Jinkyung Kim , Jaesik Seo , Hyo Jeong Kim , Yunho Jeong , Hyunjun Lee , Chanwook Park , Youngho Eom
{"title":"纳米壳聚糖-海藻酸盐-蜂蜡酸洗乳油墨在水果保鲜中的协同设计","authors":"Jinkyung Kim , Jaesik Seo , Hyo Jeong Kim , Yunho Jeong , Hyunjun Lee , Chanwook Park , Youngho Eom","doi":"10.1016/j.foodhyd.2025.111462","DOIUrl":null,"url":null,"abstract":"<div><div>Chitosan nanowhisker (CSW) has attracted attention as a coating agent in packaging applications because of its biocompatibility, anti-bacterial activity, and high gas barrier. However, the poor viscoelasticity of virgin CSW dispersions limits the coating process to spraying or dip-coating at very dilute concentrations. Herein, rheology-engineered CSW inks with improved coating abilities were designed, making them suitable for mass-produced coatings. Given the positive surface charge of CSW, eight types of negatively charged eco-friendly binders were selected, and their efficiency as rheological modifiers was assessed at a CSW:binder weight fraction of 1:1. Among them, three binders, sodium alginate (SA), carboxymethyl cellulose, and guar, simultaneously enhanced the viscoelasticity and homogeneity. Accordingly, the three composite inks exhibit high spreadability in practical coating. Particularly, the CSW/SA coating films exhibited remarkable mechanical properties with strength and toughness of 32.9 MPa and 1.4 MJ m<sup>−3</sup>, respectively. To apply edible coatings for fruit preservation, beeswax (BW) was mixed with CSW/SA to form Pickering emulsion inks. CSW acts as a Pickering stabilizer in the aqueous BW emulsion, affording it high dispersibility. Owing to its improved hydrophobicity, the edible CSW/SA/BW coating significantly extended the shelf life of bananas and strawberries.</div></div>","PeriodicalId":320,"journal":{"name":"Food Hydrocolloids","volume":"167 ","pages":"Article 111462"},"PeriodicalIF":11.0000,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synergistic design of Pickering emulsion inks of nanochitosan-alginate-beeswax for edible coating in fruit preservation\",\"authors\":\"Jinkyung Kim , Jaesik Seo , Hyo Jeong Kim , Yunho Jeong , Hyunjun Lee , Chanwook Park , Youngho Eom\",\"doi\":\"10.1016/j.foodhyd.2025.111462\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Chitosan nanowhisker (CSW) has attracted attention as a coating agent in packaging applications because of its biocompatibility, anti-bacterial activity, and high gas barrier. However, the poor viscoelasticity of virgin CSW dispersions limits the coating process to spraying or dip-coating at very dilute concentrations. Herein, rheology-engineered CSW inks with improved coating abilities were designed, making them suitable for mass-produced coatings. Given the positive surface charge of CSW, eight types of negatively charged eco-friendly binders were selected, and their efficiency as rheological modifiers was assessed at a CSW:binder weight fraction of 1:1. Among them, three binders, sodium alginate (SA), carboxymethyl cellulose, and guar, simultaneously enhanced the viscoelasticity and homogeneity. Accordingly, the three composite inks exhibit high spreadability in practical coating. Particularly, the CSW/SA coating films exhibited remarkable mechanical properties with strength and toughness of 32.9 MPa and 1.4 MJ m<sup>−3</sup>, respectively. To apply edible coatings for fruit preservation, beeswax (BW) was mixed with CSW/SA to form Pickering emulsion inks. CSW acts as a Pickering stabilizer in the aqueous BW emulsion, affording it high dispersibility. Owing to its improved hydrophobicity, the edible CSW/SA/BW coating significantly extended the shelf life of bananas and strawberries.</div></div>\",\"PeriodicalId\":320,\"journal\":{\"name\":\"Food Hydrocolloids\",\"volume\":\"167 \",\"pages\":\"Article 111462\"},\"PeriodicalIF\":11.0000,\"publicationDate\":\"2025-04-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Food Hydrocolloids\",\"FirstCategoryId\":\"97\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0268005X25004229\",\"RegionNum\":1,\"RegionCategory\":\"农林科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Food Hydrocolloids","FirstCategoryId":"97","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0268005X25004229","RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Synergistic design of Pickering emulsion inks of nanochitosan-alginate-beeswax for edible coating in fruit preservation
Chitosan nanowhisker (CSW) has attracted attention as a coating agent in packaging applications because of its biocompatibility, anti-bacterial activity, and high gas barrier. However, the poor viscoelasticity of virgin CSW dispersions limits the coating process to spraying or dip-coating at very dilute concentrations. Herein, rheology-engineered CSW inks with improved coating abilities were designed, making them suitable for mass-produced coatings. Given the positive surface charge of CSW, eight types of negatively charged eco-friendly binders were selected, and their efficiency as rheological modifiers was assessed at a CSW:binder weight fraction of 1:1. Among them, three binders, sodium alginate (SA), carboxymethyl cellulose, and guar, simultaneously enhanced the viscoelasticity and homogeneity. Accordingly, the three composite inks exhibit high spreadability in practical coating. Particularly, the CSW/SA coating films exhibited remarkable mechanical properties with strength and toughness of 32.9 MPa and 1.4 MJ m−3, respectively. To apply edible coatings for fruit preservation, beeswax (BW) was mixed with CSW/SA to form Pickering emulsion inks. CSW acts as a Pickering stabilizer in the aqueous BW emulsion, affording it high dispersibility. Owing to its improved hydrophobicity, the edible CSW/SA/BW coating significantly extended the shelf life of bananas and strawberries.
期刊介绍:
Food Hydrocolloids publishes original and innovative research focused on the characterization, functional properties, and applications of hydrocolloid materials used in food products. These hydrocolloids, defined as polysaccharides and proteins of commercial importance, are added to control aspects such as texture, stability, rheology, and sensory properties. The research's primary emphasis should be on the hydrocolloids themselves, with thorough descriptions of their source, nature, and physicochemical characteristics. Manuscripts are expected to clearly outline specific aims and objectives, include a fundamental discussion of research findings at the molecular level, and address the significance of the results. Studies on hydrocolloids in complex formulations should concentrate on their overall properties and mechanisms of action, while simple formulation development studies may not be considered for publication.
The main areas of interest are:
-Chemical and physicochemical characterisation
Thermal properties including glass transitions and conformational changes-
Rheological properties including viscosity, viscoelastic properties and gelation behaviour-
The influence on organoleptic properties-
Interfacial properties including stabilisation of dispersions, emulsions and foams-
Film forming properties with application to edible films and active packaging-
Encapsulation and controlled release of active compounds-
The influence on health including their role as dietary fibre-
Manipulation of hydrocolloid structure and functionality through chemical, biochemical and physical processes-
New hydrocolloids and hydrocolloid sources of commercial potential.
The Journal also publishes Review articles that provide an overview of the latest developments in topics of specific interest to researchers in this field of activity.