共价有机框架中的稳定配位聚合物无定形纳米粒子

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-04-24 DOI:10.1039/d5cc01530h

Boonrasri Seeleang, Soracha Kosasang, Karnjana Atthawilai, Thanakorn Tiyawarakul, Thidarat Imyen, Kanokwan Kongpatpanich, Satoshi Horike

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引用次数: 0

摘要

我们提出了一种方法来制备范围从5到20纳米的无定形配位聚合物纳米颗粒，通过将它们嵌入COF基质中。电子显微镜、x射线吸收光谱和全散射分析证实了无定形配位聚合物的结构。纳米颗粒的高分布有利于杂化材料的高孔隙率和可调发射。

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Stabilisation coordination polymer amorphous nanoparticles in a covalent organic framework

We present an approach to preparing amorphous coordination polymer nanoparticles ranging from 5 to 20 nm by embedding them in a COF matrix. Electron microscopy, X-ray absorption spectroscopy, and total scattering analysis confirm the structure of the amorphous coordination polymer. The high distribution of the nanoparticles facilitates high porosity and tunable emission in the hybrids.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.