硫酸盐盐渍土长期侵蚀下现浇混凝土的降解机理

IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY
Bo Yang , Xiaopeng Hu , Aoyang Li , Tiansong Zhao , YuanQing Sun , Hao Fu
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引用次数: 0

摘要

研究了现浇混凝土长期暴露于硫酸盐盐渍土环境下的降解机理。通过设计不同盐浓度(5 %、10 %和15 %)、水灰比(0.3、0.4和0.5)和水泥类型(OPC、MSRC和HSRC)的影响因素,研究长期盐渍土侵蚀下现浇混凝土的外观劣化、宏观性能劣化、相组成、微观结构特征和孔隙结构变化。结果表明,硫酸盐侵蚀和富钙相的溶解浸出是盐渍土中混凝土降解的主要机制。值得注意的是,较高的盐浓度加速了降解过程,使其更快、更局限。长期暴露于盐渍土中,混凝土孔隙率先减小后增大,孔隙分布特征发生显著变化,凝胶孔隙增长率达到195.31 %-865.45 %。微观结构观察进一步揭示了混凝土中分层区的形成,从表面向内推进。这些带包括方解石外壳、多孔层、腐蚀产物富集层和一个完整的区域。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Degradation mechanism of cast-in-situ concrete under long-term sulfate saline soil attack
This study investigates the degradation mechanism of cast-in-situ concrete under long-term exposure to sulfate saline soil environments. By designing influencing factors of different salt concentrations (5 %, 10 %, and 15 %), water-to-cement ratios (0.3, 0.4, and 0.5), and cement types (OPC, MSRC, and HSRC), the study examines the appearance deterioration, macroscopic performance degradation, phase composition, microstructural features, and pore structure changes of cast-in-situ concrete under long-term saline soil attack. The results reveal that sulfate attack and the dissolution-leaching of calcium-rich phases are the primary mechanisms driving concrete degradation in saline soils. Notably, higher salt concentrations accelerate degradation processes, making them faster and more localized. Long-term exposure to saline soils causes the porosity of concrete to first decrease and then increase, with significant changes in pore distribution characteristics, and the gel pore growth rate reaching 195.31 %-865.45 %. Microstructural observations further reveal the formation of stratified zones in the concrete, progressing inward from the surface. These zones include a calcite crust, a porous layer, a corrosion product enrichment layer, and a complete area.
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来源期刊
Construction and Building Materials
Construction and Building Materials 工程技术-材料科学:综合
CiteScore
13.80
自引率
21.60%
发文量
3632
审稿时长
82 days
期刊介绍: Construction and Building Materials offers an international platform for sharing innovative and original research and development in the realm of construction and building materials, along with their practical applications in new projects and repair practices. The journal publishes a diverse array of pioneering research and application papers, detailing laboratory investigations and, to a limited extent, numerical analyses or reports on full-scale projects. Multi-part papers are discouraged. Additionally, Construction and Building Materials features comprehensive case studies and insightful review articles that contribute to new insights in the field. Our focus is on papers related to construction materials, excluding those on structural engineering, geotechnics, and unbound highway layers. Covered materials and technologies encompass cement, concrete reinforcement, bricks and mortars, additives, corrosion technology, ceramics, timber, steel, polymers, glass fibers, recycled materials, bamboo, rammed earth, non-conventional building materials, bituminous materials, and applications in railway materials.
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