Lee , Ah-Jeong Choi , Heejin Kim , Ju Yeon Kim , Young-Kwan Kim , Min Wook Lee\",\"doi\":\"10.1016/j.jwpe.2025.107767\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Recently, wastewater discharge has been increasing due to the increase in semiconductor production, and heavy metals in semiconductor wastewater can cause life-threatening effects on the brain, liver, and kidneys. In this study, we developed an eco-friendly polycaprolactone-mugwort (PCL-mugwort) adsorption membrane through electrospinning to remove various heavy metal ions contained in semiconductor wastewater. PCL is a representative biodegradable and biocompatible polymer, and mugwort is a natural material and rich in minerals, calcium, iron, and etc. The removal performance of the PCL-mugwort adsorption membranes for heavy metal ions was evaluated under static conditions with stirring and dynamic conditions with filtration. With 100 μM aqueous solution (5 mL) of copper ions, the 36 cm<sup>2</sup> the PCL-mugwort adsorption membrane, with a mugwort content in the membrane: 0.13 mg/cm<sup>2</sup>, shows a high removal efficiency of 71.7 % within 6 h under a static condition and 65.4 % under a dynamic condition with a flow rate of 10 mL/h. The removal mechanism was analyzed using two- and three-parameter isotherms, indicating that the adsorption followed a multilayer process on a heterogeneous surface with adsorption sites having different energies. In addition, the PCL-mugwort adsorption membrane was scrolled to mimic the internal structure of a non-powered artificial tree with a capillary force to pump wastewater for simultaneous removal of heavy metal ions and evaporation of clean water.</div></div>\",\"PeriodicalId\":17528,\"journal\":{\"name\":\"Journal of water process engineering\",\"volume\":\"74 \",\"pages\":\"Article 107767\"},\"PeriodicalIF\":6.3000,\"publicationDate\":\"2025-04-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of water process engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2214714425008396\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of water process engineering","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2214714425008396","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}

引用次数: 0

摘要

最近，随着半导体生产的增加，废水排放量也在增加，半导体废水中的重金属会对大脑、肝脏、肾脏造成威胁。本研究采用静电纺丝技术制备了一种环保型聚己内酯-艾草（PCL-mugwort）吸附膜，用于去除半导体废水中所含的各种重金属离子。PCL是具有代表性的生物可降解和生物相容性聚合物，而艾蒿是一种富含矿物质、钙、铁等的天然材料。在静态搅拌条件和动态过滤条件下，考察了pcl -艾蒿吸附膜对重金属离子的去除性能。当铜离子浓度为100 μM （5 mL）时，36 cm2的pcl -艾蒿吸附膜中艾蒿的含量为0.13 mg/cm2，在静态条件下，6 h内的去除率为71.7%，在动态条件下，流速为10 mL/h，去除率为65.4%。采用二参数等温线和三参数等温线分析了吸附机理，表明吸附在具有不同能量的非均质表面上遵循多层吸附过程。此外，将pcl -艾蒿吸附膜卷动，模拟无动力人工树的内部结构，利用毛细力泵送废水，同时去除重金属离子和蒸发干净的水。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Tree-inspired polycaprolactone-mugwort adsorption membrane for Cu(II) removal from wastewater

Recently, wastewater discharge has been increasing due to the increase in semiconductor production, and heavy metals in semiconductor wastewater can cause life-threatening effects on the brain, liver, and kidneys. In this study, we developed an eco-friendly polycaprolactone-mugwort (PCL-mugwort) adsorption membrane through electrospinning to remove various heavy metal ions contained in semiconductor wastewater. PCL is a representative biodegradable and biocompatible polymer, and mugwort is a natural material and rich in minerals, calcium, iron, and etc. The removal performance of the PCL-mugwort adsorption membranes for heavy metal ions was evaluated under static conditions with stirring and dynamic conditions with filtration. With 100 μM aqueous solution (5 mL) of copper ions, the 36 cm² the PCL-mugwort adsorption membrane, with a mugwort content in the membrane: 0.13 mg/cm², shows a high removal efficiency of 71.7 % within 6 h under a static condition and 65.4 % under a dynamic condition with a flow rate of 10 mL/h. The removal mechanism was analyzed using two- and three-parameter isotherms, indicating that the adsorption followed a multilayer process on a heterogeneous surface with adsorption sites having different energies. In addition, the PCL-mugwort adsorption membrane was scrolled to mimic the internal structure of a non-powered artificial tree with a capillary force to pump wastewater for simultaneous removal of heavy metal ions and evaporation of clean water.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Journal of water process engineering Biochemistry, Genetics and Molecular Biology-Biotechnology

CiteScore

10.70

自引率

8.60%

发文量

846

审稿时长

24 days

期刊介绍： The Journal of Water Process Engineering aims to publish refereed, high-quality research papers with significant novelty and impact in all areas of the engineering of water and wastewater processing . Papers on advanced and novel treatment processes and technologies are particularly welcome. The Journal considers papers in areas such as nanotechnology and biotechnology applications in water, novel oxidation and separation processes, membrane processes (except those for desalination) , catalytic processes for the removal of water contaminants, sustainable processes, water reuse and recycling, water use and wastewater minimization, integrated/hybrid technology, process modeling of water treatment and novel treatment processes. Submissions on the subject of adsorbents, including standard measurements of adsorption kinetics and equilibrium will only be considered if there is a genuine case for novelty and contribution, for example highly novel, sustainable adsorbents and their use: papers on activated carbon-type materials derived from natural matter, or surfactant-modified clays and related minerals, would not fulfil this criterion. The Journal particularly welcomes contributions involving environmentally, economically and socially sustainable technology for water treatment, including those which are energy-efficient, with minimal or no chemical consumption, and capable of water recycling and reuse that minimizes the direct disposal of wastewater to the aquatic environment. Papers that describe novel ideas for solving issues related to water quality and availability are also welcome, as are those that show the transfer of techniques from other disciplines. The Journal will consider papers dealing with processes for various water matrices including drinking water (except desalination), domestic, urban and industrial wastewaters, in addition to their residues. It is expected that the journal will be of particular relevance to chemical and process engineers working in the field. The Journal welcomes Full Text papers, Short Communications, State-of-the-Art Reviews and Letters to Editors and Case Studies