高压锂金属电池用三氟甲基化离子液体准固态醚基电解质的研究

IF 27.4 1区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Jin Li, Junjie Chen, Xiaosa Xu, Jiadong Shen, Zhenyu Wang, Zixiao Guo, Pengzhu Lin, Jing Sun, Baoling Huang, Tianshou Zhao
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引用次数: 0

摘要

准固态醚基电解质的实际应用受到锂枝晶形成和氧化稳定性差的阻碍,从而降低了电池的循环寿命和能量密度。本文利用离子液体的高离子相互作用和结构柔韧性形成优化的电极/电解质界面,设计并开发了一种具有三氟甲基化阳离子段的吡咯烷基离子液体。电解质中阴离子的氧化被诱导在阴极处形成坚固的无机富liff界面,从而有效地实现高氧化稳定性和抑制过渡金属离子的溶解。此外,由三氟甲基化阳离子衍生的LiF界面相增加了阳极界面的模量,抑制了锂枝晶的生长。因此,在高电流密度(10℃)、宽电压范围(4.5 V)、高质量负载(11.1 mg cm−2)和宽温度范围(- 20 ~ 80℃)下,具有优化电解质的Li-LiFePO4、Li-LiCoO2和Li-LiNi0.8Co0.1Mn0.1O2全电池表现出显著的性能改善。此外,2.66 ah级别的袋状电池具有超过356 Wh kg-1的高能量密度和出色的循环稳定性,证明了该策略的潜力,为准固态醚基电解质在高能量密度电池中的实际应用提供了途径。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Developing Quasi-Solid-State Ether-Based Electrolytes with Trifluorotoluylation Ionic Liquids for High Voltage Lithium Metal Batteries

Developing Quasi-Solid-State Ether-Based Electrolytes with Trifluorotoluylation Ionic Liquids for High Voltage Lithium Metal Batteries
The practical application of quasi-solid-state ether-based electrolytes is hindered by lithium dendrite formation and poor oxidation stability, which reduce the cycle life and energy density of the battery. Here, taking advantage of the ionic liquids’ high ionic interactions and structural flexibility in forming an optimized electrode/electrolyte interface, a pyrrolidinium-based ionic liquids with trifluorotoluylation cationic segment is designed and developed. The oxidation of anions in the electrolytes is induced to form a robust inorganic LiF-rich interphase at the cathode, thereby effectively achieving high oxidation stability and suppressing the dissolution of transition metal ions. In addition, the LiF interphases derived from the trifluorotoluylation cations increase the modulus of the anode interface and suppress the growth of lithium dendrites. Therefore, the Li-LiFePO4, Li-LiCoO2, and Li-LiNi0.8Co0.1Mn0.1O2 full cells with the optimized electrolytes demonstrate remarkable performance improvements at high current density (10 C), a wide voltage range of 4.5 V, a high mass loading of 11.1 mg cm−2, and a wide temperature range of −20–80 °C. Furthermore, a 2.66 Ah-level pouch cell with a high-energy-density of exceeding 356 Wh kg‒1 and excellent cyclic stability demonstrates the potential of the strategy in providing a path for the practical application of quasi-solid-state ether-based electrolytes in high-energy-density batteries.
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来源期刊
Advanced Materials
Advanced Materials 工程技术-材料科学:综合
CiteScore
43.00
自引率
4.10%
发文量
2182
审稿时长
2 months
期刊介绍: Advanced Materials, one of the world's most prestigious journals and the foundation of the Advanced portfolio, is the home of choice for best-in-class materials science for more than 30 years. Following this fast-growing and interdisciplinary field, we are considering and publishing the most important discoveries on any and all materials from materials scientists, chemists, physicists, engineers as well as health and life scientists and bringing you the latest results and trends in modern materials-related research every week.
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