芳烃多样化的区域选择性硅基装置

IF 42.8 1区化学 Q1 CHEMISTRY, PHYSICAL

Nature Catalysis Pub Date : 2025-04-25 DOI:10.1038/s41929-025-01314-9

引用次数: 0

摘要

使用单一钌催化剂，开发了位点选择性C-H功能化方法，用于在不同芳烃的邻位或元位上安装硅基甲基合成手柄，从而实现广泛的下游转化。机制研究强调，双环金属化钌（II）物种是这种反应性的关键，为未来的发展提供了见解。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Regioselective silyl installation for arene diversification

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Regioselective silyl installation for arene diversification

Using a single ruthenium catalyst, site-selective C–H functionalization methods are developed for the installation of silylmethyl synthetic handles at either ortho or meta positions on diverse arenes, enabling a wide range of downstream transformations. Mechanistic studies highlight that biscyclometallated ruthenium(II) species are key to this reactivity, offering insight for future developments.

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来源期刊

Nature Catalysis Chemical Engineering-Bioengineering

CiteScore

52.10

自引率

1.10%

发文量

140

期刊介绍： Nature Catalysis serves as a platform for researchers across chemistry and related fields, focusing on homogeneous catalysis, heterogeneous catalysis, and biocatalysts, encompassing both fundamental and applied studies. With a particular emphasis on advancing sustainable industries and processes, the journal provides comprehensive coverage of catalysis research, appealing to scientists, engineers, and researchers in academia and industry. Maintaining the high standards of the Nature brand, Nature Catalysis boasts a dedicated team of professional editors, rigorous peer-review processes, and swift publication times, ensuring editorial independence and quality. The journal publishes work spanning heterogeneous catalysis, homogeneous catalysis, and biocatalysis, covering areas such as catalytic synthesis, mechanisms, characterization, computational studies, nanoparticle catalysis, electrocatalysis, photocatalysis, environmental catalysis, asymmetric catalysis, and various forms of organocatalysis.