由可见光协同光催化和路易斯酸催化实现的无还原剂对映选择性Aza-Reformatsky反应

Mingyi Jiang, Zengcheng Yu, Linhan Yang, Prof. Fei Wang, Prof. Weidi Cao, Prof. Xiaohua Liu, Prof. Xiaoming Feng
{"title":"由可见光协同光催化和路易斯酸催化实现的无还原剂对映选择性Aza-Reformatsky反应","authors":"Mingyi Jiang,&nbsp;Zengcheng Yu,&nbsp;Linhan Yang,&nbsp;Prof. Fei Wang,&nbsp;Prof. Weidi Cao,&nbsp;Prof. Xiaohua Liu,&nbsp;Prof. Xiaoming Feng","doi":"10.1002/ange.202581762","DOIUrl":null,"url":null,"abstract":"<p>The visible-light and chiral-Lewis-acid synergistically catalyzed reductant-free asymmetric aza-Reformatsky reaction is described by Xiaoming Feng and co-workers in their Communication (e202500756). Control experiments revealed a direct SET process between excited state imine and α-iodo difluoromethyl carbonyl compound which prevents the use of reductant.\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure>\n </p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 17","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202581762","citationCount":"0","resultStr":"{\"title\":\"Frontispiz: Reductant-Free Enantioselective Aza-Reformatsky Reaction Enabled by Synergistic Visible Light Photocatalysis and Lewis Acid Catalysis\",\"authors\":\"Mingyi Jiang,&nbsp;Zengcheng Yu,&nbsp;Linhan Yang,&nbsp;Prof. Fei Wang,&nbsp;Prof. Weidi Cao,&nbsp;Prof. Xiaohua Liu,&nbsp;Prof. Xiaoming Feng\",\"doi\":\"10.1002/ange.202581762\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The visible-light and chiral-Lewis-acid synergistically catalyzed reductant-free asymmetric aza-Reformatsky reaction is described by Xiaoming Feng and co-workers in their Communication (e202500756). Control experiments revealed a direct SET process between excited state imine and α-iodo difluoromethyl carbonyl compound which prevents the use of reductant.\\n <figure>\\n <div><picture>\\n <source></source></picture><p></p>\\n </div>\\n </figure>\\n </p>\",\"PeriodicalId\":7803,\"journal\":{\"name\":\"Angewandte Chemie\",\"volume\":\"137 17\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2025-04-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202581762\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Angewandte Chemie\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ange.202581762\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ange.202581762","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

冯晓明等在他们的通讯(e202500756)中描述了可见光和手性lewis酸协同催化的无还原剂不对称aza-Reformatsky反应。对照实验表明激发态亚胺与α-碘二氟甲基羰基化合物之间存在直接的SET反应过程,避免了还原剂的使用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Frontispiz: Reductant-Free Enantioselective Aza-Reformatsky Reaction Enabled by Synergistic Visible Light Photocatalysis and Lewis Acid Catalysis

Frontispiz: Reductant-Free Enantioselective Aza-Reformatsky Reaction Enabled by Synergistic Visible Light Photocatalysis and Lewis Acid Catalysis

The visible-light and chiral-Lewis-acid synergistically catalyzed reductant-free asymmetric aza-Reformatsky reaction is described by Xiaoming Feng and co-workers in their Communication (e202500756). Control experiments revealed a direct SET process between excited state imine and α-iodo difluoromethyl carbonyl compound which prevents the use of reductant.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Angewandte Chemie
Angewandte Chemie 化学科学, 有机化学, 有机合成
自引率
0.00%
发文量
0
审稿时长
1 months
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信