利用芳基硫鎓盐光诱导N-H杂芳烃的n -芳基化反应

IF 2.5 3区化学 Q2 CHEMISTRY, ORGANIC

European Journal of Organic Chemistry Pub Date : 2025-04-22 DOI:10.1002/ejoc.202500303

Zhenhui Wang, Qianqian Yang, Lan Bao, Ruiyun Zhang, Mingming Gao, wei liu

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引用次数: 0

摘要

在这里，我们提出了一个有效的光诱导铜催化的n -芳基化反应，通过N-H杂芳烃与芳基硫鎓盐（Ar-TTs）的交叉偶联发生。这种光激活策略显示出广泛的底物范围，并提供了一种保留活化官能团（如Br， CHO和CN）用于后续衍生化的方法。

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Photoinduced Copper-Catalyzed N-Arylation Reaction of N–H Heteroarenes Using Aryl Thianthrenium Salts

Herein, we present an efficient photoinduced copper-catalyzed N-arylation reaction occurring through the cross-coupling of N–H heteroarene with aryl thianthrenium salt (Ar-TTs). This photoactivation strategy exhibits a broad substrate scope, and offers a method for preserving the activated functional groups (such as Br, CHO, and CN) for subsequent derivatizations.

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来源期刊

European Journal of Organic Chemistry 化学-有机化学

CiteScore

5.40

自引率

3.60%

发文量

752

审稿时长

1 months

期刊介绍： The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry: Liebigs Annalen Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry.