Ajeet Singh, Brij Mohan, Vijay Pratap, Wei Sun, Armando J. L. Pombeiro, Bal Chandra Yadav
{"title":"耐湿CeO2/In2O3纳米复合材料基选择性检测甲醛的化学电阻器","authors":"Ajeet Singh, Brij Mohan, Vijay Pratap, Wei Sun, Armando J. L. Pombeiro, Bal Chandra Yadav","doi":"10.1002/smll.202410023","DOIUrl":null,"url":null,"abstract":"Formaldehyde is a frequent indoor pollutant that poses a risk to human and environmental health and is suspected to be a carcinogen. However, achieving high sensitivity and selectivity for real‐time applications remains challenging. In this study, a room‐temperature operated formaldehyde chemiresistor is developed by cerium dioxide/indium oxide (CeO<jats:sub>2</jats:sub>/In<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>) nanocomposite for exclusive detection. The nanocomposite is synthesized using hydrothermal, forming CeO<jats:sub>2</jats:sub> nanospheres grown on In<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> nanocubes. This unique structure enhances the sensing capabilities of CeO<jats:sub>2</jats:sub>/In<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>, allowing it to detect formaldehyde in the 1–50 ppm range, and a 0.157 ppm detection limit is earned. The sensor exhibits an impressive response of 175.05 at 50 ppm at room temperature and shows responsiveness to various other substances, for instance, methanol, ethanol, aniline, benzene, toluene, acetone, and ammonia. Additionally, the CeO<jats:sub>2</jats:sub>/In<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> sensor demonstrated moderate to high selectivity, sensitivity, stability, speedy response/recovery times, and resilience to humidity. This work presents a promising strategy for the detection of formaldehyde.","PeriodicalId":228,"journal":{"name":"Small","volume":"129 1","pages":""},"PeriodicalIF":13.0000,"publicationDate":"2025-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Humidity‐Resistant CeO2/In2O3 Nanocomposite‐Based Chemiresistor for Selective Detection of Formaldehyde\",\"authors\":\"Ajeet Singh, Brij Mohan, Vijay Pratap, Wei Sun, Armando J. L. Pombeiro, Bal Chandra Yadav\",\"doi\":\"10.1002/smll.202410023\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Formaldehyde is a frequent indoor pollutant that poses a risk to human and environmental health and is suspected to be a carcinogen. However, achieving high sensitivity and selectivity for real‐time applications remains challenging. In this study, a room‐temperature operated formaldehyde chemiresistor is developed by cerium dioxide/indium oxide (CeO<jats:sub>2</jats:sub>/In<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>) nanocomposite for exclusive detection. The nanocomposite is synthesized using hydrothermal, forming CeO<jats:sub>2</jats:sub> nanospheres grown on In<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> nanocubes. This unique structure enhances the sensing capabilities of CeO<jats:sub>2</jats:sub>/In<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>, allowing it to detect formaldehyde in the 1–50 ppm range, and a 0.157 ppm detection limit is earned. The sensor exhibits an impressive response of 175.05 at 50 ppm at room temperature and shows responsiveness to various other substances, for instance, methanol, ethanol, aniline, benzene, toluene, acetone, and ammonia. Additionally, the CeO<jats:sub>2</jats:sub>/In<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> sensor demonstrated moderate to high selectivity, sensitivity, stability, speedy response/recovery times, and resilience to humidity. This work presents a promising strategy for the detection of formaldehyde.\",\"PeriodicalId\":228,\"journal\":{\"name\":\"Small\",\"volume\":\"129 1\",\"pages\":\"\"},\"PeriodicalIF\":13.0000,\"publicationDate\":\"2025-04-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Small\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1002/smll.202410023\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Small","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/smll.202410023","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Humidity‐Resistant CeO2/In2O3 Nanocomposite‐Based Chemiresistor for Selective Detection of Formaldehyde
Formaldehyde is a frequent indoor pollutant that poses a risk to human and environmental health and is suspected to be a carcinogen. However, achieving high sensitivity and selectivity for real‐time applications remains challenging. In this study, a room‐temperature operated formaldehyde chemiresistor is developed by cerium dioxide/indium oxide (CeO2/In2O3) nanocomposite for exclusive detection. The nanocomposite is synthesized using hydrothermal, forming CeO2 nanospheres grown on In2O3 nanocubes. This unique structure enhances the sensing capabilities of CeO2/In2O3, allowing it to detect formaldehyde in the 1–50 ppm range, and a 0.157 ppm detection limit is earned. The sensor exhibits an impressive response of 175.05 at 50 ppm at room temperature and shows responsiveness to various other substances, for instance, methanol, ethanol, aniline, benzene, toluene, acetone, and ammonia. Additionally, the CeO2/In2O3 sensor demonstrated moderate to high selectivity, sensitivity, stability, speedy response/recovery times, and resilience to humidity. This work presents a promising strategy for the detection of formaldehyde.
期刊介绍:
Small serves as an exceptional platform for both experimental and theoretical studies in fundamental and applied interdisciplinary research at the nano- and microscale. The journal offers a compelling mix of peer-reviewed Research Articles, Reviews, Perspectives, and Comments.
With a remarkable 2022 Journal Impact Factor of 13.3 (Journal Citation Reports from Clarivate Analytics, 2023), Small remains among the top multidisciplinary journals, covering a wide range of topics at the interface of materials science, chemistry, physics, engineering, medicine, and biology.
Small's readership includes biochemists, biologists, biomedical scientists, chemists, engineers, information technologists, materials scientists, physicists, and theoreticians alike.