二氮基二硫族化合物与二茂铁基磷离子的氧化加成：合成、结构和有机催化活性

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-04-25 DOI:10.1039/d5cc01555c

Corina Stoian, Nils Schmidt, Thomas Kuzmera, Pim Puylaert, Enno Lork, Boris J. Nachtsheim, Emanuel Hupf, Jens Beckmann

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引用次数: 0

摘要

二茂铁基磷离子[Fc2P]+ （Fc =二茂铁基）与PhEEPh （E = S, Se, Te）、FcSeSeFc和二苯并[1,2]二硒胺（biphenSe2）反应生成双（芳基）二茂铁基磷离子[Fc2P(SPh)2]+、[Fc2P(SePh)2]+、[Fc2P(TePh)2]+、[Fc2P(SeFc)2]+和[Fc2P(Se2biphen)]+，用于ChB介导的1-甲基吡啶和反式β-克罗酮的Michael加成。

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Oxidative Addition of Diaryldichalcogenides to the Diferrocenylphosphenium Ion: Synthesis, Structure and Organocatalytic Activity

The reaction of the diferrocenylphosphenium ion, [Fc2P]+ (Fc = ferrocenyl) with PhEEPh (E = S, Se, Te), FcSeSeFc and dibenzo[1,2]diselenine (biphenSe2) gave rise to the formation of the bis(arylchalcogenido) diferrocenylphosphonium ions [Fc2P(SPh)2]+, [Fc2P(SePh)2]+, [Fc2P(TePh)2]+, [Fc2P(SeFc)2]+ and [Fc2P(Se2biphen)]+, which were utilised for the chalcogen bond (ChB)-mediated Michael addition of 1-methylindole and trans-β-crotonophenone.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.