发布求助
文献互助 智能选刊 最新文献

对超分子封装敏感的酰基迁移

IF 4.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Chemical Communications Pub Date : 2025-04-25 DOI:10.1039/d5cc01417d
Oleksandra Lagerna, Alexander Shivanyuk, Tetyana Kienko, Svitlana V. Shishkina, Oleg Lukin, Volodymyr Fetyukhin
{"title":"对超分子封装敏感的酰基迁移","authors":"Oleksandra Lagerna, Alexander Shivanyuk, Tetyana Kienko, Svitlana V. Shishkina, Oleg Lukin, Volodymyr Fetyukhin","doi":"10.1039/d5cc01417d","DOIUrl":null,"url":null,"abstract":"Four isomeric resorcin[4]arene tetrabenzoates interconvert via reversible, base-catalysed acyl migrations. Extraction of solid Me4N+I− into a chloroform solution of the isomers gradually shifts the equilibria towards the C2V-symmetric component due to the formation of highly stable hydrogen-bonded molecular capsules.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"42 1","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Acyl Migrations Sensitive to Supramolecular Encapsulation\",\"authors\":\"Oleksandra Lagerna, Alexander Shivanyuk, Tetyana Kienko, Svitlana V. Shishkina, Oleg Lukin, Volodymyr Fetyukhin\",\"doi\":\"10.1039/d5cc01417d\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Four isomeric resorcin[4]arene tetrabenzoates interconvert via reversible, base-catalysed acyl migrations. Extraction of solid Me4N+I− into a chloroform solution of the isomers gradually shifts the equilibria towards the C2V-symmetric component due to the formation of highly stable hydrogen-bonded molecular capsules.\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"42 1\",\"pages\":\"\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2025-04-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d5cc01417d\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d5cc01417d","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

四种同分异构体间苯二甲酸酯通过可逆的碱催化酰基迁移相互转化。由于形成高度稳定的氢键分子胶囊，将固体Me4N+I -萃取到氯仿溶液中，使平衡逐渐向c2v对称组分转移。
本文章由计算机程序翻译，如有差异，请以英文原文为准。
分享
查看原文 本刊更多论文
Acyl Migrations Sensitive to Supramolecular Encapsulation
Four isomeric resorcin[4]arene tetrabenzoates interconvert via reversible, base-catalysed acyl migrations. Extraction of solid Me4N+I− into a chloroform solution of the isomers gradually shifts the equilibria towards the C2V-symmetric component due to the formation of highly stable hydrogen-bonded molecular capsules.
求助全文
通过发布文献求助，成功后即可免费获取论文全文。 去求助
来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整，为了账户安全，请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们：info@booksci.cn Book学术提供免费学术资源搜索服务，方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号：481959085
Book学术官方微信