芳香环醚需氧C(sp3) -H键光氧化活性Pd6L3笼的配位组装

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-04-25 DOI:10.1039/d5cc01997d

Yu-Hang Hu, Fan Yin, Shun-Xing Hong, Lipeng Zhou, Ke-Han Tang, Ying-Mei Zhong, Chen-Chen Li, Li-Xuan Cai, Qing-Fu Sun

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引用次数: 0

摘要

合成了一种具有大灯笼形腔的Pd6L3笼，并通过NMR、ESI-TOF-MS和x射线衍射分析对其进行了表征，该笼在温和条件下对芳香环醚的C-H选择性有氧光氧化反应表现出优异的催化活性。

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Coordination-Assembly of a Redox-Active Pd6L3 Cage for Aerobic C(sp3)–H Bond Photooxidation of Aromatic Cyclic Ethers

A redox-active Pd₆L₃ cage with a large lantern-shaped cavity has been synthesized and characterised by NMR, ESI-TOF-MS and X-ray diffraction analysis, which shows exceptional catalytic activity in the selective aerobic C–H photooxidation of aromatic cyclic ethers under mild conditions.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.