2,3-二氢呋喃与单质硫化物硫代反应对呋喃和噻吩的不同反应

IF 1.9 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

ChemistrySelect Pub Date : 2025-04-23 DOI:10.1002/slct.202501419

Quang Huy Tran, Cao Nguyen Nguyen, Ngoc Lan Chu, Dr. Thai Thanh Thu Bui, Prof. Thi Thu Tram Nguyen, Minh Tu Ha, Prof.Dr. Dinh Hung Mac, Dr. Thanh Binh Nguyen

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引用次数: 0

摘要

研究了2,3-二氢呋喃与单质硫或分子氧的可切换硫代反应，生成了完全取代的噻吩或呋喃。在这个版本的噻吩生成中，硫化是通过用廉价的硫粉进行一连串的硫化环编辑而发生的。相反，呋喃的生产是通过碱性介质中的好氧氧化来实现的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Divergent Access to Furans and Thiophenes by Chalcogenation of 2,3-Dihydrofurans with Elemental Chalcogens

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Divergent Access to Furans and Thiophenes by Chalcogenation of 2,3-Dihydrofurans with Elemental Chalcogens

A switchable chalcogenation of 2,3-dihydrofurans with elemental sulfur or molecular oxygen to construct fully substituted thiophenes or furans was developed. In this version of thiophene generation, the sulfuration occurs through a cascade of sulfurative ring editing with inexpensive sulfur powder. Conversely, the production of furans is enabled by aerobic oxidation in basic media.

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来源期刊

ChemistrySelect Chemistry-General Chemistry

CiteScore

3.30

自引率

4.80%

发文量

1809

审稿时长

1.6 months

期刊介绍： ChemistrySelect is the latest journal from ChemPubSoc Europe and Wiley-VCH. It offers researchers a quality society-owned journal in which to publish their work in all areas of chemistry. Manuscripts are evaluated by active researchers to ensure they add meaningfully to the scientific literature, and those accepted are processed quickly to ensure rapid online publication.